| Titre : |
Synthesis and application of novel tricyanofuran hydrazone dyes as sensors for detection of microbes |
| Type de document : |
texte imprimé |
| Auteurs : |
Tawfik A. Khattab, Auteur ; Hatem E. Gaffer, Auteur |
| Année de publication : |
2016 |
| Article en page(s) : |
p. 460-465 |
| Note générale : |
Bibliogr. |
| Langues : |
Anglais (eng) |
| Catégories : |
Bactéries
Capteurs optiques
Chromophores
Colorants -- Synthèse
Indicateurs biologiques
pH
|
| Index. décimale : |
667.2 Colorants et pigments |
| Résumé : |
Acknowledging the need to develop rapid and sensitive bacterial recognition approaches, we functionalised the tricyanofuran hydrazone molecular switch. Of significant interest in relation to the synthesised hydrazones is the formation of two different conjugated structures upon exposure to different pH values. Many bacteria release ammonia gas, which alkalises environments. Herein we report the synthesis of a tricyanofuran hydrazone having the function of a colorimetric pH sensor. The UV-visible absorption and fluorescence spectra exhibit reversible colour changes of the tricyanofuran hydrazone solution in acetonitrile under acid–base conditions. Our results indicate that the tricyanofuran hydrazone probe can identify the bacterial targets quickly with high sensitivity. The infected samples exhibit a significant colour change from orange to blue and in the mean time there is a decrease in fluorescence emission as a function of ammonia and volatile amines released from bacterial metabolites. This tricyanofuran hydrazone chromophore is proposed for use in food packaging with a pH-sensing capability. |
| Note de contenu : |
- EXPERIMENTAL : Materials and methods - pH control for sensor testing in solution - Preparation of bacterial samples - Synthetic approaches
- RESULTS AND DISCUSSION : Synthesis and characterisation - Molecular switching of TCFH in solution - Bacterial sample testing |
| DOI : |
10.1111/cote.12233 |
| En ligne : |
https://drive.google.com/file/d/1Tt7zliB0bKHLFHepUNJCnr0PTHplDDlN/view?usp=drive [...] |
| Format de la ressource électronique : |
Pdf |
| Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=27283 |
in COLORATION TECHNOLOGY > Vol. 132, N° 6 (12/2016) . - p. 460-465
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