Titre : |
Thermal properties of intumescent coating with waterborne melamine-acrylic emulsion resin for plywood |
Type de document : |
texte imprimé |
Auteurs : |
Chih-Shen Chuang, Auteur ; Po-Heng Lin, Auteur |
Année de publication : |
2023 |
Article en page(s) : |
p. 1193-1205 |
Note générale : |
Bibliogr. |
Langues : |
Américain (ame) |
Catégories : |
Copolymère mélamine-formaldéhyde Intumescence (chimie) Polyacryliques Résonance magnétique nucléaire Revêtements -- Propriétés thermiques Revêtements en phase aqueuse Revêtements organiques Thermocinétique
|
Index. décimale : |
667.9 Revêtements et enduits |
Résumé : |
A mixture of etherified melamine–formaldehyde and acrylic emulsion resin was designed, with the hybrid resin improving the fire retardancy of indoor plywood as well as the CO and CO2 emissions. The water-based hybrid resin exhibited a single curing peak; the need for solvents was reduced. Compared with pure etherified melamine–formaldehyde resin, the hybrid resin had better flame retardancy and produced less pollution. Scanning electron microscopy and cone calorimetry were conducted, and the analyses revealed that lower binder resin concentrations resulted in improved flame retardancy and better char layer formation. When the binder resin concentrations were increased and CO/CO2 emissions were continued beyond 300 s, the flame retardancy of the intumescent coating was the same as that of the lower binding resin concentrations. Furthermore, the chemical structure and durability of the phosphocarbonaceous structure were verified through Fourier transform infrared spectroscopy and solid-state nuclear magnetic resonance analyses. |
Note de contenu : |
- EXPERIMENT :
- Materials
- Preparation of water-based melamine acrylic resin and intumescent coating
- Thermal property analysis of resin and coating film
- Cone calorimeter test
- Analysis of chemical properties of coating film (Fourier-transform infrared spectroscopy and 31 P solid-state nuclear magnetic resonance test)
- RESULTS AND DISCUSSION :
- Thermal properties of melamine/acrylic hybrid resin
- Analysis of FR of intumescent coatings
- TGA of intumescent coatings
- CO and CO 2 emissions
- Fourier transform infrared analysis
- P solid state NMR analysis
- Table 1 : Basic information of the material
- Table 2 : Different formulations of intumescent fire-retardant paint in solid weight ratio (w/w)
- Table 3 : The different compositions coatings of cone calorimeter experiments |
DOI : |
https://doi.org/10.1007/s11998-023-00736-5 |
En ligne : |
https://link.springer.com/content/pdf/10.1007/s11998-023-00736-5.pdf?pdf=button% [...] |
Format de la ressource électronique : |
Pdf |
Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=39710 |
in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH > Vol. 20, N° 4 (07/2023) . - p. 1193-1205