Adsorptive removal of As(V) from aqueous solution by Zr(IV)-loaded skin shavings / Jiao Limin in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CIV, N° 9 (09/2009)  

[article]  inJOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA) > Vol. CIV, N° 9 (09/2009) . - p. 308-315 Titre : Adsorptive removal of As(V) from aqueous solution by Zr(IV)-loaded skin shavings Type de document : texte imprimé Auteurs : Jiao Limin, Auteur ; Xuepin Liao, Auteur ; Bi Shi, Auteur Année de publication : 2009 Article en page(s) : p. 308-315 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Absorbants et adsorbants Arsenic Cuirs et peaux -- Déchets Cuirs et peaux de porcs Déchets -- Elimination Isotherme d'adsorption Solutions aqueuses (chimie) Wet-white (tannage) Zirconium Index. décimale : 675 Technologie du cuir et de la fourrure Résumé : Wet-white shavings are one of the main solid wastes produced in the leather industry. In this paper, Zirconium (IV)-loaded adsorbent (ZrLA) was prepared by using wet-white shavings as the supporting matrix. The fundamental adsorption behaviors of this new adsorbent for arsenic [As(V)] were investigated. It was found that the adsorption capacity of ZrLA for As(V) in aqueous solution was 60.90 mg-g-1, when the initial concentration of As(V) was 75.0 mg. L-1 at pH 4.0 and the dosage of ZrLA was 1.0 g.L-1. The initial pH of As(V) solution significantly affected adsorption capacity of ZrLA to As(V) and the optimal pH for adsorption was in the range of 3.0-6.0. The adsorption isotherms of As(V) could be well fitted by the Langmuir equation, and the maximum adsorption capacities calculated by the Langmuir equation were close to those determined by experiments. The adsorption kinetics of As(V) on ZrLA could be satisfactorily described by the pseudo-second-order rate model. The adsorption capacity was increased with the increase of the zirconium content in ZrLA, and the highest adsorption capacity was obtained when zirconium content of ZrLA was 90-110 mg.g-1. Note de contenu : - EXPERIMENTAL METHODS : Materials - Preparation of Zr(IV)-loaded absorbent based on wet-white shavings - Preparation of As(V) stock solution - Effect of initial pH on adsorption capacity of ZrLA to As(V) - Adsorption isotherms - Effect of zirconium content in ZrLA on adsorption capacity - Adsorption kinetics - RESULTS AND DISCUSSION : Effect of initial pH on adsorption capacity of ZrLA to As(V) - Adsorption isotherm - Effect of the zirconium content in ZrLA on As(V) adsorption - Adsorption kinetics En ligne : https://drive.google.com/file/d/1UEbM9mmPakXpBVSI8vBe0FL-y0wo2W29/view?usp=drive [...] Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=17835 [article]

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Phosphorylated collagen fibre : preparation and use for adsorbing heavy metals / Jiao Limin in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 93, N° 5 (09-10/2009)  

[article]  inJOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC) > Vol. 93, N° 5 (09-10/2009) . - p. 201-206 Titre : Phosphorylated collagen fibre : preparation and use for adsorbing heavy metals Type de document : texte imprimé Auteurs : Jiao Limin, Auteur ; Xuepin Liao, Auteur ; Bi Shi, Auteur Année de publication : 2009 Article en page(s) : p. 201-206 Note générale : Bibliogr. Langues : Anglais (eng) Index. décimale : 675 Technologie du cuir et de la fourrure Résumé : Phosphorylated collagen fibre (P-CF) was prepared using phosphorus oxychloride as a phosphorylating reagent. Solid state 31P-NMR and FTIR analysis proved that phosphate groups were bound with amino groups of collagen fibre.As a novel fibrous adsorbent, P-CF performed to be an effective adsorbent for metal ions, such as Pb2+, Cd2+, Co2+, Ni2+, Cu2+, Zn2+ and UO2 2+. By using Cd2 as probe ion, the fundamental adsorption behaviours of P-CF to metal ions were investigated. The adsorption capacity was significatly influenced by pH value, and the optimal pH for adsorbing Cd2+ located in the pH range of 3.83-6.22. The adsorption isotherms of Cd2+ were well fitted by the langmuir equation. The adsorption capacity was increased with the increase of temperature. The adsorption kinetics was satisfactorily described by the pseudo-second-order rate model, implying that the chemical adsorption of P-CF to Cd2+ is the rate controlling step. Moreover, P-CF can be easily desorbed using dilute HNO3 solution. En ligne : https://drive.google.com/file/d/1f1luv_KVuG7Luz_kx7kxwST9GisqfiqD/view?usp=drive [...] Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=6281 [article]

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