| Titre : |
Mechanistic studies of mineral tanning - Part I : : Solid state aluminium-27 NMR studies and the thermodynamics of shrinking |
| Type de document : |
texte imprimé |
| Auteurs : |
Anthony D. Covington, Auteur ; R. A. Hancock, Auteur ; I. A. Ioannidis, Auteur |
| Année de publication : |
1989 |
| Article en page(s) : |
p. 1-8 |
| Note générale : |
Bibliogr. |
| Langues : |
Anglais (eng) |
| Index. décimale : |
675 Technologie du cuir et de la fourrure |
| Résumé : |
Aluminium-27 solid state NMR spectroscopy has been applied to investigate the interactionat the molecular level of various aluminium based tanning salts with leather. High resolution and variable temperature Al-solid state NMR studies, combined with differential scanning calorimetry and kinetic studies of the shrinking of Al-tanned hide powder and sheepskin samples have clearly shown that shrinking is a kinetically controlled process, during which the synthetic crosslinks remain intact. The shrinkage temperature is determined by the size of the formed crosslinked macromolecular moieties which in turn depends on the kinetics stability of the interactions of the tanning agent with collagen. |
| En ligne : |
https://drive.google.com/file/d/1nWW_-bJbgR1Pfd3BbI_FsAWZj_n39ZNi/view?usp=drive [...] |
| Format de la ressource électronique : |
Pdf |
| Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=8812 |
in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC) > Vol. 73 (Année 1989) . - p. 1-8
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Mechanistic studies of mineral tanning - Part I : in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 73 (Année 1989)
