Titre : |
Highly selective and sensitive colorimetric chemosensor based on tricarboyanine for detection of Ag+ in industrial wastewater |
Type de document : |
texte imprimé |
Auteurs : |
Xiaolong Zeng, Auteur ; Xuezhao Li, Auteur ; Wen Sun, Auteur |
Année de publication : |
2020 |
Article en page(s) : |
11 p. |
Note générale : |
Bibliogr. |
Langues : |
Anglais (eng) |
Catégories : |
Argent Capteurs chimiques Eaux usées -- Analyse Fluorescence Ions Ions métalliques
|
Index. décimale : |
631.7 Conservation des eaux |
Résumé : |
An efficient fluorescent probe 1 based on tricarbocyanine derivative was designed and synthesized, which can detect Ag+ in real industrial wastewater. UV-Vis absorption and fluorescent emission spectra of probe 1 were carried out and indicated this probe can bind Ag+ via complexation reaction, then leading to a remarkable color change from blue to light red. Furthermore, probe 1 showed high sensitive performance and excellent selectivity toward Ag+ over other common metal ions in neutral pH. The sensing mechanism was proposed and further confirmed by 1H NMR, which demonstrate analyte-induced destruction of the π-electron system could be shorten by the disruption of the pull-push π-conjugation system in probe 1. Moreover, a test strip was prepared by filter paper immersing in probe 1 solution, which further provide its potential application for trace Ag+ detection in real industrial wastewater. |
Note de contenu : |
- EXPERIMENTAL METHODS : Materials and reagents - Instrumentations - Synthesis - Measurement method
- RESULTS AND DISCUSSION : Construction and characterization of intermediate and probe 1 - Fluorescence and UV-Vis spectral response of probe 1 to Ag+ - The selectivity to various metal ion as well as common anion and pH effect of probe 1 - Investigation of binding mechanism - Preliminary application for preparing test strips and applicability for real wastewater samples
- Table 1 : Determination of Ag+ from real wastewater samples |
DOI : |
https://doi.org/10.1186/s42825-020-00031-2 |
En ligne : |
https://link.springer.com/content/pdf/10.1186/s42825-020-00031-2.pdf |
Format de la ressource électronique : |
Pdf |
Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37450 |
in JOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 2 (Année 2020) . - 11 p.