[article]
| Titre : |
Kinetic spectrophotometric flow injection determination of hyamine cationic surfactants in tannery effluent |
| Type de document : |
texte imprimé |
| Auteurs : |
Tu Jie, Auteur ; Zhang Xinshen, Auteur ; Dai Shinjun, Auteur ; Yu Lingyun, Auteur ; Tong Ling, Auteur ; Sun Dongmei, Auteur ; Liu Hongyan, Auteur ; Yu Lan, Auteur |
| Année de publication : |
2009 |
| Article en page(s) : |
p. 114-117 |
| Note générale : |
Bibliogr. |
| Langues : |
Anglais (eng) |
| Index. décimale : |
675 Technologie du cuir et de la fourrure |
| Résumé : |
A flow injection analysis coupled with catalytic spectrophotometry is proposed for simple and rapid determination of trace hyamine cationic surfactants (CSs) in tannery effluent and environmental water. The scheme is based on the markedly catalytic reaction of cationic surfactants, i.e., cetyltrimetylammonium bromide (CTMAB) and cetylpyridinium bromide (CPB) which, on oxidation using KIO4 inhighly acidic hydrochloric acid medium discolour Arsenazo (III). Under the optimum conditions, the linear ranges for CTMAB and CPB are 0.1-20mg 1-1, and all relative coefficients of the two Css in different subsections of the linear ranges exceeds 09986 (n=11). The detection limits (3delta) of both the CSs are 0.08mg 1-1, and the recoveries range from 95.7 % to 103.1 %.
The relative standard deviation (R. S. D.) is 1.21 % for 2mg 1-1 CTMAB standard solution (n = 21). The developed method, which is suitable for automatic and continuous analysis, can monitor 15 samples per hour. It has been applied successfully to tannery effluent and environmental water samples. |
| En ligne : |
https://drive.google.com/file/d/1bSNhFCYzjdUi2t9M9eL2YXWic3mnL6IC/view?usp=drive [...] |
| Format de la ressource électronique : |
Pdf |
| Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=5941 |
in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC) > Vol. 93, N° 3 (05-06/2009) . - p. 114-117
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