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Exploring the oxidation of chromium(III) to chromium(VI) by unsaturated lipids in leather / Yu Congzheng in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 91, N° 3 (05-06/2007)
[article]
Titre : Exploring the oxidation of chromium(III) to chromium(VI) by unsaturated lipids in leather Type de document : texte imprimé Auteurs : Yu Congzheng, Auteur ; Ma Xingyuan, Auteur ; Liu Pengjie, Auteur ; Sun Genxing, Auteur ; Qian Yiping, Auteur Année de publication : 2007 Article en page(s) : p. 116-122 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Chrome hexavalent
Chrome trivalent -- Oxydation
Composés insaturés
Cuirs et peaux -- Analyse
Huile d'arachide
Lipides
Oléique, AcideL'acide oléique vient du latin oleum et veut dire huile. C'est le plus abondant des acides gras monoinsaturés à chaîne longue dans notre organisme. Sa formule chimique brute est C18H34O2 (ou CH3(CH2)7CH=CH(CH2)7COOH). Son nom IUPAC est acide cis-9-octadécénoïque, et son nom court de lipide est 18:1 cis-9. La forme saturée de cet acide est l'acide stéarique.
On le symbolise par les nombres 18:1 pour indiquer qu'il possède 18 atomes de carbone et une liaison éthylénique. Pour indiquer la position de la double liaison, on préfère indiquer le nombre de carbones entre le dernier carbone (n° 18) et le carbone où commence la double liaison (n° 9), d'où 18 - 9, qu'on écrit n - 9, en désignant par n le nombre de carbones de la chaîne. L'acide oléique est donc un acide gras insaturé, plus précisément monoinsaturé.
La double liaison agit sur la forme de la molécule et des triglycérides qu’elle forme avec le glycérol. Comme la molécule ne peut pas pivoter autour de C = C, la chaîne est beaucoup moins flexible que l’acide stéarique et ne peut pas former de boule. Les molécules des esters de cet acide sont beaucoup moins compactes que la tristéarine: ces sont des huiles.
À la température de notre corps c'est un liquide (huile), qui ne se solidifie qu'à 13,4 °C.Index. décimale : 675.2 Préparation du cuir naturel. Tannage Résumé : This work has broken free from the framework of the traditional leather-making process and taking a new method, has explored the influence of the double bonds of unsaturated lipids on the level of chromium(VI) in chrometanned leather. The following parameters were controlled during the experiment: temperature, humidity, time and the pH. Checking the iodine value and peroxide value of the lipids regularly and determining the structural changes by infrared, the experiment demonstrates the oxidation mechanism of chromium(III) to chromium(VI) by unsaturated lipids in chrome-tanned leather. Note de contenu : - EXPERIMENTAL PROCEDURE : Experimental process and method (the following experiments were carried out simultaneously) - Analysis and Determination
- RESULTS AND DISCUSSION : Results and discussions of different oil systems - Analysis of the oleic acid system by Fourier Transform Infrared (FTIR)
- Table 2 : Results for oleic acid system
- Table 3 : Results for peanut oil system
- Table 4 : Results for oleic acid system
- Table 5 : Cr(VI) contents in control test
- Table 6 : Results of before and after extraction on the 8th day
- Table 7 : Chromium(VI) contents of different systemsEn ligne : https://drive.google.com/file/d/1D_aH5SMQVgoDUQ-BJ3YS0RXik4Ucn6GU/view?usp=share [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=39029
in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC) > Vol. 91, N° 3 (05-06/2007) . - p. 116-122[article]Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire Structure and properties of a novel collagen-soy protein isolate film via self-assembly : a comparative study / Ruirui Wang in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 104, N° 1 (01-02/2020)
[article]
Titre : Structure and properties of a novel collagen-soy protein isolate film via self-assembly : a comparative study Type de document : texte imprimé Auteurs : Ruirui Wang, Auteur ; Hongru Wang, Auteur ; Liu Pengjie, Auteur ; Yijun Yao, Auteur ; Wanli Ji, Auteur Année de publication : 2020 Article en page(s) : p. 25-32 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Collagène
Couches minces
Couches minces -- Propriétés mécaniques
Couches minces -- Propriétés optiques
Couches minces -- Propriétés thermiques
Pansements
Perméabilité
Résistance à l'humidité:Résistance à l'eau
Soja et constituants
Systèmes auto-assemblés
Vapeur d'eauIndex. décimale : 610.72 Recherche médicale : classer la médecine expérimentale à 619 Résumé : A novel collagen-soy protein isolate (SPI) film formed via self-assembly was developed. This research investigated the structure and application properties of the collagen-SPI self-assembled film and the blend film. FTIR and XRD evaluation of structural properties indicated that the self-assembly method could effectively enhance the compatibility between collagen and SPI. The collagen-SPI self-assembled film presented a compact, smooth and continuous microstructure. The tensile strength (Ts) and elongation at break (EAB) values of the collagen-SPI self-assembled films (Ts : 13.991 ±0.53 MPa, EAB : 84.57 ± 6.21%) were nearly twice those of the blend films. The water vapour permeability (WVP) values of the collagen-SPI self-assembled film were more than 2000 g•m-2.24h. The maximum decomposition peak of collagen-SPI self-assembled films was located at 313.2°C. The collagen-SPI self-assembled films could achieve swelling equilibrium quickly within 2 hours, and the structural integrity of the film was maintained for 24 hours. The collagen-SPI self-assembled film had excellent ultraviolet shielding and visible light transmission qualities. The collagen-SPI self-assembled film had better mechanical properties, optical properties, thermal stability and water resistance properties as opposed to blend film. As a clean and feasible method, the self-assembly method could improve the functional properties of the collagen-SPI film. The collagen-SPI self-assembled films could be used as novel wound dressings in the future./ Note de contenu : - EXPERIMENTAL SECTIONS : Materials - Preparation of the collagen-SPI self-assembled film - Preparation of the collagen-SPI blend fim - Characterisation of the collagen-SPI films
- RESULTS AND DISCUSSION : Microstructure of the collagen-SPI micelles formed via self-assembly - FTIR spectra of the collagen-SPI film - X-ray diffraction (XRD) of the collagen-SPI self-assembled film - Scanning electron microscopy (SEM) of the collagen-SPI film - Mechanical properties of the collagen-SPI film - Water vapour permeability (WVP) of the collagen-SPI film - Thermal stability of the collagen-SPI film - Optical properties of the collagen-SPI self-assembled film - Water resistance of the collagen-SPI filmEn ligne : https://drive.google.com/file/d/1Lcp-coMg2d9TLJASa1DefKNz4mUx3O8T/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=33540
in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC) > Vol. 104, N° 1 (01-02/2020) . - p. 25-32[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 21508 - Périodique Bibliothèque principale Documentaires Disponible The influence of relative humidity on the level of Cr(VI) in level of Cr(VI) in chrome-tanned leather / Yu Congzheng in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 89, N° 5 (09-10/2005)
[article]
Titre : The influence of relative humidity on the level of Cr(VI) in level of Cr(VI) in chrome-tanned leather Type de document : texte imprimé Auteurs : Yu Congzheng, Auteur ; Liu Pengjie, Auteur ; Sun Genxing, Auteur ; Duan Liming, Auteur ; Ren Huijun, Auteur Année de publication : 2005 Article en page(s) : p. 194-198 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Air -- Humidité
Cuir -- Teneur en chrome hexavalent
Cuirs et peaux -- Analyse
pHIndex. décimale : 675.2 Préparation du cuir naturel. Tannage Résumé : The influence of relative humidity of the environment on the level of Cr(VI) in chrome-tanned leather was studied. The experiments were carried out as follows : a leather sample was cut into pieces which were stored in different relative humidities followed by determination of Cr(VI). Subsequently, these same pieces were stored at different relative humidities followed by re-determination of the Cr(VI) levels. To confirm the influence of relative humidity, pieces of leather soaked in dichromate solution were dried and then subjected to similar treatment as was given to the earlier leather samples. The results showed that there is a close relationship between the stored humidity and Cr(VI) levels in leather. The higher the relative humidity, the lower the level of Cr(VI) and vice versa. Note de contenu : - EXPERIMENTAL PROCEDURE : Experimental scheme - Determination of the iodine value of the fatliquor (GB5532-85) - Determination of Cr(VI) level in leather according to IU C- 18 standard of the IULTCS - comparing influences of pH value and humidity on chrome (VI) level in leather - Influence of different humidities on the Cr(VI) content in leather - Influence of humidity reversed adjustment on Cr(VI) content in leather - Intensifying treatment of leather samples
- RESULTS AND DISCUSSION : Determination of the iodine value of different fatliquors and the corresponding Cr(VI) contents in leather - Determination of pH values of the stored leathers in different humidities - Cr(VI) content in leather stored at different humidity - Influence of humidity reversed adjustment on Cr(VI) content in leather - Intensifying experiment on different humidity of leathers and different Cr(VI) solutionsEn ligne : https://drive.google.com/file/d/1LnO09Mpg3he-RIIhOwtrlOmyIWRBMVux/view?usp=share [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=39229
in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC) > Vol. 89, N° 5 (09-10/2005) . - p. 194-198[article]Exemplaires
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