[article]
| Titre : |
Synthesis of Cationic Surfactant Intermediates 3-(dimethylamino)-propane-1,2-di-alkylcarbamate |
| Type de document : |
texte imprimé |
| Auteurs : |
S.-M. Zhang, Auteur ; W.-H. Qiao, Auteur ; X.-Y. Chen, Auteur ; D.-L. Liu, Auteur |
| Année de publication : |
2009 |
| Article en page(s) : |
p. 228-231 |
| Note générale : |
Bibliogr. |
| Langues : |
Anglais (eng) |
| Catégories : |
Surfactants -- Synthèse
|
| Tags : |
Synthese surfactant cationique 3-(diméthylamino)-propane-1,2-di-alkylcarbamate |
| Index. décimale : |
668.1 Agents tensioactifs : savons, détergents |
| Résumé : |
Two cationic surfactant intermediates were synthesized by improved method. The alkyl isocyanates, dodecyl isocyanate (1a) and tetradecyl isocyanate (1b), were synthesized by corresponding alkyl amines and bis(trichloromethyl) carbonate (BTC) in anhydrous toluene. The yield of 1a–b reached 86%, the product was colorless liquid and the purity was measured more than 98% by GC. The target products, 3-(dimethylamino)propane-1,2-di-dodecylcarbamate (2a) and 3-(dimethylamino)propane-1,2-di-tetradecylcarbamate (2b) were synthesized by 1-dimethylamino-2,3-propanediol and alkyl isocyanates with triethylamine as catalyst, the yield of 2a–b was 65%. |
| Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=6056 |
in TENSIDE, SURFACTANTS, DETERGENTS > Vol. 46, N° 4/2009 (07-8/2009) . - p. 228-231
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Synthesis of Cationic Surfactant Intermediates 3-(dimethylamino)-propane-1,2-di-alkylcarbamate in TENSIDE, SURFACTANTS, DETERGENTS, Vol. 46, N° 4/2009 (07-8/2009)
