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Preparation and characteristics of graphene-based polymeric leather fatliquor / Zhenyu Zhang in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CXV, N° 9 (09/2020)
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Titre : Preparation and characteristics of graphene-based polymeric leather fatliquor Type de document : texte imprimé Auteurs : Zhenyu Zhang, Auteur ; Mengjie Cui, Auteur ; Zhonghui Wang, Auteur ; Haojun Fan, Auteur ; Yi Chen, Auteur ; Jun Xiang, Auteur ; Jun Yan, Auteur ; Jixin Ning, Auteur Année de publication : 2020 Article en page(s) : p. 337-346 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Antibactériens
Blindage (électricité)
Caractérisation
Essais (technologie)
Essais de comportement au feu
Oxyde de graphène
Produits de nourriture du cuir
Résistance au rayonnement ultravioletIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : Although the research of leather chemicals has experienced considerable advances, it remains imperative and challenging to develop functional ones ; especially functionalized fatliquors or retanning agents. In consideration with the unique structure and properties, graphene oxide (GO) has been reported as a potential alternative to ameliorate the performance of leather. However, one of the intractable handicaps is how to make graphene penetrate evenly and react with collagen fibers. Here, we demonstrate a method for preparing graphene-based polymeric fatliquor (PFGO) via an amidation reaction between amino-groups of aminated graphene (AGO) and anhydride bonds of maleic anhydride-rapeseed ouf copolymer (MRO), which was synthesized by free radical copolymerization. The results show that the as-prepared fatliquor has good emulsion stability and can penetrate into the collagen fibers uniformly. Compared with the control sample without graphene, the antibacterial, electromagnetic shielding, flame retardant and UV resistance characteristics of the PFGO-treated leather were significantly improved. Overall, this effective yet promising paradigm may provide an achievable solution toward developing graphene-based polymer composites simultaneously with high physical property and high functional performance. Note de contenu : - EXPERIMENTAL : Materials - Synthesis of GO based faltiquor (PFGO) - Fatliquoring process
- CHARACTERIZATION AND PERFORMANCE TESTS : Instrument testing - Stability of fatliquor solution - SEM observation of leather - Antibacterial testing of fatliquor - Electromagnetic radiation shielding. Performance testing of leather - Flammability testing of leather - UV-resistance property testing of leather - Thermal stability testing of leather - Mechanical measurements
- RESULTS AND DISCUSSION : Characterization of AGO - Characterization of fatliquor - Distribution of fatliquor in leather - Antibacterial property of fatliquor - Electromagnetic shielding performance of leather - Flammability of leather - UV-resistance of fatliquored leatherDOI : https://doi.org/10.34314/jalca.v115i9.3849 En ligne : https://drive.google.com/file/d/1v5ccCkackiJzJmgK2tdNNEZKqF3muZUK/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=34587
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