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Effect of calcium in delimed hide on leather quality / Chao Lei in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CXVIII, N° 3 (03/2023)
[article]
Titre : Effect of calcium in delimed hide on leather quality Type de document : texte imprimé Auteurs : Chao Lei, Auteur ; Xuyang Chen, Auteur ; Yunhang Zeng, Auteur ; Bi Shi, Auteur Année de publication : 2023 Article en page(s) : p. 109-116 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Confitage Le confitage est une action biochimique effectuée au moyen de produits enzymatiques, qui a pour but de dégrader les fibres élastiques, contribuant ainsi à augmenter la souplesse du cuir. En outre, les enzymes complètent la dégradation des résidus épidermiques, donnant ainsi une fleur plus propre et plus lisse.
Croûte (cuir)On entend par "cuir en croûte" des cuirs ayant subi les opérations jusqu'au tannage, à l'exclusion de toute opération de corroyage ou de finissage, mais qui, par opposition aux wet-blue ont été séchés.
Cuirs et peaux -- Analyse
Cuirs et peaux -- Qualité
Cuirs et peaux -- Teneur en calcium
DéchaulageOpération consistant à débarrasser les peaux de la chaux et des substances alcalines qui leur ont été appliquées au pelanage.
Post-tannage
Tannage au chromeIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : The efficient removal of calcium from delimed hide is essential to leather quality, but few reports have elaborated on how residual calcium in delimed hide affects leather quality. In this study, four delimed hides containing different calcium content were first prepared by using ammonium sulfate and sodium gluconate. Energy dispersive X-ray spectrometry results showed that the atomic percentages of calcium on the grain surfaces of the four delimed hides were 8.17%, 4.82%, 2.34%, and 0.25%, respectively. The bating, chrome tanning, and post-tanning performances of the four delimed hides were then analyzed to evaluate the effect of calcium in delimed hide on leather quality. Results showed that the removal efficiency of non-collagenous protein from hide in enzymatic bating, the evenness of chromium distribution, the shrinkage temperature of wet blue, and the physical properties of crust leather all increased as the calcium content of delimed hide decreased. Furthermore, efficient calcium removal from the grain surface of delimed hide played a key role in the color brightness and uniformity of wet blue and crust leather. The results draw our attention to the importance of considering the effectual removal of calcium from delimed hide for obtaining high-quality leather. Note de contenu : - EXPERIMENTAL : Materials - Deliming experiments and evaluation of deliming performance - Bating experiments and evaluation of bating performance - Tanning experiments and evaluation of tanning performance - Post-tanning experiments and evaluation of crust leather performance
- RESULTS AND DISCUSSION : Preparation of delimed hides with different calcium contents - Effect of calcium in delimed hide on bating performance - Effect of calcium in delimed hide on chrome tanning performance - Effect of calcium in delimed hide properties of crust leather
- Table 1 : Color parameters of the wet blue
- Table 2 : Color parameters of the crust leathers
- Table 3 : Physical properties of the crust leathersDOI : https://doi.org/10.34314/jalca.v118i3.6814 En ligne : https://drive.google.com/file/d/1n_-gOygNCeRyRRHTXA8LSWDtFa7g5kkf/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=39001
in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA) > Vol. CXVIII, N° 3 (03/2023) . - p. 109-116[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 23921 - Périodique Bibliothèque principale Documentaires Disponible Effect of pickling materials on leather quality from a hide surface charge perspective / Tianqi Yang in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CXVII, N° 7 (07/2022)
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Titre : Effect of pickling materials on leather quality from a hide surface charge perspective Type de document : texte imprimé Auteurs : Tianqi Yang, Auteur ; Yunhang Zeng, Auteur ; Qingyong Sun, Auteur ; Chao Lei, Auteur ; Bi Shi, Auteur Année de publication : 2022 Article en page(s) : p. 279-287 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Composés aromatiques
Croûte (cuir)On entend par "cuir en croûte" des cuirs ayant subi les opérations jusqu'au tannage, à l'exclusion de toute opération de corroyage ou de finissage, mais qui, par opposition aux wet-blue ont été séchés.
Cuirs et peaux -- Propriétés physiques
Pénétration cutanée
PicklageLe picklage consiste à faire absorber à la peau en tripe une quantité importante d'acide, en présence de sel neutre (NaCl) pour réprimer le gonflement que provoquerait l'acidité du milieu.
Sulfoniques, Acides
Tannage au chrome
Wet-blue (tannage)Peau tannée au chrome (le chrome donne une couleur bleue)Index. décimale : 675 Technologie du cuir et de la fourrure Résumé : Salt-free pickling technology has recently received increased attention because it produces much lower salt pollution than the conventional pickling technology using formic acid, sulfuric acid, and sodium chloride. However, the existing salt-free pickling materials, for instance, aromatic sulfonic acids (ASAs), lead to reduced leather quality and the reason behind this phenomenon is unclear. In this study, we explored how ASAs affect the properties of tanned leather. Results showed that typical ASAs, such as 5-sulfosalicylic acid, 1,5-naphthalenedisulfonic acid, and 2-naphthalenesulfonic acid, penetrated cattle hide more slowly compared with formic and sulfuric acids because of their large molecular weight and strong intermolecular interactions with hide collagen. ASAs decreased the positive charge of the pickled hide via interactions with their sulfonic acid groups, resulting in the increased adsorption rate of chrome tanning agent to the hide surface. Rapid tanning agent adsorption could impede the deep penetration and uniform distribution of the agent in the ASA-pickled hide. Thus, the properties of wet blues and crust leathers pickled with ASAs are inferior to those of wet blue and crust leather pickled using conventional pickling materials. Our results indicate that a strongly positive charge of the pickled hide is vital to obtaining high-quality leather and provide insights into salt-free pickling materials from a hide surface charge perspective. Note de contenu : - EXPERIMENTAL : Materials - Pickling experiments - Analyses of pickling performance - Analyses of chrome tanning performance - Determination of the physical properties of crust leather
- RESULTS AND DISCUSSION : Penetration of various acids into hide - Surface charge properties of hides pickled with various acids - Hydrothermal stability and fiber dispersion of hides pickled with various acids - Effect of pickling materials on chrome tanning performance - Effect of pickling materials on the physical properties of crust leathers
- Table 1 : Pickling and chrome tanning processes
- Table 2 : Pseudo-first-order and pseudo-second-order kinetic parameters for chrome adsorption
- Table 3 : Physical properties of crust leathersDOI : https://doi.org/10.34314/jalca.v117i7.5962 En ligne : https://drive.google.com/file/d/1UhajIthtPvDv2bquUbfxlI9pj2WugNC8/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37820
in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA) > Vol. CXVII, N° 7 (07/2022) . - p. 279-287[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 23515 - Périodique Bibliothèque principale Documentaires Disponible Efficient removal of ammonia-nitrogen from deliming effluent by using magnesium ammonium phosphate precipitation method / Hao Wang in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CXVII, N° 3 (03/2022)
[article]
Titre : Efficient removal of ammonia-nitrogen from deliming effluent by using magnesium ammonium phosphate precipitation method Type de document : texte imprimé Auteurs : Hao Wang, Auteur ; Chao Lei, Auteur ; Yunhang Zeng, Auteur ; Hongguang Guo, Auteur ; Bi Shi, Auteur Année de publication : 2022 Article en page(s) : p. 104-112 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Azote ammoniacal
Caractérisation
Cuirs et peaux
Déchets industriels -- Elimination
Eaux usées -- Epuration
pH
Phosphate d'ammonium
Phosphate de magnésiumLe terme phosphate de magnésium est le nom générique pour les sels inorganiques de magnésium issus de l'acide phosphorique. Leur formule est :
- le dihydrogénophosphate de magnésium (Mg(H2PO4)2) ;
- l'hydrogénophosphate de magnésium (MgHPO4) ;
- le phosphate de magnésium (proprement dit) ou phosphate de trimagnésium (Mg3(PO4)2
Ils incorporent éventuellement des molécules d'eau de cristallisation ; par exemple, le phosphate de magnésium tribasique (Mg3(PO4)2⋅nH2O) peut contenir 4, 5 ou 8 molécules d'eau. La bobierrite (it) est la forme minérale naturelle du phosphate de magnésium octahydraté.
L'hydrogénophosphate de magnésium trihydraté se présente sous la forme d'une poudre blanche cristalline. La newbéryite est sa forme minérale naturelle.
Les phosphates de magnésium entrent dans la composition du tissu osseux. (Wikipedia)
Précipitation (chimie)
Tannage -- DéchetsIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : Ammonia nitrogen (NH 3 -N) pollutant has received much attention in the leather industry. An efficient strategy for removal of NH 3 -N from tannery wastewater was proposed by using a magnesium ammonium phosphate (MAP) precipitation method to remove NH 3 -N from deliming effluent with the highest NH 3 -N concentration among all leather-making effluents. Results showed that approximately 80% of NH 3 -N was removed from deliming effluent when reacting at P/Mg/N mole ratio of 1.2:1.2:1.0 and pH 9.5 for 20 min. The NH 3 -N and total nitrogen concentrations of tannery wastewater (a composite wastewater of all leather-making effluents) sharply decreased by treating deliming effluent with MAP precipitation, which greatly improved the biological treatment efficiency of tannery wastewater. The residual concentration of NH 3 -N in the treated tannery wastewater was less than 2 mg/L. The total phosphorus concentration of tannery wastewater increased by less than 0.4 mg/L, indicating that secondary pollution of phosphorus did not occur after MAP precipitation treatment. Note de contenu : - EXPERIMENTAL : Materials - Effect of pH adjustment method on NH3-N removal efficency - Optimization of MAP precipitation method for removal of NH3-N from deliming effluent - Effect of P/N - Effect of Mg/N - Effect of reaction pH - Effect of reaction time - X-ray diffraction analysis of precipitate - Aerobic bological treatment of simulated tannery wastewater
- RESULTS AND DISCUSSION : Effect of pH adjustment method on NH3-H removal efficiency - Effects of reaction conditions on the removal of NH3-N from deliming effluent byusing MAP precipitation method - Characterization of precipitation - Effect of MAP precipitation method on the biological treatment of tannery wastewater
- Table 1 : Wastewater sampling from leather-making procedures
- Table 2 : Effect of pH adjustment method on nH3-N removal efficiency
- Table 3 : Concentrations of NH3-N, TOC, TN, and TP in simulated tannery wastewater before and after aerobic biological treatmentEn ligne : https://drive.google.com/file/d/1x6437XHaUBXbfG44KKIBz68wrvyhOs4J/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37601
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Code-barres Cote Support Localisation Section Disponibilité 23402 - Périodique Bibliothèque principale Documentaires Disponible Enhancement of mechanical and thermal insulation properties of polyvinyl chloride foam using leather shavings / Chao Lei in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CXIX, N° 6 (06/2024)
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Titre : Enhancement of mechanical and thermal insulation properties of polyvinyl chloride foam using leather shavings Type de document : texte imprimé Auteurs : Chao Lei, Auteur ; Xu Weixing, Auteur ; Bi Shi, Auteur ; Yunhang Zeng, Auteur Année de publication : 2024 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Charges (matériaux)
Chlorure de polyvinyle
Cuirs et peaux -- Déchets -- Recyclage
Essais de résilience
Essais dynamiques
Isolation thermique
Mousses plastiques
Mousses plastiques -- Propriétés mécaniques
RhéologieIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : The global production of leather shavings (LSs) amounts to millions of tons annually, posing significant challenges in terms of resource waste and environmental pollution if not effectively managed. This study explores the utilization of LSs by fabricating modified leather fibers (MLFs) as reinforcing fillers to enhance the mechanical and thermal insulation properties of polyvinyl chloride (PVC) foams. The process involved pulverizing LSs and modifying them with a polyethylene glycol–isophorone diisocyanate (PEG–IPDI) prepolymer to create MLF. This MLF was then incorporated into PVC to produce MLF/PVC foam. The PEG–IPDI prepolymer modification aligned the surface free energy of MLF (33.82 ± 1.97 mJ/m2) with that of PVC (31.08 ± 3.65 mJ/m2), thereby improving their interfacial compatibility and imparting thermal energy storage capacity to the MLF. The resulting MLF/PVC foam exhibited enhancements in compressive strength and modulus, showing increases of 93.7% and 165.8%, respectively, compared to pure PVC foam. Furthermore, MLF/PVC foam demonstrated a slower surface temperature increase when heated using a heating plate at 110°C compared to pure PVC foam. These findings indicate that MLF enhances the mechanical and thermal insulation properties of PVC foams, primarily due to the improved foaming and thermal storage capacities imparted by the MLF. Note de contenu : - EXPERIMENTAL : Materials - Preparation of MLF - Preparation of PVC-based composite foams - Analyses of morphology and chemical structure - Analysis of rheological behavior - Analysis of foaming capacity - Testing of compressive properties - Analysis of thermal energy storage capacity - Testing of thermal insulation property
- RESULTS AND DISCUSSION : Structure and properties of MLF - Interfacial structure of MLF/PVC - Rheological behavior of MLF/PVC - Foaming capacity of MLF/PVC - Mechanical properties of MLF/PVC foam - Thermal energy storage capacity of MLF/PVC foam - Thermal insulation properties of MLF/PVC foam
- Table 1 : Formulation of pure PVC and composite foams
- Table 2 : Thermal performance parameters of fillers and foamsDOI : https://doi.org/10.34314/syc1sb89 En ligne : https://drive.google.com/file/d/1VkmDNoHTu43WmMgf6eTJ34uTVdIWI9Za/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=40988
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Code-barres Cote Support Localisation Section Disponibilité 24700 - Périodique Bibliothèque principale Documentaires Sorti jusqu'au 30/09/2024