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Derivative cathodic stripping voltammetry in the simultaneous determination of three textile dyes in aqueous solutions / LÃdia B Santos in COLORATION TECHNOLOGY, Vol. 132, N° 3 (06/2016)
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Titre : Derivative cathodic stripping voltammetry in the simultaneous determination of three textile dyes in aqueous solutions Type de document : texte imprimé Auteurs : LÃdia B Santos, Auteur ; Alexandre T. Paulino, Auteur ; Fernando S. Domingues, Auteur ; Thábata K. S. F. Souza, Auteur ; Vitor C. Almeida, Auteur ; Nilson E. Souza, Auteur ; Juliana C. G. Moraes, Auteur Année de publication : 2016 Article en page(s) : p. 201-207 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Solutions aqueuses (chimie)
Teinture -- Fibres textiles
VoltampérométrieIndex. décimale : 667.3 Teinture et impression des tissus Résumé : Reactive dyes, such as Procion Yellow, Procion Red, and Procion Blue, were simultaneously determined in aqueous ternary solutions using derivative cathodic stripping voltammetry following adsorption on a hanging mercury drop electrode. An electrochemical cell containing Britton–Robinson buffer solution at pH 8 was used as the supporting electrolyte. The following experimental conditions were established: ?0.100 V deposition potential, 80 s deposition time, 50 mV pulse amplitude, 50 mV s?1 scan rate, and 0.40 mm2 maximum mercury drop size. A linear response was observed over the 0.630 × 10?3 to 1.050, 1.441 × 10?3 to 1.572, and 0.198 to 1.570 mg l?1 ranges for Procion Yellow, Procion Red, and Procion Blue respectively. The detection limits were 0.210 × 10?3, 0.480 × 10?3, and 0.066 mg l?1 respectively, with a relative standard deviation (n = 3) of 1.22%. The accuracy of the method was evaluated by derivative spectrophotometry, certifying the results as a function of proximity. All results were similar, indicating that derivative cathodic stripping voltammetry may be efficiently applied for the simultaneous determination of textile dyes in aqueous ternary solutions. Note de contenu : - EXPERIMENTAL : Apparatus - Solutions - Voltammetric measurements - Electrochemical calibration method - Dyebath preparation - Statistical analysis and process efficiency
- RESULTS AND DISCUSSION : Experimental conditions for voltammetric measurements - Electrochemical reduction mechanisms for Procion yellow, Procion red, and Procion blue - Derivative voltammetry for ternary mixture of dyes - Accuracy, validation, and statistical figures of merit - Efficiency of dyeing processDOI : 10.1111/cote.12209 En ligne : https://drive.google.com/file/d/1mHDnWNd2oRu4Vg1tdWRJKBGRxL2jCNDl/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=26351
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Code-barres Cote Support Localisation Section Disponibilité 18101 - Périodique Bibliothèque principale Documentaires Disponible