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Fabrication and characterization of polysiloxane/polyacrylate composite latexes with balanced water vapor permeability and mechanical properties: effect of silane coupling agent / Jie Shen in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 15, N° 1 (01/2018)
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Titre : Fabrication and characterization of polysiloxane/polyacrylate composite latexes with balanced water vapor permeability and mechanical properties: effect of silane coupling agent Type de document : texte imprimé Auteurs : Jie Shen, Auteur ; Yang Hu, Auteur ; Ling-Xiao Li, Auteur ; Jian-Wu Sun, Auteur ; Cheng-You Kan, Auteur Année de publication : 2018 Article en page(s) : p. 165-173 Note générale : Bibliogr. Langues : Américain (ame) Index. décimale : 667.9 Revêtements et enduits Résumé : In order to improve the water vapor permeability and mechanical properties of latex films, polysiloxane/polyacrylate (PSi/PA) composite latexes were fabricated via seeded emulsion polymerization of methyl methacrylate and butyl acrylate onto PSi latex particles, and the effects of the silane coupling agent 3-methacryloyloxypropyl trimethoxysilane (MATS) on the morphologies of the latex particles and films, as well as the microphase separation degree, the water vapor permeability and the mechanical properties of the latex films were investigated. Results indicated that MATS was essential for obtaining the PSi/PA composite latex particles with PSi as core and PA as shell and made a great contribution to restrict the phase separation. The PSi/PA core/shell latex films showed similar tensile strength and elongation with pure PA film, while exhibiting promising water vapor permeability. It was found that the influences of MATS content on the water vapor permeability and mechanical properties were opposite, and on the premise of the requirements for mechanical properties, lower MATS content could provide the PSi/PA core/shell latex films with better water vapor permeability. Note de contenu : - MATERIALS AND METHODS : Materials - Latex preparation - Characterization
- RESULTS AND DISCUSSION : Preparation and colloid property of the latexes - Effect of MATS on the particle morphology - Effects of MATS on the phase structure of the latex films - Effect of MATS on the water vapor permeability - Effect of MATS on the mechanical propertiesDOI : 10.1007/s11998-017-9970-1 En ligne : https://link.springer.com/content/pdf/10.1007%2Fs11998-017-9970-1.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=30109
in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH > Vol. 15, N° 1 (01/2018) . - p. 165-173[article]Réservation
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