Titre : |
Study on the thermal stability and smoke suppressant effect of polyurethane foam modified by ammonium lignosulfonate |
Type de document : |
texte imprimé |
Auteurs : |
Xu Zhang, Auteur ; Dehe Yuan, Auteur ; Simiao Sun, Auteur ; Zhi Wang, Auteur ; Hua Xie, Auteur ; Zhanpeng Su, Auteur |
Année de publication : |
2024 |
Article en page(s) : |
p. 15-31 |
Note générale : |
Bibliogr. |
Langues : |
Anglais (eng) |
Catégories : |
Anti-fumée Lignosulfonate d'ammonium Mousses plastiques Polyuréthanes Stabilité thermique
|
Index. décimale : |
668.4 Plastiques, vinyles |
Résumé : |
The modified polyurethane foam (PUF) with ammonium lignosulfonate was prepared by one-step water foaming method. The effects of ammonium lignosulfonate on its thermal stability and smoke suppression were investigated by thermogravimetric analysis, pyrolysis kinetics analysis, smoke density (Ds) and smoke toxicity analysis. The results showed that the addition of 15 % ammonium lignosulfonate (PUFA15) had the lowest mass loss of PUFs and the highest integral programmed decomposition temperature (870.8 °C). Its activation energy was the highest according to the Flynn-Wall-Ozawa method (110.1 kJ/mol), Kissinger method (181.1 kJ/mol), Starnk method (106.3 kJ/mol) and Coats-Redfern method (149.7 kJ/mol). In addition, PUFA15 had the lowest Ds (34.43) and the highest transmittance (66.74). This indicated that PUFA15 had good thermal stability and smoke suppression properties. The research results had a reference value for exploring the production of environmentally friendly PUF by biomass modification. |
Note de contenu : |
- EXPERIMENTAL : Materials - Preparation of the polyols - Preparation of the PUFs - Measurements and characterization
- RESULTS AND DISCUSSION : Thermal weight loss analysis - IPDT analysis - Pyrolysis kinetics analysis - Smoke density - Smoke toxicity - Flame retardant mechanism |
DOI : |
https://doi.org/10.1515/ipp-2023-4378 |
En ligne : |
https://drive.google.com/file/d/1G1OWeYMO1PLKRSho4tCXWx7CWpYLEEJW/view?usp=drive [...] |
Format de la ressource électronique : |
Pdf |
Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=40848 |
in INTERNATIONAL POLYMER PROCESSING > Vol. 39, N° 1 (2024) . - p. 15-31