Titre : |
Preparation of amino-terminated hyperbranched buffing dust and its adsorption property towards acid fuchsin : Use of an industry by-product to adsorb dyestuffs |
Type de document : |
texte imprimé |
Auteurs : |
Jie Liu, Auteur ; Zhang Feifei, Auteur ; Yinghu Song, Auteur ; Zhendi An, Auteur ; Yanchun Li, Auteur |
Année de publication : |
2021 |
Article en page(s) : |
p. 31-40 |
Note générale : |
Bibliogr. |
Langues : |
Anglais (eng) |
Catégories : |
Analyse quantitative (chimie) Caractérisation Colorants -- Adsorption Cuirs et peaux -- Déchets -- Recyclage Eaux usées -- Epuration Electrostatique Fuchsine, Acide Isotherme d'adsorption Poids moléculaires Polymères ramifiés Poussière de cuir
|
Index. décimale : |
675 Technologie du cuir et de la fourrure |
Résumé : |
Buffing dust (BD) is generated in the buffing process of leather making. Amino-terminated hyperbranched polymer (HBPN) was used to modify the BD to prepare hyperbranched polymer modified BD (HBPN-B). The molecular weight of HBPN was analysed by GPC and FTIR, SEM-EDS and BET analysis were employed to characterise the structure of the HBPN-B. The BET specific surface area of HBPN-B was 7.128m2.g-1. The EDS analysis results show that after modification, the N content of BD increased from 21.23% to 24.47%. HBPN-B was then used in the adsorption of dye from wastewater. The influences of reaction conditions on the adsorption properties of HBPN-B towards acid fuchsin were studied and the adsorption kinetic and isotherm were researched. The removal rate of acid fuchsin by HBPN-B increased with the increase of pH, the removal rate reached the maximum at pH2.5. Electrostatic attraction was the chief adsorption mechanism. The removal rate increased with the increase of HBPN-B dosage and temperature. The adsorption process was in conformity with pseudo-second order kinetic and Langmuir adsorption isotherm model adsorption. |
Note de contenu : |
- MATERIALS AND METHODS : Chemicals - Preparation of HBPN-B - The characterisation of HBPN-B - Quantification of acid fuchsin - Batch adsorption experiments - Adsorption kinetic - Adsorption isotherm
- RESULTS AND DISCUSSION : Characterisation of the HBPN-B - Effect of conditions of solution to the adsorption property of HBPN-B - Kinetics adsorption studies - Adsorption isotherm
- Table 1 : GPC analysis result of HBPN
- Table 2 : BET characterisation of biosorbent
- Table 3 : Constants for the kinetic models of acid fuchsin on the HBPN-B
- Table 4 : Isotherm parameters obtained from the fitting to experimental results on the adsorption of acid fuchsin onto the HBPN-B |
En ligne : |
https://drive.google.com/file/d/1HBFOgdQ3CcXaP5KEwrSo-QjLF-JlWCTB/view?usp=drive [...] |
Format de la ressource électronique : |
Pdf |
Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=35315 |
in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC) > Vol. 105, N° 1 (01-02/2021) . - p. 31-40