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Development of natural colors in Cr-Fe tanned upper leathers / Jonnalagadda Raghava Rao in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. XCVII, N° 7 (07/2002)
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Titre : Development of natural colors in Cr-Fe tanned upper leathers Type de document : texte imprimé Auteurs : Jonnalagadda Raghava Rao, Auteur ; C. Prabhakar, Auteur ; R. Rajapandian, Auteur ; Palanisamy Thanikaivelan, Auteur ; J. Malathi, Auteur ; Balachandran Unni Nair, Auteur Année de publication : 2002 Article en page(s) : p. 267-283 Note générale : Bibliogr. Langues : Américain (ame) Index. décimale : 675.2 Préparation du cuir naturel. Tannage Résumé : Dyes based on synthetic formulations are being widely used in the leather industry. However, it is known that many aryl amine dyes are banned due to their carcinogenic nature. Environmental concern leads one to look for dye products based on natural resources, which have several advantages like biodegradability, less toxicity, etc. The basis of this approach is to achieve an eco-friendly dyeing process with the use of iron salts, which give rise to various colors on reacting with vegetable tannins. Goatskins have been tanned with Cr-Fe tanning salt and striked with different vegetable tanning materials like wattle, chestnut, myrobalan and quebracho at various concentrations. Colors like brown, bluish black, deep black and grey shades have been developed. The color shades obtained have been quantified by reflectance measurements and compared with the visual assessment data. The strength and bulk properties are not significantly altered by increasing the concentration of various vegetable tannins from 1 to 5%. However, treatment with 5% wattle decreases the strength properties of the leathers appreciably due to its heavy filling nature coupled with prior filling using co-filling syntans. En ligne : https://drive.google.com/file/d/1V2CEzpPOP0NqfSdqEwjsHzy5U6UKp9Bf/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=4287
in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA) > Vol. XCVII, N° 7 (07/2002) . - p. 267-283[article]Réservation
Réserver ce documentDevelopment of natural colours in Cr-Fe tanned garment leathers / J. R. Rao in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 86, N° 3 (05-06/2002)
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Titre : Development of natural colours in Cr-Fe tanned garment leathers Type de document : texte imprimé Auteurs : J. R. Rao, Auteur ; Palanisamy Thanikaivelan, Auteur ; J. Malathi, Auteur ; R. Rajaram, Auteur ; Balachandran Unni Nair, Auteur Année de publication : 2002 Article en page(s) : p. 106-111 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Acacia et constituants
chataigner et constituants
Chrome
Colorimétrie
Croûte (cuir)On entend par "cuir en croûte" des cuirs ayant subi les opérations jusqu'au tannage, à l'exclusion de toute opération de corroyage ou de finissage, mais qui, par opposition aux wet-blue ont été séchés.
Cuirs et peaux -- Propriétés physiques
Cuirs et peaux -- Teinture
Fer
Myrobalan et constituants
QuebrachoLe quebracho est un arbre à écorce ligneuse, mesurant 30 mètres de haut, à feuilles tannées et à fleurs tubulées blanches.
Quebracho est l'un des noms communs, en espagnol, d'au moins trois espèces similaires d'arbres originaires du Gran Chaco, en Amérique latine : Schinopsis lorentzii (quebracho colorado santiagueño), de la famille des Anacardiaceae ; Schinopsis balansae (quebracho colorado chaqueño), de la même famille ;
Aspidosperma quebracho-blanco (quebracho blanc), de la famille des Apocynaceae.
Ces trois espèces sont riches en tanin et fournissent un bois très dur, particulièrement résistant. Leur nom provient de l'espagnol quiebrahacha, qui signifie brise-hache.
Réflectance
Résistance à l'abrasion
Tanins végétaux
Tannage minéralTannage dans lequel interviennent différents minéraux. Le plus répandu est le tannage aux sels de chrome, mais aussi à l’aluminium
Vêtements en cuirIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : Dyes based on synthetic formulations are widely used in the leather industry, however, many aryl amine dyes are restricted due to their carcinogenic nature. Environmental concern leads one to look for the dye products based on natural resources, which may have advantages of biodegradability and lower toxicity. We aimed to create an eco-friendly dyeing process by forming in-situ complexes between vegetable tannins and the Cr-Fe tanning salt, where the use of iron salts results in various colours on reaction with various vegetable tannins. Sheepskins were tanned using the Cr-Fe tanning salt and treated with various vegetable tanning materials, brown, black and grey shades were developed. The shades obtained have been quantified by reflectance measurements and compared by visual assessment.
Strength characteristics of the leathers treated with 5% vegetable tannins are higher than those treated with 1% tannins, bulk properties not being affected with the increase in concentration from 1 to 5%. The light, wet and dry rub fastness of the naturally coloured leathers are good with no change on ageing. Colour reproduction at bulk level production is acceptable with minor batch variations.Note de contenu : - EXPERIMENTAL DETAILS : Process details for larger scale trials - Physical testing
- RESULTS AND DISCUSSION : Wattle - Chestnut - Myrobalan - Quebracho - Environmental Perception
- Table 1 : Percentage reflectance measurement for garment leathers coloured with various concentrations of wattle
- Table 2 : Visual assessment data of the garment samples treated with various concentrations of wattle (Grade points 0-poor and 10-very good)
- Table 3 : Visual assessment data of the garment samples treated with various concentrations of chestnut (Grade points 0-poor and 10-very good)
- Table 4 : Visual assessment data of the garment samples treated with various concentrations of myrobalan (Grade points 0-poor and 10-very good)
- Table 5 : Percentage reflectance measurement for garment leathers coloured with various concentrations of quebrancho
- Table 6 : Visual assessment data of the garment samples treated with various concentrations of quebracho (Grade points 0-poor and 10-very good)
- Table 7 : Strength characteristics for various crust garment leathers
- Table 8 : Visual assessment data for garment leathers treated with selected concentrations of vegetable tannins
- Table 9 : Fastness of the naturally coloured leathers treated with selected concentration of vegetable tannins to wet, dry rubbing and artificial light
- Table 9 : Comparison of colour measurements data between the sample and bulk colouration of leathers using selected concentration vegetable tanninsEn ligne : https://drive.google.com/file/d/1cy6baDBVvluD26gKPLzG7iFzZjo83l1w/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=39924
in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC) > Vol. 86, N° 3 (05-06/2002) . - p. 106-111[article]