Titre : |
Iodinated thermal-fused polymer as a biocidal additive to commercial and chemical-resistant coatings |
Type de document : |
texte imprimé |
Auteurs : |
L. di Ionno, Auteur ; P. J. Messier, Auteur |
Année de publication : |
2004 |
Article en page(s) : |
p. 265-272 |
Note générale : |
Bibliogr. |
Langues : |
Anglais (eng) |
Catégories : |
Antimicrobiens Formulation (Génie chimique) HalogènesVIIA. Ces éléments chimiques sont : le fluor 9F, le chlore 17Cl, le brome 35Br, l’iode 53I et l’astate 85At.
Ces éléments chimiques peuvent se trouver liés à la quasi-totalité des autres éléments chimiques du tableau périodique, y compris quelques gaz nobles pour ce qui concerne le fluor. A 0 °C sous la pression atmosphérique, les corps simples correspondant sont sous forme de molécules diatomiques : à l'état gazeux pour le difluor F2 et le dichlore Cl2, liquide pour le dibrome Br2 et solide pour le diiode I2 et l’astate. Aucun ne se trouve dans la nature sous cette forme. La forme la plus courante, dans la nature est la forme ionique (ions fluorure, chlorure, bromure ou iodure) et, en quantité moins abondante, dans des combinaisons moléculaires, par exemple avec le carbone. C'est le cas des hormones thyroïdiennes iodées par exemple. Iode Latex Polyacryliques Polyalkydes Polymères -- Additifs Résistance chimique Revêtement émail:Peinture-émail Revêtements en phase aqueuse -- Additifs:Peinture en phase aqueuse -- Additifs Revêtements organiques
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Index. décimale : |
667.9 Revêtements et enduits |
Résumé : |
This paper includes internal and external research demonstrating surface bioactivation by an iodinated thermalfused polymer. An antimicrobial technology based on the controlled release of iodine was demonstrated for medical, commercial mould contamination, outdoor environment contamination, and military chemical agent-resistant coatings (CARC). Results showed biocidal activity of CARC paint incorporating this antimicrobial system againstErwinia herbicola (Eh) andEscherichia coli (E coli). Water-based flat latex and alkyd oil-based enamel showed reductions >99.96% and 99.98%, respectively. Both formulations displayed significant biocidal activity againstE coli Bacteriophages MS2. Commercial paint formulations have demonstrated active anti-microbial activity againstbacillus subtilis and fungi. An analytical method was developed to determine the level of volatile iodine released from the iodinated thermal- fused polymer- painted surface at standard air exchanges. Iodine was collected and the resultant iodide was quantitated using the Leuco Crystal Violet method. A detection limit of 0.01 mg/m3 was achieved and was deemed adequately sensitive relative to the referenced threshold limit value (TLV) of 1.036 mg/m3. Iodine airborne concentrations for both latex and acrylic paints tested in the simulation chamber were observed to be equal to or less than the TLV with the exception of a few data points. |
Note de contenu : |
- METHOD : Biocidal activity screening - Surface bioactivation protocol developed by USMC - Standard method to determine resistance to mould - Toxicology protocol
- RESULTS AND DISCUSSION : USMC study - ASTM D3293-94 resistance to mould study - Toxicology study
- CONCLUSIONS : USMC study - Surface bioactivation - ASTM D3293-94 resistance to mould study - Toxicology study
- Table 1 : Percentage reduction ol Eco/iand Eh
- Table 2 : Solvent-borne CARC challenged with Eh suspension2
- Table 3 : Waler-borne CARC challenged with Eh suspension2
- Table 4 : Water-based flat latex challenged with Eh suspension2
- Table 5 : Alkyd oil-based enamel challenged with Eh suspension2
- Table 6 : Results of MS2 liquid spray challenge ot the Mil-C-2275O/iodinated thermal-fused polymer-impregnated coupons2
- Table 7 : Performance of iodinated thermal-fused polymer incorporated paint against Bacillus subtilis spores afler 24 and 48 hours of contact time
- Table 8 : Comparative ratings for mould growth observed on panels exposed in environmental chamber 1
- Table 9 : Comparalive ratings lor mould growth observed on panels exposed in environmental chamber2
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DOI : |
10.1007/BF02699675 |
En ligne : |
https://link.springer.com/content/pdf/10.1007/BF02699675.pdf |
Format de la ressource électronique : |
Pdf |
Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=5447 |
in SURFACE COATINGS INTERNATIONAL. PART B : COATINGS TRANSACTIONS > Vol. 87, B4 (12/2004) . - p. 265-272