Aliphatic anionic polyurethane microemulsion leather filling-retanning agent / Bao Lihong in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 91, N° 2 (03-04/2007)  

[article]  inJOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC) > Vol. 91, N° 2 (03-04/2007) . - p. 73-80 Titre : Aliphatic anionic polyurethane microemulsion leather filling-retanning agent Type de document : texte imprimé Auteurs : Bao Lihong, Auteur ; Lan Yunjun, Auteur ; Shufen Zhang, Auteur Année de publication : 2007 Article en page(s) : p. 73-80 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Agents de tannage Caractérisation Charges (matériaux) Chimie analytique Cuirs et peaux -- Propriétés mécaniques Cuirs et peaux -- Propriétés organoleptiques Cuirs et peaux -- Propriétés physiques Formulation (Génie chimique) Imperméabilisation Microémulsions Poids moléculaires Polymères aliphatiques Polyuréthanes Retannage Index. décimale : 675.2 Préparation du cuir naturel. Tannage Résumé : The retanning process plays an important role in optimizing the leather’s colour, levelness, softness, fullness, and hydrophobicity. Polymer retanning agents are important materials for this process. The present study used maleic anhydride modified castor oil (MCO), PEG1000 (polyethylene glycol) and IPDI (isophorone diisocyanate) as main materials to synthesize polyurethane microemulsions (MC-PURs) and employed them to retan chrometanned leathers. The hydroxyl functionality of MCO was investigated by chemical and 1HNMR analysis, and confirmed to be about 2.0. The chemical structures of MCO, prepolymer and MC-PUR were characterized by IR. The optimized synthesis formulation and polyurethane microemulsion MC-PUR3 for MC-PURs as retanning agent was selected by comparing the properties of retanned leathers, such as softness, fullness, grain tightness, tensile strength, extension at break, depth of shade, waterproof properties et al. Then, MC-PUR3 was characterized by means of DSC, TG/DTG and TEM techniques. SEM microgram of MC-PUR3 retanned leather shows that the fibres are well dispersed. Note de contenu : - EXPERIMENTAL PROCEDURES : Materials - Preparation of maleic anhydride modified castor oil (MCO) - Preparation of microemulsions of polyurethane filling retanning agents (MC-PURs) - Determination of molecular weight - H n.m.r. spectroscopy - Purification - FT-IR spectroscopy - Differential scanning spectroscopy - Thermo-gravimetric analysis - Transmission electron microscope analysis - Measurement of final dyebath exhaustion - Physical and waterproofness properties of leathers - Organoleptic properties of the final leathers - Scanning electron microscopic analysis - RESULTS AND DISCUSSION : Determination of the average molecular weight, hydroxyl number and average hydroxyl functionality (Fn(OH)) of MCO - Determination of the average hydroxyl functionality of MCO by chemical analysis - Determination of the average hydroxyl functionality of MCO by 1HNMR - Chemical structure analysis by IR - OPTIMIZATION OF RETANNING AGENT : Effect of MCO/PEG1000 mass ratio on the properties of retanned leathers - Effect of carboxyl content of MC-PUR on the properties of retanned leathers - Effect of NCO/OH molar ratio on the properties of retanned leathers - Thermal properties of MC-PUR3 - Table 1 : Basic formulations of MC-PURs - Table 2 : Filling, retanning and wet finishing processes - Table 3 : Effect of MCO/PEG1000 mass ratio on the properties of retanned leathers - Table 4 : Effect of carboxyl content of MC-PUR on the properties of retanned leathers - Table 5 : Effect of NCO/OH molar ratio on the properties of retanned leathers En ligne : https://drive.google.com/file/d/19ti2BicD3kfHFF4Z4QLX1cSWPC0J39gs/view?usp=share [...] Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=39037 [article]

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Low-water-soluble reactive dyes for application in ultrafine polyamide/polyurethane synthetic leather / Dexiang Li in COLORATION TECHNOLOGY, Vol. 140, N° 2 (04/2024)  

[article]  inCOLORATION TECHNOLOGY > Vol. 140, N° 2 (04/2024) . - p. 252-261 Titre : Low-water-soluble reactive dyes for application in ultrafine polyamide/polyurethane synthetic leather Type de document : texte imprimé Auteurs : Dexiang Li, Auteur ; Wei Ma, Auteur ; Bingtao Tang, Auteur ; Shufen Zhang, Auteur Année de publication : 2024 Article en page(s) : p. 252-261 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Colorants réactifs Cuir synthétique Cuirs et peaux -- Teinture Polyamides Un polyamide est un polymère contenant des fonctions amides -C(=O)-NH- résultant d'une réaction de polycondensation entre les fonctions acide carboxylique et amine. Selon la composition de leur chaîne squelettique, les polyamides sont classés en aliphatiques, semi-aromatiques et aromatiques. Selon le type d'unités répétitives, les polyamides peuvent être des homopolymères ou des copolymères. Polyuréthanes Solidité de la couleur Index. décimale : 667.2 Colorants et pigments Résumé : Ultrafine polyamide/polyurethane synthetic leather (UP/PSL), with a highly natural leather-like appearance and touch, is widely used in many leather commodities. Generally, acid dyes, which are mostly used for dyeing UP/PSL, exhibit poor colour fastness. While, reactive dyes are well-known for their good colour fastness. However, reactive dyes are not used to dye UP/PSL because they are water-soluble and cannot stain the polyurethane (PU) in UP/PSL. In this study, five low water-soluble reactive dyes with good affinity for both polyamide (PA) and PU were synthesised and characterised using ultraviolet-visible and infrared spectroscopy, and mass spectrometry. All low-water-soluble reactive dyes were monoazo dyes with only one sulfonic group and two different functional groups. The reactive dyes were used to dye UP/PSL at 98°C and fixed at 90°C with 7-azatridecane-1,13-diamine as a crosslinking agent. For comparison, Eriofast Red-2B (ER-2B) was used to dye UP/PSL using a special dyeing procedure. ER-2B showed severe issues related to low utilisation and uneven dyeing, whereas the five low water-soluble reactive dyes exhibited better performance than ER-2B. Both the exhaustion and fixation of dyes 1 and 4 exceeded 90.0% when the dosage was less than 3.0% owf (on weight of fabric). In addition, they exhibited good levelling. The washing fastness of the five reactive dyes was excellent and higher than grade 4. The dry rubbing fastness was higher than grade 3-4. Therefore, UP/PSL can be satisfactorily dyed using the reactive dyes with a solubility of less than 1.0 g/L and meet the requirements of daily life applications. Note de contenu : - MATERIALS AND METHODS : Chemicals and instruments - Preparation of reactive dyes with low solubilities - Dyeing process - Measurements of colour strength and fastness - Dyeing results of PU in UP/PSL with low water-soluble reactive dyes and ER-2B - RESULTS AND DISCUSSION : Structures and UV-vis absorption spectra of the low water-soluble reactive dyes - Results of dyeing UP/PSL with low water-soluble reactive dyes - Colour fastness of UP/PSL dyed with five low water-soluble reactive dyes DOI : https://doi.org/10.1111/cote.12692 En ligne : https://drive.google.com/file/d/10-sAJ3RcR8wrRTGti-sf8xWLZ9y5Ww0i/view?usp=drive [...] Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=40941 [article]

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Studies on dyeing method and dyeing properties of a sulphur black dye containing carboxylic acid groups on cotton / Jinqiu Xiao in COLORATION TECHNOLOGY, Vol. 123, N° 3 (2007)  

[article]  inCOLORATION TECHNOLOGY > Vol. 123, N° 3 (2007) . - p. 191-196 Titre : Studies on dyeing method and dyeing properties of a sulphur black dye containing carboxylic acid groups on cotton Type de document : texte imprimé Auteurs : Jinqiu Xiao, Auteur ; Shufen Zhang, Auteur ; Jinzong Yang, Auteur Année de publication : 2007 Article en page(s) : p. 191-196 Note générale : Bibliogr. Langues : Anglais (eng) Index. décimale : 667.3 Teinture et impression des tissus Résumé : In this study the dyeing method of a sulphur black dye containing carboxylic acid groups on cotton was investigated. A dip–pad–bake dyeing process was applied and dyeing conditions were examined in detail. Thermal gravimetric analysis was used to determine both the baking temperature and the dehydrant selection. Fastness properties of the sulphur black dye containing carboxylic acid groups were tested. It is concluded that the sulphur black dye not only has good dyeing performance, but also possesses good fastness properties. DOI : 10.1111/j.1478-4408.2007.00081.x En ligne : http://onlinelibrary.wiley.com/doi/10.1111/j.1478-4408.2007.00081.x/pdf Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=3543 [article]

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Syntheses and dyeing properties of novel water-soluble reactive sulphur black dyes / Zhengyang Gao in COLORATION TECHNOLOGY, Vol. 140, N° 3 (06/2024)  

[article]  inCOLORATION TECHNOLOGY > Vol. 140, N° 3 (06/2024) . - p. 403-411 Titre : Syntheses and dyeing properties of novel water-soluble reactive sulphur black dyes Type de document : texte imprimé Auteurs : Zhengyang Gao, Auteur ; Wei Ma, Auteur ; Bingtao Tang, Auteur ; Shufen Zhang, Auteur Année de publication : 2024 Article en page(s) : p. 403-411 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Caractérisation Colorants -- Propriétés tinctoriales Colorants -- Synthèse Colorants réactifs Coton Le coton est une fibre végétale qui entoure les graines des cotonniers "véritables"(Gossypium sp.), un arbuste de la famille des Malvacées. Cette fibre est généralement transformée en fil qui est tissé pour fabriquer des tissus. Le coton est la plus importante des fibres naturelles produites dans le monde. Depuis le XIXe siècle, il constitue, grâce aux progrès de l'industrialisation et de l'agronomie, la première fibre textile du monde (près de la moitié de la consommation mondiale de fibres textiles). Essais (technologie) Noir (couleur) Soufre Teinture -- Fibres textiles Teinture au tampon Index. décimale : 667.2 Colorants et pigments Résumé : The practical application of a sulphur black dye relies on its ability to dye cotton fibres with pure black colour and maintain the colour with high light fastness. Here, we report a synthesis method to prepare a novel water-soluble reactive sulphur black dye. The approach involves the reduction of CI Sulphur Black 1 to its leuco form and subsequent reaction with a water-soluble intermediate containing reactive groups synthesised from amino acid and cyanuric chloride. The optimal carboxyl and reactive group content of the water-soluble reactive sulphur black dye is 141 mmol/100 g, and the water solubility can reach 92 g/L. The fixation of the reactive sulphur black dye on cotton reaches 89% in a pad dyeing process without using sodium sulphate. The reactive sulphur black dye can achieve a light fastness of grade 6-7, a dry rub fastness of grade 4 and a wet rub fastness of grade 2, comparable or higher than the conventional CI Sulphur Black 1. The dyeing results showed that the novel water-soluble reactive sulphur black dye has excellent performance and good application prospects. Note de contenu : - EXPERIMENTAL : Reagents and instruments - Synthesis of water-soluble reactive sulphur black dyes - Characterisation of water-soluble reactive sulphur black dye - Dyeing process - Dye fixation of the pad dyeing process - Test method for colour and fastness - RESULTS AND DISCUSSION : Synthesis of water-soluble reactive sulphur black dyes - Dyeing performance of the water-soluble reactive sulphur black dyes DOI : https://doi.org/10.1111/cote.12707 En ligne : https://drive.google.com/file/d/1vIZmqXIP5wThqrDeaw_qioiLZRiyMjca/view?usp=drive [...] Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=40958 [article]

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Synthesis and application of KM-type reactive dyes containing 2-ethoxy-4-chloro-s-triazine / Qiushui Zhang in COLORATION TECHNOLOGY, Vol. 135, N° 5 (10/2019)  

[article]  inCOLORATION TECHNOLOGY > Vol. 135, N° 5 (10/2019) . - p. 335-348 Titre : Synthesis and application of KM-type reactive dyes containing 2-ethoxy-4-chloro-s-triazine Type de document : texte imprimé Auteurs : Qiushui Zhang, Auteur ; Wei Xiong, Auteur ; Shufen Zhang, Auteur ; Ma Wei, Auteur ; Bingtao Tang, Auteur Année de publication : 2019 Article en page(s) : p. 335-348 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Etalonnage Fixation (chimie) Hydrolyse Photostabilité Résistance au nettoyage Solubilité Teinture -- Fibres textiles Index. décimale : 667.3 Teinture et impression des tissus Résumé : A new kind of hetero-bifunctional reactive dye containing 2-ethoxy-4-chloro-s-triazine, with better activity matching with β-hydroxyethyl sulphone sulphate at a low fixation temperature, was successfully synthesised and characterised. An ethoxy group was designed to be introduced into triazine to increase the substantivity and the reactivity of the dyes. Thereby, the fixation of mono-s-chlorotriazine/hydroxyethyl sulphone sulphate (KM-type) bifunctional reactive dyes on cotton was improved, and dyeing under mild conditions with high fixation was realised. Nineteen dyes with orange, red and blue colours were synthesised and characterised by UV-Vis and infrared spectroscopy and mass spectrometry. Synthesised dyes were dyed at 60, 75 and 90°C, respectively. Exhaustion and reactivity for all of the ethoxy-containing KM-type dyes was over 90% at the optimal temperature, and fixation was over 87%, which was higher than the ethoxy-free comparative dyes. The optimal fixation temperature of ethoxy-containing dyes was initially reduced to 75°C, and then to 60°C. Compared with comparative dyes, the wash fastness and light fastness were basically unchanged, and the wet rub fastness of the H-acid series was reduced by one grade. Note de contenu : - EXPERIMENTAL : Materials - Synthesis of dyes - Determination of standard curve and solubility - Study of hydrolysis reaction kinetics - Dyeing and fixing process - Measurements - RESULTS AND DISCUSSION : Synthesis and spectral properties of the dyes - Structure of dye intermediates - Structures and UV-Vis absorption spectra of KM-type reactive dyes - Determination of the hydrolysis reaction rate constant - Syeing results of KM-type and K-type reactive dyes - J-acid monoazo series reactive dyes - γ-acid monoazo series reactive dyes - H-acid series reactive dyes - Colour fastness properties of KM-type reactive dyes DOI : 10.1111/cote.12424 En ligne : https://onlinelibrary.wiley.com/doi/epdf/10.1111/cote.12424 Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=33066 [article]

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Synthesis and application of a novel, triphendioxazine-based, phosphorus-containing acid dye for wool / Jinhai Cui in COLORATION TECHNOLOGY, Vol. 134, N° 5 (10/2018)  

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Synthesis and application of yellow azo-anthraquinone disperse dyes for polylactide fibres / Liang He in COLORATION TECHNOLOGY, Vol. 126, N° 2 (2010)

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Synthesis and dyeing properties of polyvinylamine dyes for cotton / Bin Shan in COLORATION TECHNOLOGY, Vol. 136, N° 3 (06/2020)  

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Synthesis and properties of poly(styrene-co-maleic acid) macromolecular reactive dyes / Fuchun Wang in COLORATION TECHNOLOGY, Vol. 139, N° 1 (02/2023)  

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Textile applications of photochromic dyes. Part 5 : application of commercial photochromic dyes to polyester fabric by a solvent-based dyeing method / Yong Deng in COLORATION TECHNOLOGY, Vol. 129, N° 2 (04/2013)  

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