| Titre : |
Hyperbranched polymer polyols : their preparation, modification and use in the leather industry |
| Type de document : |
texte imprimé |
| Auteurs : |
Wang Xuechuan, Auteur ; Yuan Xuzheng, Auteur ; Qiang Taotao, Auteur ; Ren Longfang, Auteur |
| Année de publication : |
2009 |
| Article en page(s) : |
p. 61-72 |
| Note générale : |
Bibliogr. |
| Langues : |
Anglais (eng) |
| Index. décimale : |
675 Technologie du cuir et de la fourrure |
| Résumé : |
A series of hyperbranched (poly(amine-ester) polyols (HPAEPs) were synthesized by the polycondensation of N,N-diethylol-3-amine-methylpropionate [prepared by the Michael addition reaction of methyl acrylate (MA) with diethanolamine (DEA)] as an AB2-type monomer with trimethylol propane (TMP) as the core moiety, proceeding in one-step procedure in the melt with p-toluenesulfonic acid (p-TSA) as catalyst. Then, it was modified by diethyl malonate (DEM) in the presence of catalyst (anhydrous K2CO3) via transesterification to obtain a water-soluble hyperbranched polymer with active methylene (HPAM), which can be used as formaldehyde elimination agent. The obtained polymers were characterized by FTIR and TGA. the application results show that HPAEP can be used as the retanning agent with reinforcing performance (tear strength increased by 23.3 % and tensile strength increased by 11.3 %) and bleaching efect (whiteness value increase by 19.8 %) meanwhile. The removal efficiency of free-formaldehyde in leather could reach 56.25 % at 2 % dosage of HPAM for capturing 5h. |
| En ligne : |
https://drive.google.com/file/d/12Z2LzH5ZpratMjYdV_Cs8EhKwA1PLKpP/view?usp=drive [...] |
| Format de la ressource électronique : |
Pdf |
| Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=5094 |
in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC) > Vol. 93, N° 2 (03-04/2009) . - p. 61-72
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Hyperbranched polymer polyols : their preparation, modification and use in the leather industry in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 93, N° 2 (03-04/2009)
