Effect of three structurally different epoxy resins on fire resistance, optical transparency, and physicomechanical properties of intumescent fire-retardant transparent coatings / Raj Shree in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 18, N° 2 (03/2021)  

[article]  inJOURNAL OF COATINGS TECHNOLOGY AND RESEARCH > Vol. 18, N° 2 (03/2021) . - p. 535–547 Titre : Effect of three structurally different epoxy resins on fire resistance, optical transparency, and physicomechanical properties of intumescent fire-retardant transparent coatings Type de document : texte imprimé Auteurs : Raj Shree, Auteur ; R. Baloji Naik, Auteur ; Rupesh S. Naik, Auteur ; G. Gunasekaran, Auteur Année de publication : 2021 Article en page(s) : p. 535–547 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Caractérisation Charbon, Cendres de Composés organiques -- Synthèse Epoxydes Essais de comportement au feu Fourier, Spectroscopie infrarouge à transformée de Gommes et résines Ignifugeants Composé chimique utilisé pour réduire l'inflammabilité. Il peut être incorporé au produit durant sa fabrication ou appliqué ultérieurement à sa surface. Intumescence (chimie) Phosphates Polyphosphorique, Acide Revêtements -- Propriétés mécaniques Revêtements -- Propriétés physiques Revêtements organiques Transparence (optique) Index. décimale : 667.9 Revêtements et enduits Résumé : Transparent intumescent fire-retardant (IFR) coatings are the newest passive fireproofing materials which maintain structural integrity without losing aesthetic appearance of the substrate. In this present paper, effects of three IFR coatings with structurally different epoxy resins, namely aliphatic, cycloaliphatic, and aromatic, on the fire resistance, transparency, and physicomechanical properties were investigated. Different phosphate resin acids (PRA) were prepared by reacting synthesized phosphate ester acid (PEA) with aliphatic, cycloaliphatic, and aromatic epoxy resins. The chemical structures of the above PEA and PRAs were confirmed by Fourier transform infrared spectroscopy (FTIR), 1H-nuclear magnetic resonance spectroscopy (1H-NMR), and 31P-nuclear magnetic resonance spectroscopy (31P-NMR). Subsequently, transparent IFR coatings were prepared by mixing these PRAs with hexamethoxy methyl melamine resin. Transparency of the coatings was confirmed by UV–Vis–NIR spectrophotometeric studies. Fire protection property and char compressive strength were done to investigate the fire protection ability of the coatings, and the quality of the char formed was analyzed by field emission scanning electron microscope. The decomposition process of prepared fire-retardant coatings was studied by thermogravimetric analysis. Results showed that aliphatic epoxy-based transparent coating produced tough and compact char, but the char height was negligible, and aromatic epoxy-based transparent coating produced soft and fluffy char having excellent char height; however, the fluffy char reduced protection for longer duration. Cycloaliphatic epoxy-based transparent coating produced tough and compact char with good char height, thereby reducing heat transfer during combustion, and also showed superior scratch, abrasion, impact, and water resistance compared to other compositions. Note de contenu : - EXPERIMENTAL : Materials - Synthesis of phosphate resin acid (PRA) - Preparation of coating sample - CHARACTERIZATION : Characterization of prepared resins - Characterization of transparent coatings - Characterization of char formed - RESULTS AND DISCUSSION : Thermogravimetric analysis (TGA) - Transparency of coating prepared using PRAs - Physicomechanical properties of transparent IR coatings - Fire resistant test - Characterization of char - Table 1 : Composition and acid value of prepared resins - Table 2 : Physicomechanical performance of all PRAs - Table 3 : Elemental composition of char obtained from the EDAX analysis DOI : https://doi.org/10.1007/s11998-020-00422-4 En ligne : https://link.springer.com/content/pdf/10.1007/s11998-020-00422-4.pdf Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=35613 [article]

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Phytic acid based novel optically transparent intumescent fire-retardant coating for protection of combustible substrates with retention of aesthetic appearance / Raj Shree in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 19, N° 2 (03/2022)  

[article]  inJOURNAL OF COATINGS TECHNOLOGY AND RESEARCH > Vol. 19, N° 2 (03/2022) . - p. 509-525 Titre : Phytic acid based novel optically transparent intumescent fire-retardant coating for protection of combustible substrates with retention of aesthetic appearance Type de document : texte imprimé Auteurs : Raj Shree, Auteur ; R. Baloji Naik, Auteur ; G. Gunasekaran, Auteur Année de publication : 2022 Article en page(s) : p. 509-525 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Caractérisation Composés organiques -- Synthèse Ester de phosphate Ignifugeants Composé chimique utilisé pour réduire l'inflammabilité. Il peut être incorporé au produit durant sa fabrication ou appliqué ultérieurement à sa surface. Intumescence (chimie) Phytique, Acide Polymères ramifiés Polyols Revêtements -- Propriétés mécaniques Revêtements -- Propriétés physiques Revêtements organiques Revêtements protecteurs Transparence (optique) Index. décimale : 667.9 Revêtements et enduits Résumé : Phosphorus source in transparent intumescent fire-retardant (IFR) coatings plays a crucial role in determining its performance against protecting structures from fire. In the present work, naturally occurring environmentally benign phosphorus-rich phytic acid (PA) was used as a phosphorus source. Phosphate ester resin (PER) was synthesized using PA and hyperbranched polyol (HBP), which was then used as a precursor for preparing optically transparent IFR coatings. The prepared PER was further modified with hydrogenated bisphenol-A (DGEHBA)-based epoxy resin in different wt% (25–100) to get PER-1, PER-2, PER-3, and PER-4, respectively. The formation of the PER resins was confirmed by Fourier transform infrared spectroscopy (FTIR), 13C-nuclear magnetic resonance, 31P-nuclear magnetic resonance spectroscopy (31P-NMR), and acid value analysis. The transparent IFR coatings were prepared by suitably mixing PER with hexamethoxy methyl melamine (HMMM) resin, and their performance was studied by measuring mechanical properties, optical transparency, thermal stability, fire retardancy, and smoke emission characteristics using various analytical instruments. The combination of PA and hyperbranched polyol improved the physicomechanical properties of PER-based transparent IFR coatings. The char formed after burning was also analyzed using FESEM and UTM. Results revealed that phytic acid and HBP combination increased the height as well as strength of the char. Among the prepared transparent IFR coatings, PER-0 and PER-1 have shown higher char height and strength. Note de contenu : - EXPERIMENTAL : Materials - Synthesis and modification of phosphate ester resin (PER) - Preparation of transparent IFR coating - CHARACTERIZATION - RESULTS AND DISCUSSION : Characterization of synthesized resins - Transparency characterization - Physicomechanical properties of the coatings - Characterization of char - Table 1 : Composition of different PER resins - Table 2 : Assignment of the peaks in FTIR spectra of raw materials and the synthesized resins - Table 3 : Physicomechanical properties of the transparent IFR coating - Table 4 : TGA data of the transparent IFR coatings - Table 5 : Fire-retardant properties of transparent IFR coatings DOI : https://doi.org/10.1007/s11998-021-00537-2 En ligne : https://link.springer.com/content/pdf/10.1007/s11998-021-00537-2.pdf Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37284 [article]

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