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Dimethyl secondary amine chain extenders : a conceptual approach to in situ generation of advanced epoxy resins for rapid-cure, low-VOC coatings / Frederick H. Walker in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 6, N° 3 (09/2009)
[article]
Titre : Dimethyl secondary amine chain extenders : a conceptual approach to in situ generation of advanced epoxy resins for rapid-cure, low-VOC coatings Type de document : texte imprimé Auteurs : Frederick H. Walker, Auteur ; Rob Rasing, Auteur ; Gamini A. Vedage, Auteur ; Michael Cook, Auteur Année de publication : 2009 Article en page(s) : p. 283-313 Note générale : Bibliogr. Langues : Américain (ame) Tags : Poly(N-methylazetidine) Dimethyl-meta-xylylenediamine Pseudo-first-order kinetic Amine reactivity epoxy curing agent Epoxy resin coating Flexibility Crosslink density Miller-Macosko calculation Chain extender VOC Low temperature cure Environmental movement Electrochemical impedance Aine reaction mechanism Mannich base Index. décimale : 667.9 Revêtements et enduits Résumé : Advanced epoxy resin oligomers have traditionally been utilized for coatings that combine fast dry-to-touch speed and good flexibility--properties demanded in many markets such as marine and industrial maintenance coatings. Unfortunately, advanced epoxy resins require formulation with large quantities of solvent that make attainment of modern VOC regulations difficult or impossible. Coatings formulated from low molecular weight liquid epoxy resin, on the other hand, can easier meet VOC challenges, but dry slowly and tend to be brittle. This presentation explores the concept of using fast reacting, di-functional amine chain extenders to generate epoxy oligomers in situ as a means to meet these opposing property demands. Methylamine-terminated poly-(N-methylazetidine) (pNMAz, 1) is prepared in a two-step process involving the Michael addition of methylamine to acrylonitrile, followed by hydrogenation in a methylamine-containing atmosphere to yield an oligomer stream with an [M.sub.n] of about 250. Competitive pseudo-first-order kinetic measurements conducted in isopropyl alcohol indicate methyl-substituted disecondary diamines reacted approximately 3 to 3.6 times faster with phenyl glycidyl ether (PGE) than the primary amine meta-xylylenediamine (MXDA). These chain extenders can be formulated with traditional multi-functional amine crosslinkers to yield coatings with lower VOC, faster dry speed, and better flexibility compared to corresponding coatings formulated without the chain extender. DOI : 10.1007/s11998-009-9178-0 En ligne : https://link.springer.com/content/pdf/10.1007%2Fs11998-009-9178-0.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=6111
in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH > Vol. 6, N° 3 (09/2009) . - p. 283-313[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 011503 - Périodique Bibliothèque principale Documentaires Disponible Optimization of UV curable acrylated polyester-polyuréthane/polysiloxane ceramer coatings using a response surface methodology / Ahmet Nebioglu in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 3, N° 1 (01/2006)
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Titre : Optimization of UV curable acrylated polyester-polyuréthane/polysiloxane ceramer coatings using a response surface methodology Type de document : texte imprimé Auteurs : Ahmet Nebioglu, Auteur ; Mark D. Soucek, Auteur Année de publication : 2006 Article en page(s) : p. 61-68 Note générale : Bibliogr. Langues : Américain (ame) Tags : Photochemistry organosilane UV EB radiation cure adhesion design of experiments statistical isocyanate aluminum Index. décimale : 667.9 Revêtements et enduits Résumé : Dual UV and moisture curable acrylated polyester, organic/inorganic hybrid coatings were prepared using a coupling agent and tetraethylorthosilicate (TEOS) oligomers. An acrylated polyester resin based on adipic acid, neopentyl glycol, trimethylolpropane, and acrylic acid was synthesized. TEOS oligomers were prepared through the hydrolysis and condensation of TEOS with water and 3-(triethoxysilyl)propylisocyanate (TEOSPI) was used as the coupling agent between organic and inorganic phases. Trimethylolpropane triacrylate (TMPTA) was used as a reactive diluent. The formulations were cured into films by utilizing UV, followed by moisture curing. The resultant coatings were evaluated in terms of tensile and fracture toughness properties by using ANOVA. Effects of the TEOS oligomers, TEOSPI, and TMPTA on the free radical UV polymerization kinetics were also investigated. The experiments were planned according to the three-factor, three-level Box-Behnken design. Reaction kinetics, fracture toughness, and tensile properties were evaluated in terms of the concentrations of TEOS oligomers, TEOSPI, and TMPTA concentrations. DOI : 10.1007/s11998-006-0006-5 En ligne : https://link.springer.com/content/pdf/10.1007%2Fs11998-006-0006-5.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=3721
in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH > Vol. 3, N° 1 (01/2006) . - p. 61-68[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 003762 - Périodique Bibliothèque principale Documentaires Disponible