| Titre : |
Design and application of a multifunctional reactive dye capable of high fixation efficiency on cellulose |
| Type de document : |
texte imprimé |
| Auteurs : |
K. F. Morris, Auteur ; David M. Lewis, Auteur ; Peter J. Broadbent, Auteur |
| Année de publication : |
2009 |
| Article en page(s) : |
p. 186-194 |
| Note générale : |
Bibliogr. |
| Langues : |
Anglais (eng) |
| Index. décimale : |
667.3 Teinture et impression des tissus |
| Résumé : |
A polyfunctional reactive dye containing two dichloro-s-triazine residues linked through aliphatic amino groups via a third triazine system to the chromophoric residue has been prepared. The dye was synthesised stepwise from a specially synthesised 2,4-dichloro-s-triazine dyes. The first step is the reaction of both carbon–chlorine sites in the 'parent' dye with 2 mol ethylenediamine under selected conditions of pH and temperature; these conditions ensure that only one of the amino groups in the ethylenediamine will react to give the bis-2,4-aminoethyleneaminotriazine dye. The second step is the condensation of 2 mol cyanuric chloride with the two pendant primary amino groups. The alkylamino-linked dichloro-s-triazine dyes show very different dyeing properties when compared with those shown by the parent dichloro-s-triazine dye, which has the reactive group linked directly into the aromatic chromophore; in particular, the new dyes have high fixation efficiencies when dyed on cotton at 50 °C and the dye–fibre bond stability to boiling acidic conditions is very good. |
| DOI : |
10.1111/j.1478-4408.2008.00140.x |
| En ligne : |
http://onlinelibrary.wiley.com/doi/10.1111/j.1478-4408.2008.00140.x/pdf |
| Format de la ressource électronique : |
Pdf |
| Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=3161 |
in COLORATION TECHNOLOGY > Vol. 124, N° 3 (2008) . - p. 186-194
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Design and application of a multifunctional reactive dye capable of high fixation efficiency on cellulose in COLORATION TECHNOLOGY, Vol. 124, N° 3 (2008)
