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Identifying variations in cross-linked epoxies / Kiersten M. Smith in ADHESION - ADHESIVES + SEALANTS, Vol. 19, N° 3/2022 (2022)
[article]
Titre : Identifying variations in cross-linked epoxies Type de document : texte imprimé Auteurs : Kiersten M. Smith, Auteur ; Thomas D. Lazzara, Auteur ; Raymond H. Fernando, Auteur Année de publication : 2022 Article en page(s) : p. 18-22 Langues : Multilingue (mul) Catégories : Adhésifs -- Propriétés mécaniques
Adhésifs -- Propriétés thermiques
Analyse mécanique dynamique
Epoxydes
Humidité -- Absorption
Réticulation (polymérisation)Index. décimale : 668.3 Adhésifs et produits semblables Résumé : The thermal and mechanical properties of an epoxy resin are derived from the structure and chemistry of its cross-linked network. Dynamic mechanical analysis can be used to measure transition temperatures of epoxies, including the primary transition : the glass transition temperature. Secondary transitions can provide additional insights into the structure property of epoxies. Note de contenu : - Materials and methods
- Thermomechanical evaluation of an epoxy
- Epoxy transition temperatures measured by DMA
- Effect of temperature on primary and secondary transitions
- Reversible solvent absorption
- Table 1 : Some commercially available epoxies tested (purchased at online retailer in pre-packaged cartridges or small bottle products)
- Fig. 1 : Thermomechanical analysis of a type A (left) and B epoxies (right). Type B epoxies have secondary transitions
- Fig. 2 : Type B epoxies have secondary transitions, which are apparent when applying peak deconvolution techniques (Igor Pro software used for data processing)
- Fig. 3 : The type A epoxy (ID5, Table 1) was mixed at different ratios to demonstrate that the primary transition changes with A:B ratio. Schematic representation of a cross-linked network, from bottome to top : excess part A (resin) to excess part B (hardener)
- Fig. 4 : A type B epoxy was exposed at different temperatures showing that the secondary transition peak eventually merges with the primary transition peak
- Fig. 5 : Epoxies of type A and type B exposed to boiling water for 1 h to evaluate if moisture absorption can be detected by DMA measurementsEn ligne : https://drive.google.com/file/d/10T9KnsKTwYgXKQXugJX-IevwhT9pewis/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=38007
in ADHESION - ADHESIVES + SEALANTS > Vol. 19, N° 3/2022 (2022) . - p. 18-22[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 23512 - Périodique Bibliothèque principale Documentaires Disponible Parameters influencing the spray behavior of waterborne coatings / Lin-lin Xing in JOURNAL OF COATINGS TECHNOLOGY (JCT), Vol. 71, N° 890 (03/1999)
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Titre : Parameters influencing the spray behavior of waterborne coatings Type de document : texte imprimé Auteurs : Lin-lin Xing, Auteur ; J. Edward Glass, Auteur ; Raymond H. Fernando, Auteur Année de publication : 1999 Article en page(s) : p. 37-50 Note générale : bibliogr. Langues : Américain (ame) Catégories : Cisaillement (mécanique)
Dépôt par pulvérisation
Gouttelettes
Latex
Revêtements en phase aqueuse:Peinture en phase aqueuse
Rhéologie
Système de pulvérisation (technologie)
ViscositéIndex. décimale : 667.9 Revêtements et enduits Résumé : The influence of liquid pressures and orifice diameters on the sprayability of non-Newtonian, waterborne latex coatings, that vary in latex particle size and thickener composition are examined in this study. It is observed that the higher the dynamic uniaxial extensional viscosities (DUEVs, ηe) of the coatings, the larger the Sauter mean diameters (SMDs) of the spray droplets and the broader the droplet size distributions. The shear viscosities at high shear rates and the parameter reflecting shear elasticity, the storage moduli, at low deformation rates do not correlate with the droplet sizes and the distributions observed. In addition to these observations, the Sauter mean diameters of spray droplets decrease with increasing spray pressures and with decreasing orifice diameters; however, with increasing pressures, pulsations in the fluid due to turbulence create areas of high and low droplet density.The relationship of the SMD to orifice diameters using fan nozzles is defined by the relationship:[FORMULA]The experimental results associated with each of these parameters are discussed in the text. Note de contenu : - EXPERIMENTAL SECTION : Formulation of latex coatings - Airless spray process - Measurement of droplet size and their distribution in spray coatings - Rheology measurements
- RESULTS AND DISCUSSION : The effect of orifice diameters on SMDs of spray droplets - Derivation of parameter dependent equation for latex coatings sprayed by airless equipment through fan nozzlesPermalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=18025
in JOURNAL OF COATINGS TECHNOLOGY (JCT) > Vol. 71, N° 890 (03/1999) . - p. 37-50[article]Exemplaires (1)
Code-barres Cote Support Localisation Section Disponibilité 009604 - Périodique Bibliothèque principale Documentaires Exclu du prêt Scratch behavior of nano-alumina/polyurethane coatings / Li-Piin Sung in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 5, N° 4 (12/2008)
[article]
Titre : Scratch behavior of nano-alumina/polyurethane coatings Type de document : texte imprimé Auteurs : Li-Piin Sung, Auteur ; Bryce R. Floryancic, Auteur ; Aaron M. Forster, Auteur ; Jeffrey Comer, Auteur ; Hu Haiqing, Auteur ; Lucas J. Brickweg, Auteur ; Raymond H. Fernando, Auteur Année de publication : 2008 Article en page(s) : p. 419-430 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Alumine
Microscopie confocale
Nanoparticules
Polyuréthanes
Résistance à l'abrasion
Revêtements -- Propriétés mécaniques:Peinture -- Propriétés mécaniques
SiliceLa silice est la forme naturelle du dioxyde de silicium (SiO2) qui entre dans la composition de nombreux minéraux.
La silice existe à l'état libre sous différentes formes cristallines ou amorphes et à l'état combiné dans les silicates, les groupes SiO2 étant alors liés à d'autres atomes (Al : Aluminium, Fe : Fer, Mg : Magnésium, Ca : Calcium, Na : Sodium, K : Potassium...).
Les silicates sont les constituants principaux du manteau et de l'écorce terrestre. La silice libre est également très abondante dans la nature, sous forme de quartz, de calcédoine et de terre de diatomée. La silice représente 60,6 % de la masse de la croûte terrestre continentale.
Surfaces -- Analyse
Transition vitreuseIndex. décimale : 667.9 Revêtements et enduits Résumé : Incorporating metal-oxide nanoparticles such as nano-alumina and nano-silica into polymer coatings to enhance mechanical durability is widely utilized in the current antiscratch and mar technologies. In this article, a quantitative study of the effect of a nano-alumina additive on the surface mechanical properties and scratch behavior of a two-part polyurethane coating is reported. An instrumented indenter with a conical diamond tip is used to measure surface mechanical properties (modulus and hardness) and to perform scratch tests, over a wide range of scratch loads. The scratch behavior in terms of the onset of elastic–plastic transition and scratch morphology were characterized by laser scanning confocal microscopy. The scratch results were correlated to the surface mechanical properties and relevant bulk material properties to understand the overall scratch behavior of the coatings. The results show that the scratch behavior of the coatings depends strongly on the concentration of nano-alumina. DOI : 10.1007/s11998-008-9110-z En ligne : https://link.springer.com/content/pdf/10.1007%2Fs11998-008-9110-z.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=3467
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Code-barres Cote Support Localisation Section Disponibilité 010911 - Périodique Bibliothèque principale Documentaires Disponible Shear-induced 1-D alignment of alumina nanoparticles in coatings / Lucas J. Brickweg in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 4, N° 1 (03/2007)
[article]
Titre : Shear-induced 1-D alignment of alumina nanoparticles in coatings Type de document : texte imprimé Auteurs : Lucas J. Brickweg, Auteur ; Bryce R. Floryancic, Auteur ; Erik D. Sapper, Auteur ; Raymond H. Fernando, Auteur Année de publication : 2007 Article en page(s) : p. 107-110 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Alumine
Matériaux hybrides
Nanoparticules
Nanotechnologie
Polyuréthanes
SiliceLa silice est la forme naturelle du dioxyde de silicium (SiO2) qui entre dans la composition de nombreux minéraux.
La silice existe à l'état libre sous différentes formes cristallines ou amorphes et à l'état combiné dans les silicates, les groupes SiO2 étant alors liés à d'autres atomes (Al : Aluminium, Fe : Fer, Mg : Magnésium, Ca : Calcium, Na : Sodium, K : Potassium...).
Les silicates sont les constituants principaux du manteau et de l'écorce terrestre. La silice libre est également très abondante dans la nature, sous forme de quartz, de calcédoine et de terre de diatomée. La silice représente 60,6 % de la masse de la croûte terrestre continentale.
VernisIndex. décimale : 667.9 Revêtements et enduits Résumé : Atomic Force Microscopy and Scanning Electron Microscopy were used to study shear-induced alignment of alumina and silica nanoparticles in two-component polyurethane clear coatings. 1-D strings of nanoparticles, formed in an extended pearl-necklace fashion were observed near the surfaces of cured films at nanoparticle volume fractions less than 0.05. This alignment is affected by the shear conditions of the application method. When applied by spraying, linear particle strings as long as 5 cm were observed in the direction of shear. Nanoparticle strings were also found, to a lesser extent, when coatings were applied by a drawdown method. The phenomenon was not observed in coatings applied with minimal shear. These particle string formations, in addition to affecting the performance of coatings, may have broader implications in the field of nanomaterials. Our literature searches so far have not uncovered reports of stable, 1-D nanoparticle arrangements with same degree of linearity produced under simple shear with compositions having very low particle loadings. DOI : 10.1007/s11998-007-9002-7 En ligne : https://link.springer.com/content/pdf/10.1007%2Fs11998-007-9002-7.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=3676
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Code-barres Cote Support Localisation Section Disponibilité 007149 - Périodique Bibliothèque principale Documentaires Disponible 008267 - Périodique Bibliothèque principale Documentaires Disponible Syneresis and rheology mechanisms of a latex-HEUR associative thickener system / Franceska A. Santos in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 14, N° 1 (01/2017)
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Titre : Syneresis and rheology mechanisms of a latex-HEUR associative thickener system Type de document : texte imprimé Auteurs : Franceska A. Santos, Auteur ; Tyler J. Bell, Auteur ; Alexandra R. Stevenson, Auteur ; Dana J. Christensen, Auteur ; Michaela R. Pfau, Auteur ; Brendan Q. Nghiem, Auteur ; Christopher R. Kasprzak, Auteur ; Travis B. Smith, Auteur ; Raymond H. Fernando, Auteur Année de publication : 2017 Article en page(s) : p. 57-67 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Adsorption
Epaississants
Floculation
Latex
Polyuréthane éthoxylé modifié de façon hydrophobe
Rhéologie
SynérèseEn chimie, la synérèse définit la séparation d'un liquide de son gel.Index. décimale : 667.9 Revêtements et enduits Résumé : This study focuses on the phase behavior, rheology, and interactions of polymer latex particles and a hydrophobically modified ethoxylated urethane (HEUR) associative thickener in water. At constant 0.25 latex particle volume fraction, increasing HEUR caused stable, followed by phase separated (syneresis), and stable mixtures as HEUR concentration increased from 0% to 2.0% (by weight) in the latex-thickener aqueous mixture. The mixtures that underwent syneresis were flocculated. The relationship between the flocculation behavior and the composition of the latex-HEUR mixtures is consistent with previous work reported by other investigators. However, detailed rheological data on systems like these that have undergone syneresis have not been reported. This paper presents detailed viscosity vs shear rate data and correlates viscosity trends with the both flocculation and syneresis behavior. The stable latex-HEUR mixtures at low HEUR levels show Newtonian or shear-thinning viscosity with well-defined low-shear Newtonian plateaus. As HEUR level is increased to levels at which syneresis is observed, erratic rheological profiles with shear thinning as well as thickening are observed. This type of shear thickening has been attributed to bridging flocculation by other investigators. When HEUR level is further increased to levels at which no syneresis is observed, low-shear Newtonian plateaus re-appeared, albeit at higher viscosities. Detailed analysis of syneresis and shear-thickening behavior of a latex-HEUR mixture containing 0.5% (by weight) HEUR showed two shear-thickening regions, one between 0.1 and 0.5 s−1 shear rate range and another between 30 and 100 s−1 shear rate range. Molecular weight distribution (MWD) of the HEUR thickener indicates that the two shear-thickening regions are related to the bi-modal nature of the thickener’s MWD. Note de contenu : - Thickening of aqueous phase
- Adsorption
- Bridging flocculation of dispersed particles
- Depletion flocculation of dipersed particles
- Effect of shear rate on thickening mechanismsDOI : 10.1007/s11998-016-9829-x En ligne : https://link.springer.com/content/pdf/10.1007%2Fs11998-016-9829-x.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=27789
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Code-barres Cote Support Localisation Section Disponibilité 18674 - Périodique Bibliothèque principale Documentaires Disponible The effects of color concentrates on the rheology of tint bases / Douglas J. Herrick in COATINGS TECH, Vol. 10, N° 9 (09/2013)
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