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Biotechnological routes towards bio-based surfactants : state of the art and future challenges / Ulrich Schörken in SOFW JOURNAL, Vol. 143, N° 5 (05/2017)
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Titre : Biotechnological routes towards bio-based surfactants : state of the art and future challenges Type de document : texte imprimé Auteurs : Ulrich Schörken, Auteur ; Stéphan Barbe, Auteur ; Thomas Hahn, Auteur ; Susanne Zibek, Auteur Année de publication : 2017 Article en page(s) : p. 18-30 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Biocatalyse
Biosurfactants
Biotechnologie
Chimie écologique
Composés organiques -- Synthèse
Lipides
Microbiologie industrielleIndex. décimale : 668.5 Parfums et cosmétiques Résumé : Bio-based surfactants and biosurfactants on the basis of renewable resources are green alternatives for the cosmetic and detergent industry. Consumer trends towards sustainability and the need for CO2, reduction to achieve future climate goals wifl certainly increase interest in these bio-based products. Opportunities for biotechnological production by Combining naturally derived polar head groups with a lipid tail are manifold. In combination with appropriate reaction engineering immobilized hydrolases can be exploited for surfactant synthesis. In their reverse reactions, glycosidases are able to form glyosidic bonds, aùinoacylases were shown to catalyze amide bond formation and several lipases synthesize sugar esters in solvent systems under nearly water free conditions. The microbial synthesis of natural biosurfactants widens the spectrum of accessible molecules and several species of bacteria and fungi were shown to secrete amphiphilic molecules not easily accessible by chemical synthesis. The fermentative production of lipopeptides and glycolipids is feasible in large scale, and several of these microbial biosurfactants have been commercialized already for specialties application. Thus, biocatalytic processes and microbial biotransformations utilizing renewable resources add new sustainable technologies and new bio-based molecules to the surfactant market.
The review, including some own results, is a summary of the 2016 EDC congress lectures "Assessment of biotechnological processes towards bio-based surfactants" and "Microbial synthesis of mannosylerythritol- and cellobioselipids"Note de contenu : - INTRODUCTION TO BIO-BASED SURFACTANTS : MARKET, STRUCTURES AND CHEMICAL MANUFACTURING OF BENCHMARK COMPOUNDS
- BIOCATALYTIC SYNTHESIS OF BIO-BASED SURFACTANTS IN REVERSE HYDROLYSIS REACTIONS : Alkyl glycosides bia glycosidase reactions - Biocatalysts for acylamino acid coupling - Lipase catalyzed sugar ester synthesis
- MICROBIAL PRODUCTION OF BIOSURFACTANTS : Celliobiose lipids - Mannosylerythritol lipids - Rhamnolipids - Sophorolipids
- FUTURE CHALLENGES AND RESEARCH NEEDS : Bio-based surfactants via biocatalysis - Microbial surfactantsEn ligne : https://drive.google.com/file/d/1dYHM82RcLFh9Z6aiXDPQuFW8L39GoQly/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=28683
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