Sucrose octaesters as reactive diluents for alkyd coatings / Andriy Popadyuk in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 15, N° 3 (05/2018)  

[article]  inJOURNAL OF COATINGS TECHNOLOGY AND RESEARCH > Vol. 15, N° 3 (05/2018) . - p. 481-488 Titre : Sucrose octaesters as reactive diluents for alkyd coatings Type de document : texte imprimé Auteurs : Andriy Popadyuk, Auteur ; Austin Breuer, Auteur ; James Bahr, Auteur ; Ihor Tarnavchyk, Auteur ; Andriy Voronov, Auteur ; Bret J. Chisholm, Auteur Année de publication : 2018 Article en page(s) : p. 481-488 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Diluants Haut extrait sec Polyalkydes Revêtements Tags : 'Diluant  réactif'  'Revêtement  alkyde'  'Sucrose  polyester'  de  soja'  'Ester  d'acide  gras  saccharose'  'Haute  teneur  en  solides' Index. décimale : 667.9 Revêtements et enduits Résumé : Sucrose octasoyate (SS8) was investigated as a reactive diluent for a medium oil alkyd (MOA). SS8, which is derived from sugar and soybean oil, is 100% biobased, nontoxic, and biodegradable. As a result of its unique molecular architecture, it was expected that SS8 would be an excellent reactive diluent for alkyd coatings. The experiment conducted basically involved the incremental replacement of the MOA with SS8, while maintaining essentially equivalent solution viscosity. The properties of cured coatings were determined using industry standard methods. In general, it was found that SS8 could be used to reduce volatile organic compound content of the coatings, while also reducing drying time (i.e., tack-free time), increasing solvent resistance, and increasing impact resistance. Of the properties measured, the only cured film property that was negatively affected by the use of SS8 was the König pendulum hardness. However, the reduction in König pendulum hardness was only observed when the amount of MOA replaced by SS8 was greater than 10 wt%. Overall, these initial results suggest that SS8 is a very good reactive diluent for alkyd coatings. Note de contenu : - Fig. 1 : The chemical structure of a number of molecules that have been described in the literature as potential reactive diluents for alkyd coating - Fig. 2 : representative chemical structure of an SS8 molecule. It should be understood that the chemical structure of the soy-based fatty acid ester molecules around a single sucrose core will vary and the distribution will depend on the fatty acid ester profile of the soybean oil used as a starting material - Fig. 3 : Tack-free time as a function of SS8 content in the coating. Tack-free time was determined according to ASTM D1640 - Fig. 4 : Pendulum hardness as a function of SS8 content for the MOA/SS8 coatings - Fig. 5 : The variation in solvent resistance with SS8 content for the MOA/SS8 coatings - Fig. 6 : Direct impact resistance as a function of SS8 content for the MOA/SS8 coatings - Fig. 7 : The variation in reverse impact resistance with SS8 content for the MOA/SS8 coatings - Fig. 8 : relative comparison of the properties of coatings 90/10 MOA/SS8 and 75/25 MOA/SS8 to coating 100/0 MOA/ SS8. The spider chart shown in this figure was constructed such that the data point farthest from the center along any given axis is given a value of 1.0 and corresponds to the coating that had the most desired value for that property. For example, coating 75/25 MOA/SS8 exhibited the highest solvent resistance, highest direct impact resistance, highest reverse impact resistance, lowest VOC content, and shortest drying time (i.e., tack-free time). As a result, a value of 1.0 was assigned to each of these properties for coating 75/25 MOA/SS8. However, for pendulum hardness, coating 100/0 MOA/SS8 exhibited the highest pendulum hardness, and, thus, a value of 1.0 was assigned to this coating on the hardness axis. The other two data points on each axis represent the magnitude of the property for the other two coatings as a fraction relative to the coating with the most desirable value for the property - Table 1 : A description of the raw materials used for the study - Table 2 : Compositions of the coating solutions produced - Table 3 : The coating properties measured and the ASTM methods used to test them - Table 4 : The solids and VOC content of the coating solutions produced and the biobased content of the cured films derived from the coating solutions - Table 5 : Drying/curing characteristics of the coatings as determined using ASTM D1640 DOI : 10.1007/s11998-017-0016-5 En ligne : https://link.springer.com/content/pdf/10.1007%2Fs11998-017-0016-5.pdf Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=30744 [article]

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