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Accelerated weathering of oligomers by UV-B / Inwhan Oh in POLYMERS PAINT COLOUR JOURNAL - PPCJ, Vol. 210, N° 4666 (12/2020)
[article]
Titre : Accelerated weathering of oligomers by UV-B Type de document : texte imprimé Auteurs : Inwhan Oh, Auteur ; Hak-Yul Kim, Auteur ; Sungseo Cho, Auteur ; Indrajit Bhattacharya, Auteur Année de publication : 2020 Article en page(s) : p. 18-21 Langues : Anglais (eng) Catégories : Copolymère uréthane acrylate
Essais de résilience
Oligomères
Photoréticulation
Polymères -- Effet du rayonnement ultraviolet
Polymères -- Détérioration
Polymères aliphatiquesIndex. décimale : 667.9 Revêtements et enduits Résumé : Ultra Violet (UV) energy curing is one of the fastest crosslinking techniques used to dry coatings. UV curable coatings are also one of the most environmentally friendly coating systems as they are typically solvent-free (extremely low VOC/HAPS). Oligomers being almost 100% solids (ppm level solvent residues) have low to medium average molecular weights. Hence, they are liquid at room temperatures. Some oligomers contain some monomers to help reduce their viscosity, to make it easy for the formulator to handle them. However, some industry players do not believe UV curing is really a good solution for outdoor durable coatings. Hence, Miwon Specialty Chemical Co Ltd (MSC) decided to study the performance of some its aliphatic urethane acrylates under accelerated conditions to determine their durability. This paper discusses the tests and the performance that can be achieved when certain well-designed oligomers are exposed to harsh conditions. Note de contenu : - UV curing
- Weathering test equipment
- Preparing the test
- Exposure test and results
- Table 1 : Description of oligomers
- Table 2 : Results using ASTM G154 cycle B test for the five products
- Table 3 : Measurements taken after 1500hr and 2000hr
- Table 4 : Results after testing to ASTM G154 at 1000hr
- Table 5 : Results after testing to ASTM G154 at 2000hrEn ligne : https://drive.google.com/file/d/15yJ7l-CBWLmw0F4QT0uzIQzdG-z6gbGO/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=36740
in POLYMERS PAINT COLOUR JOURNAL - PPCJ > Vol. 210, N° 4666 (12/2020) . - p. 18-21[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 23119 - Périodique Bibliothèque principale Documentaires Disponible
[article]
Titre : Accelerated weathering of oligomers by UV-B Type de document : texte imprimé Auteurs : Inwhan Oh, Auteur ; Hak-Yul Kim, Auteur ; Indrajit Bhattacharya, Auteur ; Sungseo Cho, Auteur Année de publication : 2021 Article en page(s) : p. 72-80 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Copolymère uréthane acrylate
Essais accélérés (technologie)
Oligomères
Photoréticulation
Polymères -- Effet du rayonnement ultraviolet
Polymères -- Détérioration
Polymères aliphatiquesIndex. décimale : 667.9 Revêtements et enduits Résumé : Ultra Violet (UV) energy curing is one of the fastest crosslinking techniques used to dry coatings. UV curable coatings are also one of the most environmentally friendly coating systems as they are typically solvent-free (extremely low VOCIHAPS). Oligomers being almost 100 % solids (ppm level solvent residues) have low to medium average molecular weights. Hence, they are liquid at room temperatures. Some Oligomers contain some monomers, to help reduce their viscosity, to make the formulators job easy to handle them.
However, some industry players do flot believe UV curing is really a good solution for Outdoor durable coatings. Hence Miwon Specialty Chemical Co. Ltd. (MSC) decided to study the performance of some its Aliphatic Urethane acrylates under accelerated conditions to determine their durability. The paper discusses the tests and the performance that can be achieved when certain well-designed Oligomers are exposed to harsh conditions.Note de contenu : - UV curing
- Wheathering test equipment
- Preparing the test
- Exposure test and resultsEn ligne : https://drive.google.com/file/d/1d1nS47mEYceJ5_92Uu40Fc1W6Jo9VmH-/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=36881
in PAINTINDIA > Vol. LXXI, N° 10 (10/2021) . - p. 72-80[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 23037 - Périodique Bibliothèque principale Documentaires Disponible Aliphatic anionic polyurethane microemulsion leather filling-retanning agent / Bao Lihong in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 91, N° 2 (03-04/2007)
[article]
Titre : Aliphatic anionic polyurethane microemulsion leather filling-retanning agent Type de document : texte imprimé Auteurs : Bao Lihong, Auteur ; Lan Yunjun, Auteur ; Shufen Zhang, Auteur Année de publication : 2007 Article en page(s) : p. 73-80 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Agents de tannage
Caractérisation
Charges (matériaux)
Chimie analytique
Cuirs et peaux -- Propriétés mécaniques
Cuirs et peaux -- Propriétés organoleptiques
Cuirs et peaux -- Propriétés physiques
Formulation (Génie chimique)
Imperméabilisation
Microémulsions
Poids moléculaires
Polymères aliphatiques
Polyuréthanes
RetannageIndex. décimale : 675.2 Préparation du cuir naturel. Tannage Résumé : The retanning process plays an important role in optimizing the leather’s colour, levelness, softness, fullness, and hydrophobicity. Polymer retanning agents are important materials for this process. The present study used maleic anhydride modified castor oil (MCO), PEG1000 (polyethylene glycol) and IPDI (isophorone diisocyanate) as main materials to synthesize polyurethane microemulsions (MC-PURs) and employed them to retan chrometanned leathers. The hydroxyl functionality of MCO was investigated by chemical and 1HNMR analysis, and confirmed to be about 2.0. The chemical structures of MCO, prepolymer and MC-PUR were characterized by IR.
The optimized synthesis formulation and polyurethane microemulsion MC-PUR3 for MC-PURs as retanning agent was selected by comparing the properties of retanned leathers, such as softness, fullness, grain tightness, tensile strength, extension at break, depth of shade, waterproof properties et al. Then, MC-PUR3 was characterized by means of DSC, TG/DTG and TEM techniques. SEM microgram of MC-PUR3 retanned leather shows that the fibres are well dispersed.Note de contenu : - EXPERIMENTAL PROCEDURES : Materials - Preparation of maleic anhydride modified castor oil (MCO) - Preparation of microemulsions of polyurethane filling retanning agents (MC-PURs) - Determination of molecular weight - H n.m.r. spectroscopy - Purification - FT-IR spectroscopy - Differential scanning spectroscopy - Thermo-gravimetric analysis - Transmission electron microscope analysis - Measurement of final dyebath exhaustion - Physical and waterproofness properties of leathers - Organoleptic properties of the final leathers - Scanning electron microscopic analysis
- RESULTS AND DISCUSSION : Determination of the average molecular weight, hydroxyl number and average hydroxyl functionality (Fn(OH)) of MCO - Determination of the average hydroxyl functionality of MCO by chemical analysis - Determination of the average hydroxyl functionality of MCO by 1HNMR - Chemical structure analysis by IR
- OPTIMIZATION OF RETANNING AGENT : Effect of MCO/PEG1000 mass ratio on the properties of retanned leathers - Effect of carboxyl content of MC-PUR on the properties of retanned leathers - Effect of NCO/OH molar ratio on the properties of retanned leathers - Thermal properties of MC-PUR3
- Table 1 : Basic formulations of MC-PURs
- Table 2 : Filling, retanning and wet finishing processes
- Table 3 : Effect of MCO/PEG1000 mass ratio on the properties of retanned leathers
- Table 4 : Effect of carboxyl content of MC-PUR on the properties of retanned leathers
- Table 5 : Effect of NCO/OH molar ratio on the properties of retanned leathersEn ligne : https://drive.google.com/file/d/19ti2BicD3kfHFF4Z4QLX1cSWPC0J39gs/view?usp=share [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=39037
in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC) > Vol. 91, N° 2 (03-04/2007) . - p. 73-80[article]Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire Application of nonionic gemini aliphatic polyurethane surfactant for improving the performance of vegetable tanned leather / Shuangquan Lai in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CXIV, N° 11 (11/2019)
[article]
Titre : Application of nonionic gemini aliphatic polyurethane surfactant for improving the performance of vegetable tanned leather Type de document : texte imprimé Auteurs : Shuangquan Lai, Auteur ; Yong Jin, Auteur ; Liangjie Shi, Auteur ; Shenghua Wang, Auteur ; Heng Yang, Auteur Année de publication : 2019 Article en page(s) : p. 403-412 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Acide polyacrylique
Agents de tannage
Collagène
Cuirs et peaux -- Analyse
Cuirs et peaux -- Propriétés mécaniques
Cuirs et peaux -- Propriétés organoleptiques
Morphologie (matériaux)
Photostabilité
Polymères -- Synthèse
Polymères aliphatiques
Retannage
Surfactants
Surfactants -- Synthèse
Tannage végétal
Température de retraitIndex. décimale : 675.2 Préparation du cuir naturel. Tannage Résumé : Vegetable tanned leathers with good embossing, air permeability, natural look and pleasing firm handle properties have applied in many goods with multiple uses. However, the performances of vegetable tanned leathers still need a further improvement. In this work, a kind of nonionic gemini aliphatic polyurethane surfactants (GPUs) with different hydrophobic chain lengths as a retanning agent combined with polyacrylic acid (PAA) for condensed tannin tanned leathers to improve their performances. The effects of the alone or combined use of the PAA and GPU, the hydrophobic chain length of GPU, and the offer percentage of retanning agent were studied by evaluating the organoleptic properties, shrinkage temperature, mechanical properties of the obtained leathers. The best performance was found in the leather retanned with PAA and 12-GPU-550 complex retanning agent, and the mechanical properties of leather could be improved when the total offer percentage was controlled at 4 wt%. Moreover, the collagen fibers morphologies and lightfastness properties of leathers retanned with different retanning agents were investigated. The results showed that the total color difference ΔE and the yellowness index Δb decreased significantly with the introduction of 12-GPU-550, and the leather retanned with PAA and 12-GPU-550 complex retanning agent showed the lowest value of ΔE, demonstrating that the lightfastness properties were improved significantly. Therefore, it was an attractive way to combine use of PAA and 12-GPU-550 as complex retanning agent, which can improve the mechanical and lightfastness properties of vegetable tanned leathers simultaneously. Note de contenu : - MATERIALS AND METHODS : Materials - Synthesis of polyacrylic acid (PAA) - Synthesis of nonionic gemini aliphatic polyurethane surfactants (GPUs) - Application of the synthesized retanning agents - The organoleptic and physical mechanical properties of leathers - Scanning Electron Microscopy analysis of leathers - Light fastness properties of leathers
- RESULTS AND DISCUSSION : Effects of different retanning agents on the properties of leathers - Effect of the hydrophobic chain length of GPU on the properties of leathers - Effect of the offer percentage of complex retanning agent on the properties of leathers - SEM analysis of leathers - Effects of retanning agents on the lightfastness properties of leathersEn ligne : https://drive.google.com/file/d/1ajQdsq8W9LW8sFu6kytH1lIoq_J-RMzI/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=33252
in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA) > Vol. CXIV, N° 11 (11/2019) . - p. 403-412[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 21341 - Périodique Bibliothèque principale Documentaires Disponible Coating performance and characteristics for UV-curable aliphatic urethane acrylate coatings containing norrish type I photoinitiators / Byoung-Hoo Lee in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 3, N° 3 (07/2006)
[article]
Titre : Coating performance and characteristics for UV-curable aliphatic urethane acrylate coatings containing norrish type I photoinitiators Type de document : texte imprimé Auteurs : Byoung-Hoo Lee, Auteur ; J. H. Kim, Auteur ; Jae-Hoon Choi, Auteur Année de publication : 2006 Article en page(s) : p. 221-229 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Copolymère uréthane acrylate
Formulation (Génie chimique)
Fourier, Spectroscopie infrarouge à transformée de
Photoamorceurs (chimie)
Photochimie
Polymères aliphatiques
Revêtements -- Séchage sous rayonnement ultraviolet
Spectroscopie ultraviolette
Surfaces -- AnalyseIndex. décimale : 667.9 Revêtements et enduits Résumé : The purpose of this study was to investigate the influence of several Norrish I (a-cleavage) type photoinitiators and UV dose on the curing behavior and coating performance of UV-curable aliphatic urethane acrylate coatings. UV-curable coatings were cured under a high-pressure mercury lamp. The curing behavior and coating performance of the UV-curable coatings that were cured using 2-hydroxy-2-methyl-1-phenyl-propan-l-one or 1-hydroxy-cyclohexyl-phenyl-ketone were superior to those of the UV-curable coatings cured using bis (2,4,6-trimethylbenzoyl)-phenylphosphine oxide or diphenyl (2,4,6-trimethylbenzoyl)-phosphine oxide, when the UV-curable coating was cured in air. DOI : 10.1007/BF02774511 En ligne : https://link.springer.com/content/pdf/10.1007%2FBF02774511.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=3695
in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH > Vol. 3, N° 3 (07/2006) . - p. 221-229[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 005076 - Périodique Bibliothèque principale Documentaires Disponible Conférences Rencontres Matières premières des 4 et 20 mai 2010 / 2010
PermalinkCuring polyurethane problems / Daniels Len in ADHESIVE TECHNOLOGY, Vol. 15, N° 4 (12/1998)
PermalinkDisbonded coating and cathodic protection shielding for pipelines and utility poles / Mehrooz Zamanzadeh in JOURNAL OF PROTECTIVE COATINGS & LININGS (JPCL), Vol. 34, N° 7 (07/2017)
PermalinkEnvironment-friendly composites for marine applications : the Navecomat project / D. Bourçois in JEC COMPOSITES MAGAZINE, N° 67 (08-09/2011)
PermalinkFully bio-based aliphatic thermoset polyesters via self-catalyzed self-condensation of multifunctional epoxy monomers directly extracted from natural sources / Samer Nameer in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 14, N° 4 (07/2017)
PermalinkFunctional fillers in UV curing wood coatings / Hubert Oggermüller in POLYMERS PAINT COLOUR JOURNAL - PPCJ, Vol. 203, N° 4591 (12/2013)
PermalinkPermalinkGlossy components without painting / Ronny Ebling in KUNSTSTOFFE INTERNATIONAL, Vol. 110, N° 6 (2020)
PermalinkGrafting of biodegradable polyesters on cellulose for biocomposites : characterization and biodegradation / Fatima Ezahra Tabaght in INTERNATIONAL POLYMER PROCESSING, Vol. XXXV, N° 1 (03/2020)
PermalinkHidden blackness of carbon black / Yulia B. Monakhova in EUROPEAN COATINGS JOURNAL (ECJ), (07-08/2024)
PermalinkHyperbranched polymers - A novel class for high performance coatings / Tirthankar Jana in PAINTINDIA, Vol. LXVI, N° 3 (03/2016)
PermalinkInherent matte polyurethane dispersions as matting agent / Terri Carson in COATINGS TECH, Vol. 13, N° 2 (02/2016)
PermalinkInnovative binders for polyaspartic coating concepts / Ayoub Mulla in PAINTINDIA, Vol. LXXI, N° 12 (12/2021)
PermalinkPermalinkModel compound study for acrylic latex crosslinking reactions with cycloaliphatic epoxides / Shaobing Wu in JOURNAL OF COATINGS TECHNOLOGY (JCT), Vol. 69, N° 869 (06/1997)
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