| Titre : |
Redox optimization for emulsion polymer chase to reduce cycle time |
| Type de document : |
texte imprimé |
| Auteurs : |
Philip L. Simer, Auteur ; Jessica Linker, Auteur |
| Année de publication : |
2022 |
| Article en page(s) : |
p. 54-58 |
| Langues : |
Américain (ame) |
| Catégories : |
Essais (technologie)
Oxydoréduction
Polymères en émulsion
Temps de cycle (production) -- Réduction
|
| Index. décimale : |
667.9 Revêtements et enduits |
| Résumé : |
Chemically converting monomer via oxidizing and reducing agents (redox) in post-polymerization is a widely used technique ; however, little time or effort is typically invested in optimizing this step. Through redox optimization, cost savings can be realized via shortened cycle times while also reducing residual free monomer to non-detectable levels.
While temperature and pH play a major role in the kinetics of redox chemistry, these are variables that often cannot be altered. However, improvements can be achieved regardless of these conditions as well as process or equipment restraints. A few of the variables that impact reaction time in the postpolymerization step that can more easily be optimized include redox pair, dosage/concentration, rate, and method of addition. A series of tests were performed to study the impact of these factors. |
| En ligne : |
https://drive.google.com/file/d/1dqgaAbjfHf_v8C8IMTv2U3uBXLq-r2fm/view?usp=drive [...] |
| Format de la ressource électronique : |
Pdf |
| Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37865 |
in COATINGS TECH > Vol. 19, N° 5 (05-06/2022) . - p. 54-58
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Redox optimization for emulsion polymer chase to reduce cycle time in COATINGS TECH, Vol. 19, N° 5 (05-06/2022)
