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Adsorption isotherm and kinetics of tannic acid on to carbonized chrome tanned leather solid waste / Rubina Chaudhary in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CXII, N° 6 (06/2017)
[article]
Titre : Adsorption isotherm and kinetics of tannic acid on to carbonized chrome tanned leather solid waste Type de document : texte imprimé Auteurs : Rubina Chaudhary, Auteur ; Anupama Pati, Auteur Année de publication : 2017 Article en page(s) : p. 198-206 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Absorbants et adsorbants
Carbonisation
Cinétique chimique
Cuirs et peaux -- Déchets
Déchets industriels -- Elimination
Isotherme d'adsorption
Solutions aqueuses (chimie)
TaninsIndex. décimale : 675.2 Préparation du cuir naturel. Tannage Résumé : The disposal of chrome tanned leather shavings (CTLS) waste is a serious concern for the environment due to the presence of chromium. In this study, an attempt has been made to prepare adsorbent from CTLS through carbonization process. Carbonization of CTLS at temperature 600°C had provided surface area of 620 m2 g-1 and total pore volume of 0.49 cm3 g-1. The adsorption study is conducted by employing adsorbent prepared from CTLS on adsorbate tannic acid. The effects of various experimental parameters have been investigated using a batch adsorption technique to obtain information on treating wastewater containing tannic acid. The extent of tannic acid removal was studied by varying parameters such as pH, contact time, initial concentration of the tannic acid and amount of adsorbent. The removal efficiency of tannic acid in aqueous solution is found to be about 95%. The experimental equilibrium data for this system has been analyzed using the linearized forms of Langmuir and Freundlich isotherms. The Langmuir isotherm was found to provide the best theoretical correlation of the experimental data for the adsorption of tannic acid. The adsorption of tannic acid on adsorbent increased from 57 to 63 mg g-1, when the temperature was increased from 30 to 60°C. The adsorption was found to follow pseudo-second order kinetics. In short, this study provides a greener solution for CTLS and tannin containing wastewater. Note de contenu : - EXPERIMENTAL : Materials - Preparation of carbonized (CTLS) - Preparation of aqueous solution of tannic acid as adsorbent - Adsorption studies - Isotherm studies - Adsorption kinetics
- RESULTS AND DISCUSSION : Characteristics of adsorbent - Effect of pH, initial concentration and treatment period on the removal of tannic acid - Adsorption isotherms - Adsorption kineticsEn ligne : https://drive.google.com/file/d/1Lftyao8lb93ahjiuqGy0Rs24kz2_QTyL/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=28690
in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA) > Vol. CXII, N° 6 (06/2017) . - p. 198-206[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 19012 - Périodique Bibliothèque principale Documentaires Disponible Adsorptive removal of As(V) from aqueous solution by Zr(IV)-loaded skin shavings / Jiao Limin in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CIV, N° 9 (09/2009)
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Titre : Adsorptive removal of As(V) from aqueous solution by Zr(IV)-loaded skin shavings Type de document : texte imprimé Auteurs : Jiao Limin, Auteur ; Xuepin Liao, Auteur ; Bi Shi, Auteur Année de publication : 2009 Article en page(s) : p. 308-315 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Absorbants et adsorbants
Arsenic
Cuirs et peaux -- Déchets
Cuirs et peaux de porcs
Déchets -- Elimination
Isotherme d'adsorption
Solutions aqueuses (chimie)
Wet-white (tannage)
ZirconiumIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : Wet-white shavings are one of the main solid wastes produced in the leather industry. In this paper, Zirconium (IV)-loaded adsorbent (ZrLA) was prepared by using wet-white shavings as the supporting matrix. The fundamental adsorption behaviors of this new adsorbent for arsenic [As(V)] were investigated. It was found that the adsorption capacity of ZrLA for As(V) in aqueous solution was 60.90 mg-g-1, when the initial concentration of As(V) was 75.0 mg. L-1 at pH 4.0 and the dosage of ZrLA was 1.0 g.L-1. The initial pH of As(V) solution significantly affected adsorption capacity of ZrLA to As(V) and the optimal pH for adsorption was in the range of 3.0-6.0. The adsorption isotherms of As(V) could be well fitted by the Langmuir equation, and the maximum adsorption capacities calculated by the Langmuir equation were close to those determined by experiments. The adsorption kinetics of As(V) on ZrLA could be satisfactorily described by the pseudo-second-order rate model. The adsorption capacity was increased with the increase of the zirconium content in ZrLA, and the highest adsorption capacity was obtained when zirconium content of ZrLA was 90-110 mg.g-1. Note de contenu : - EXPERIMENTAL METHODS : Materials - Preparation of Zr(IV)-loaded absorbent based on wet-white shavings - Preparation of As(V) stock solution - Effect of initial pH on adsorption capacity of ZrLA to As(V) - Adsorption isotherms - Effect of zirconium content in ZrLA on adsorption capacity - Adsorption kinetics
- RESULTS AND DISCUSSION : Effect of initial pH on adsorption capacity of ZrLA to As(V) - Adsorption isotherm - Effect of the zirconium content in ZrLA on As(V) adsorption - Adsorption kineticsEn ligne : https://drive.google.com/file/d/1UEbM9mmPakXpBVSI8vBe0FL-y0wo2W29/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=17835
in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA) > Vol. CIV, N° 9 (09/2009) . - p. 308-315[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 011556 - Périodique Bibliothèque principale Documentaires Disponible 011557 - Périodique Bibliothèque principale Documentaires Disponible Adsorptive removal of Ni2+ from aqueous solution by low cost cellulosic adsorbent-adsorption kinetics and isotherm study / Sultan Alam in TENSIDE, SURFACTANTS, DETERGENTS, Vol. 50, N° 2 (03-04/2013)
[article]
Titre : Adsorptive removal of Ni2+ from aqueous solution by low cost cellulosic adsorbent-adsorption kinetics and isotherm study Type de document : texte imprimé Auteurs : Sultan Alam, Auteur ; Noor-ul-Amin, Auteur ; Najeeb-ur-Rehman, Auteur ; Azmat Ullah, Auteur Année de publication : 2013 Article en page(s) : p. 104-112 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Absorbants et adsorbants
CelluloseLa cellulose est un glucide constitué d'une chaîne linéaire de molécules de D-Glucose (entre 200 et 14 000) et principal constituant des végétaux et en particulier de la paroi de leurs cellules.
Cinétique chimique
Coefficient de partage (chimie)
Isotherme d'adsorptionIndex. décimale : 668.1 Agents tensioactifs : savons, détergents Résumé : Adsorptive removal of Ni2+ from aqueous solution by low cost cellulosic adsorbent was investigated with respect to adsorption kinetics and adsorption isotherm. Adsorbent was characterized by BET surface area, SEM, EDX, FTIR and Zeta potential technique and reported earlier. The surfaces contain carbonyl and hydroxyl functional groups, which act as binding sites for Ni2+ ion. Adsorption kinetics of Ni2+ was tested by first order, Elovich, parabolic diffusion and Bangham kinetic equations. Thermodynamic parameters like ?H?, ?S? and ?G? were calculated from the kinetic data. The rate of adsorption was high at high adsorption temperature. Positive values of ?S? reflect some structural exchange among the active site of the adsorbent and metal ion. Freundlich, Langmuir, Temkin isotherms and distribution coefficient were found fit to the adsorption isotherm data.. Note de contenu : - EXPERIMENTAL : Materials and instruments - Characterization - Adsorbent preparation - Adsorption kinetic - Adsorption isotherm study
- RESULTS AND DISCUSSION : Characterization - Adsorption kinetics - Adsorption isotherm studyDOI : 10.3139/113.110229 Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=17888
in TENSIDE, SURFACTANTS, DETERGENTS > Vol. 50, N° 2 (03-04/2013) . - p. 104-112[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 14844 - Périodique Bibliothèque principale Documentaires Disponible An investigation of mild carbon steel corrosion inhibition in hydrochloric acid medium by environment friendly green inhibitors / M. Gopiraman in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 9, N° 1 (01/2012)
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Titre : An investigation of mild carbon steel corrosion inhibition in hydrochloric acid medium by environment friendly green inhibitors Type de document : texte imprimé Auteurs : M. Gopiraman, Auteur ; P. Sakunthala, Auteur ; D. Kesavan, Auteur ; V. Alexramani, Auteur ; I. S. Kim, Auteur Année de publication : 2012 Article en page(s) : p. 15-26 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Acier L'acier est un alliage métallique utilisé dans les domaines de la construction métallique et de la construction mécanique.
L'acier est constitué d'au moins deux éléments, le fer, très majoritaire, et le carbone, dans des proportions comprises entre 0,02 % et 2 % en masse1.
C'est essentiellement la teneur en carbone qui confère à l'alliage les propriétés du métal qu'on appelle "acier". Il existe d’autres métaux à base de fer qui ne sont pas des aciers comme les fontes et les ferronickels par exemple.
Anticorrosifs
Brugmansia suaveolens
Cassia roxburghii
Chimie écologique
Chlorhydrique, Acide
Electrochimie
Fourier, Spectroscopie infrarouge à transformée de
Isotherme d'adsorption
Métaux -- Revêtements protecteurs
Microscopie électronique à balayage
Spectroscopie d'impédance électrochimique
Surfaces -- AnalyseIndex. décimale : 667.9 Revêtements et enduits Résumé : Inhibition effect of Brugmansia suaveolens (BS) and Cassia roxburghii (CR) on mild carbon steel in 1.0 M HCl solution was studied. Inhibition efficiency of plant extracts were carried out by using chemical (weight loss method) and electrochemical techniques (potentiodynamic polarization and electrochemical impedance spectroscopy). The effect of temperature on the corrosion behavior of mild carbon steel in 1.0 M HCl with addition of plant extracts was studied in the temperature range of 300–320 ± 1 K. Inhibition efficiencies up to 94.69 for BS and 93.22 for CR can be obtained. The adsorption mechanism of inhibition was supported by FT-IR, surface analysis (SEM–EDS), and adsorption isotherms. The thermodynamic parameter values of free energy of adsorption (?G ads) reveal that inhibitor was adsorbed on the mild carbon steel surface via both physisorption and chemisorption mechanisms. Note de contenu : EXPERIMENTAL : Inhibitors preparation - Coupon and solution preparation - Chemical techniques (weight loss methods) - Electrochemical techniques - FT-IR spectrum - SEM and EDS analysis
- RESULTS AND DISCUSSION : Effect of inhibitors concentration - Effect of temperature - Effect of acid concentration - Tafel polarization - Electrochemical impedance spectroscopy - Adsorption isotherms - FT-IR spectrum - SEM and EDS analysisDOI : 10.1007/s11998-011-9374-6 En ligne : https://link.springer.com/content/pdf/10.1007/s11998-011-9374-6.pdf?pdf=button Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=14351
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Code-barres Cote Support Localisation Section Disponibilité 14095 - Périodique Bibliothèque principale Documentaires Disponible Aswan clay as sorbent for removal of Cr(III) and Cr(VI) from synthetic solution and tannery wastewater / O. A. Mohamed in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 89, N° 5 (09-10/2005)
[article]
Titre : Aswan clay as sorbent for removal of Cr(III) and Cr(VI) from synthetic solution and tannery wastewater Type de document : texte imprimé Auteurs : O. A. Mohamed, Auteur ; S. A. Sayed, Auteur ; H. S. Mohamady, Auteur ; N. H. El-Sayed, Auteur Année de publication : 2005 Article en page(s) : p. 204-209 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Absorbants et adsorbants
Adsorption
Argile
Caractérisation
Chrome trivalent -- Absorption
Déchets industriels -- Elimination
Eaux usées -- Epuration
Eaux usées -- Teneur en chrome trivalent
Isotherme d'adsorption
Tannage -- DéchetsIndex. décimale : 675.2 Préparation du cuir naturel. Tannage Résumé : The sorption on Aswan clay of Cr(III) and Cr(VI) from synthetic solution and tannery wastewater has been studied. The clay has been characterized and used for the removal of chrome. The adsorption was studied as a function of pH, contact time, adsorbate concentration, loading, temperature and interfering ions. The equilibrium data fitted well with a Freundlich adsorption isotherm, where the Kf and n values are 2.08 - 4.6 for Cr(VI), 14.45 - 2.5 for Cr(III) and 8.31 - 2.4 for tannery wastewater. In our study we choose Aswan clay, which is low in cost, to aid the economy of the process. Adsorption studies indicated that chrome removal is 77% for CrVI, 90% for CrIII and 75% for a tannery wastewater. Note de contenu : - MATERIALS AND METHODS : Adsorbents
- CHARACTERISTICS OF ASWAN CLAY : X-ray diffraction analysis - Adsorbates - Chemicals - Instrumentation - Methods
- RESULTS AND DISCUSSION : Effect of pH - Effect of agitation time - Effect of adsorbent loading - Effect of adsorbate concentration - Effect of temperature - Effect of some anions on chromium (VI) removal
- ADSORPTION ISOTHERMSEn ligne : https://drive.google.com/file/d/1TtT-yFTYThWUEKw5oSLffFro0XdfeHyr/view?usp=share [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=39231
in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC) > Vol. 89, N° 5 (09-10/2005) . - p. 204-209[article]Exemplaires
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