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Imidization of styrene-maleic anhydride copolymer for dispersing nano-SiO2 in water / Tao Xue in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 20, N° 6 (11/2023)
[article]
Titre : Imidization of styrene-maleic anhydride copolymer for dispersing nano-SiO2 in water Type de document : texte imprimé Auteurs : Tao Xue, Auteur ; Caili Yu, Auteur ; Zhongqun Zhou, Auteur ; Faai Zhang, Auteur Année de publication : 2023 Article en page(s) : p. 1867-1880 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Agents dispersants (chimie)
Analyse thermique
Caractérisation
Copolymère styrène-maléimide
Copolymères -- Synthèse
Dioxyde de silicium
Nanoparticules
Poids moléculaires
Solutions aqueuses (chimie)
ThermogravimétrieIndex. décimale : 667.9 Revêtements et enduits Résumé : Achieving functional styrene-maleic anhydride (SMA) copolymer dispersant is highly attractive but still remains a challenge. Conventional modified SMA dispersants have complex modification steps, poor performance, and limited applications. Thus, a series of styrene–maleimide (SMI) copolymers with different functionality as amphiphilic dispersants for dispersing nano-SiO2 in an aqueous solution were synthesized using a simple preparation process. The changes in the maleic anhydride groups during imidization were tracked using FTIR spectroscopy, 1H-NMR, and GPC. A rotational viscometer and an inverted bottle method were used to measure the viscosity and coagulation time of the nano-SiO2 aqueous dispersion system, respectively, after adding the SMI dispersants. The particle size, size distribution, and dispersant adsorption amount of the dispersion were analyzed using laser particle size analysis ; FTIR spectroscopy and SEM; and TGA, respectively. The results showed that the hydrogen bonds formed between the amino groups in the dispersant and the hydroxyl groups on the SiO2 surface during stirring allowed the dispersant to be adsorbed onto the SiO2 surface after being added to the nano-SiO2 aqueous system. The addition of the SMI dispersant enhanced the steric hindrance and electrostatic repulsion between the nanoparticles, thus making it possible for the SiO2 nanoparticles not to easily aggregate in water, improving their dispersity and stability. Additionally, the type and amount of SMI dispersant used significantly affected the SiO2 nanoparticles' ability to disperse in water. This makes SiO2 particles convenient to use and transport, not produce dust pollution, and easy to store. Note de contenu : - EXPERIMENTAL : Materials - Synthesis of styrene–maleimide dispersants - Preparation of nano-SiO2 aqueous system - Characterization
- RESULTS AND DISCUSSION : Synthesis and characterization of the styrene-maleimide (SMI) copolymers - TGA analysis - DSC analysis - Dispersion of the nano-SiO2 aqueous system - Solubility of polymeric dispersant in different solvents
- Table 1 : Recipe and properties of SMI dispersant
- Table 2 : Molecular weight and PDI of SMA and SMI
- Table 3 : Solubility of polymers in different solventsDOI : https://doi.org/10.1007/s11998-023-00783-6 En ligne : https://link.springer.com/content/pdf/10.1007/s11998-023-00783-6.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=40167
in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH > Vol. 20, N° 6 (11/2023) . - p. 1867-1880[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 24337 - Périodique Bibliothèque principale Documentaires Disponible Preparation of PVA/PU/PUA microcapsules and application in self-healing two-component waterborne polyurethane coatings / Xinmeng Xu in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 19, N° 3 (05/2022)
[article]
Titre : Preparation of PVA/PU/PUA microcapsules and application in self-healing two-component waterborne polyurethane coatings Type de document : texte imprimé Auteurs : Xinmeng Xu, Auteur ; Zhongqun Zhou, Auteur ; Liangrong Qin, Auteur Année de publication : 2022 Article en page(s) : p. 977-988 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Anticorrosifs
Anticorrosion
Caractérisation
Microcapsules
Polyacétate de vinyle
Polymères -- Synthèse
Polyurée
Polyuréthanes
Revêtement autoréparant
Revêtements bi-composant
Revêtements en phase aqueuseIndex. décimale : 667.9 Revêtements et enduits Résumé : It is difficult to produce coatings that have good mechanical and self-healing properties. In this study, polyvinyl alcohol/polyurethane/polyurea (PVA/PU/PUA) microcapsules (MCs) loaded with isophorone diisocyanate (IPDI) as core materials were first prepared by interfacial polymerization in an oil-in-water emulsion using different PVA as an emulsifier. The MCs were then uniformly dispersed in the matrix. Optical microscopy and scanning electron microscopy revealed that the size of MCs decreased as alcoholysis and polymerization degree of PVA increased. Thermogravimetric analysis showed that the MCs prepared with the high polymerization or alcoholysis degree of PVA revealed outstanding thermal stability, and the initial decomposition temperature increased by approximately 100°C compared with IPDI. Furthermore, the self-healing performance of the two-component waterborne polyurethane (2K WPU) coating system containing MCs was investigated. The 2K WPU coatings with 9 wt% PVA/PU/PUA MCs exhibited excellent self-healing, mechanical properties, and corrosion resistance, and indicated a high potential for smart coating. Note de contenu : - EXPERIMENTAL METHODS AND MATERIALS : Materials - Synthesis of PVA solution - Synthesis of MCs - Preparation of self-healing 2K - WPU coatings - Characterization
- RESULTS AND DISCUSSION : Analysis and characterization of MCs - Self-healing performance of 2K WPU
- Table 1 : Thermal weight loss data of MCs and capsule shells
- Table 2 : Film performance of 2K WPU coatings loaded with different types of MCs
- Table 3 : Coating performance of 2K WPU with different MCs contentDOI : https://doi.org/10.1007/s11998-021-00577-8 En ligne : https://link.springer.com/content/pdf/10.1007/s11998-021-00577-8.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=38091
in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH > Vol. 19, N° 3 (05/2022) . - p. 977-988[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 23605 - Périodique Bibliothèque principale Documentaires Disponible