| Titre : |
Rheological fingerprinting as an effective tool to guide development of personal care formulations |
| Type de document : |
document électronique |
| Auteurs : |
S. Ozkan, Auteur ; C. Alonso, Auteur ; Roger L. McMullen, Auteur |
| Année de publication : |
2020 |
| Article en page(s) : |
p. 536-547 |
| Note générale : |
Bibliogr. |
| Langues : |
Anglais (eng) |
| Catégories : |
Cheveux -- Soins et hygiène
Composés lamellaires
Epaississants
Formulation (Génie chimique)
Gels -- Emploi en cosmétologie
Polymères
Rhéologie
|
| Index. décimale : |
668.5 Parfums et cosmétiques |
| Résumé : |
- Objective : Conventional rheological techniques in the linear viscoelastic region provide insights about the spatial configuration of the microstructural components of personal care formulations in their ‘at‐rest’ state. However, they fail to describe the textural experience associated with large and fast deformations during daily consumer application. In this study we present a non‐conventional rheological technique : large amplitude oscillatory shear (LAOS)—for probing the transformation of a material during its application. This technique is proposed a practical tool for formulators in their efforts to design products with desired textural attributes.
- Methods : A non‐linear rheological technique termed LAOS was utilized to capture the textural expression perceived by consumers. Lissajous plots (stress vs. strain or strain rate) provide a fingerprint of the formula and are utilized to both analyse the thickening mechanism and monitor the influence of various parameters, such as the chemistry, molecular properties, colloidal parameters and processing conditions.
- Results : In this study, we showcased several approaches for modifying the texture of personal care formulations and show the influence of various parameters on the characteristics of the Lissajous curves and their relation to sensorial perception. This fingerprinting technique shows that increasing the molecular weight or hydrophobic modification boosts the elasticity and thickening efficiency of a given polymer. Differences in the chemistry of rheological ingredients also influence the characteristic Lissajous fingerprint. In high concentration surfactant systems, which tend to form worm‐like micelles, their unique Lissajous fingerprints indicate structure rebuild because of fast kinetics at large but slow deformations. Analysis of lamellar gel‐based hair conditioner formulations demonstrates the unique high yield stress of these types of materials, accompanied by the fast breakdown transition from a solid to viscous structure because of their crystalline lamellar gel structure.
- Conclusion : The LAOS technique presented in this article is intended to better capture the textural expression perceived by consumers. Lissajous plots—generated from the LAOS experimental data—provide a fingerprint of the tested formula and are utilized to both analyse the thickening mechanism and monitor the influence of various parameters, such as the chemistry and molecular weight of the thickener, pH of the formula medium and influence of other ingredients in the formula (surfactants, emulsifiers, etc.). |
| Note de contenu : |
- Table 1 : Hair conditioner formulations thickened with lamellar gel structure and HMHEC. The pH was adjusted with citric acid
- Table 2 : Table 2 DSC data for three formulation prototype hair conditioners : low gel phase without polymer, low gel phase with HMHEC and normal (high) gel phase without polymer
- Table 3 : Transparent hair conditioner formulas containing HEC and HPMC as thickening polymers at different pH levels. The pH was adjusted with citric acid. †See text for description |
| En ligne : |
https://drive.google.com/file/d/1azWiP1_-vXyM6m3kqxntInRFfD5sSeeu/view?usp=shari [...] |
| Format de la ressource électronique : |
Pdf |
| Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=35419 |
in INTERNATIONAL JOURNAL OF COSMETIC SCIENCE > Vol. 42, N° 6 (12/2020) . - p. 536-547
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Rheological fingerprinting as an effective tool to guide development of personal care formulations in INTERNATIONAL JOURNAL OF COSMETIC SCIENCE, Vol. 42, N° 6 (12/2020)
