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Effect of specific additives on the degree of sulfonation and its influence on leather fatliquoring / R. Janardhanan in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CVII, N° 9 (09/2012)
[article]
Titre : Effect of specific additives on the degree of sulfonation and its influence on leather fatliquoring Type de document : texte imprimé Auteurs : R. Janardhanan, Auteur ; V. Vijayabaskar, Auteur ; B. S. R. Reddy, Auteur Année de publication : 2012 Article en page(s) : p. 279-285 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Additifs
Catalyse par transfert de phase
Cuirs et peaux
Emulsifiants
Mouillage (chimie des surfaces)
Potentiel zeta
Produits de nourriture du cuir
Sulfonation
Sulfosuccinates
Surfactants
Tension superficielleIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : Sulfosuccinate type anionic surfactants are classical ingredients for industrial applications. They are of great interest because of their excellent surfactant properties. Fatliquors prepared from sulfosuccinates have been effectively utilized in the leather industry, where the degree of sulfonation of the surfactant plays a crucial role in deciding performance. This paper reports on the study of factors such as the addition of phase transfer catalyst, non-ionic wetting emulsifier and co-solvent on the degree of sulfonation. Emusification power, zeta potential, surface tension and particle size were measured. Reaction conditions were optimized, based on the results. Fatliquors were prepared using different sulfosuccinates and applied on leather. The properties of resultant leathers were studied qualitatively and quantitatively, and SEM studies were carried out for the treated leathers. This work provides a basis for the development of better fatliquoring agents. Note de contenu : - MATERIALS AND METHODS : Materials - Control batch - Experiment 1 (E1 - Addition 5% phase transfer catalyst) - Experiment 2 (E2 - Addition 5% non-ionic emulsifier) - Experiment 3 (E3 - Addition 5% co-solvent) - Application on leather - Characterisation methods
- PROPERTIES OF RESULTANT LEATHER
- SEM STUDIES
- DISCUSSION : Sulfonate content of the surfactants - Effect of co-solvent - Effect of emulsifier - Effect of phase transfer catalyst - Properties of sulfosuccinates - Properties of resultant leathersEn ligne : https://drive.google.com/file/d/1fV7HN44YCVqzM67LrDl2HHYBnbANX-r3/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=16058
in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA) > Vol. CVII, N° 9 (09/2012) . - p. 279-285[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 14267 - Périodique Bibliothèque principale Documentaires Disponible 14209 - Périodique Bibliothèque principale Documentaires Disponible Sulfate-free surfactants : what about sulfonates ? / Alexander T. Wagner in PERSONAL CARE EUROPE, Vol. 12, N° 2 (04/2018)
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Titre : Sulfate-free surfactants : what about sulfonates ? Type de document : texte imprimé Auteurs : Alexander T. Wagner, Auteur Année de publication : 2018 Article en page(s) : p. 61-65 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Sulfates -- Suppression ou remplacement
Sulfoacétates
Sulfonates
Sulfosuccinates
SurfactantsIndex. décimale : 668.5 Parfums et cosmétiques Résumé : Sulfate-free or not sulfate-free? That is the question when customers are studying the INCI list of personal care products and find ingredients like surfactants based on sulfoacetates or sulfosuccinates. In fact, the discussion linked to that question is rather fruitless but one by one....
Conversations with customers show that the demand for sulfate-free cleansing products is growing more and more. Surfactant producers follow this trend and increasingly aim to develop sulfate-free surfactants. Additionally, already existing suitable products are claimed as sulfate-free. Of course there is no question that sulfur-free surfactants like for instance the mild and natural based Zschimmer & Schwarz Protelan- and Sebumol-Types (hydrophilic groups: amino acids or their derivatives and polyglycerol)' are sulfate-free.
In discussions, the clarity in answering the question "sulfate-free or not sulfate-free?" disappears often in that moment when sulfur-containing surfactants like sulfonates corne into play. Therefore, in the following we will focus on sulfoacetates and sulfosuccinates as prominent representatives of sulfonate surfactants used in personal care applications. The perspectives that we take at first are driven by the chemistry followed by the application.Note de contenu : - Chemical perspective
- Mildness of surfactants
- Why sulfonates as replacement for sulfate surfactants
- Products based on alkyl sulfosuccinates and/or alkyl sulfoacetates
- Zschimmer & Schwarz sulfonate surfactants in detail
- Foam and viscosity in sulfoacetate sulfosuccinate based surfactant system : Disodium laureth sulfosuccinate, sodium lauryl sulfoacetate - Sodium lauroyl sarcosinate, sodium lauryl sulfoacetate
- Special application of sulfoacetate/sulfosuccinate surfactants : colour protection
- FIGURES : 1. Alkyl sulfate and alkyl ether sulfate (≥ 1) : C-O-S bonds - 2. Alkyl(ether) sulfosuccinate and alkyl sulfoacetate : C-S bonds - 3. Hydrogen sulfite - 4. Inorganic sulfate - 5. Different location of the sulfo-group : top and middle : sulfo-groups next to ester groups : "methyl-bridge" between sulfo- and ester groups - 6. Mean index of ocular irritation (test results : Z&S) : SLS : Sodium lauryl sulfate, SLES (2 EO) : sodium laureth-2-sulfate, CAPB : cocamido propyl betaine, indicated ration : related to active matter - 7. Patch test on human skin (test results Institute for Skin and Product Evaluation) A. m. : Active matter - 8. Viscosity behaviour of the formulation based on Lumoral K5601 - 9. Colour protection (different dye stuffs) by different shampoos, SLES : Sodium laureth sulfate, CAPB : cocamido propyl betaine
- TABLES : 1. Shampoo formulation baed on Lumoral K 5019 - 2. Body wash formulation based on Lumoral K 5601En ligne : https://drive.google.com/file/d/1YPaq84P1RxDO207khb5sdxsCv2WGs5ti/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=30449
in PERSONAL CARE EUROPE > Vol. 12, N° 2 (04/2018) . - p. 61-65[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 19931 - Périodique Bibliothèque principale Documentaires Disponible