Anionic surfactant sulfate dodecyl sodium (SDS)-induced thermodynamics and conformational changes of collagen by ultrasensitive microcalorimetry / Jie Zhang in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 3 (Année 2021)  

[article]  inJOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 3 (Année 2021) . - 6 p. Titre : Anionic surfactant sulfate dodecyl sodium (SDS)-induced thermodynamics and conformational changes of collagen by ultrasensitive microcalorimetry Type de document : texte imprimé Auteurs : Jie Zhang, Auteur ; Chunhua Wang, Auteur ; Fengteng Zhang, Auteur ; Wei Lin, Auteur Année de publication : 2021 Article en page(s) : 6 p. Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Analyse conformationnelle Calorimétrie Collagène Stabilité thermique Surfactants Thermodynamique Index. décimale : 675 Technologie du cuir et de la fourrure Résumé : In this communication, sulfate dodecyl sodium (SDS)-induced thermodynamics and conformational changes of collagen were studied. We used ultrasensitive differential scanning calorimetry (US-DSC) to directly monitor the thermal transition of collagen in the presence of SDS. The results show that SDS affects the conformation and thermal stability of collagen very differently depending on its concentrations. At CSDS ≤ 0.05 mM, the enhanced thermal stability of collagen indicates the stabilizing effect by SDS. However, a further increase of SDS leads to the denaturation of collagen, verifying the well-known ability of SDS to unfold proteins. This striking difference in thermodynamics and conformational changes of collagen caused by SDS concentrations can be explained in terms of their interactions. With increasing SDS, the binding of SDS to collagen can be dominated by electrostatic interaction shifting to hydrophobic interaction, and the latter plays a key role in loosening and unfolding the triple-helix structure of collagen. The important finding in the present study is the stabilizing effect of SDS on collagen molecules at extreme low concentration. Note de contenu : - Experimental section : Materials - Sample preparation - Ultra-sensitive differential scanning calorimeter (US-DSC) measurements - The interaction between SDS and collagen by microcalorimetry DOI : https://doi.org/10.1186/s42825-021-00063-2 En ligne : https://link.springer.com/content/pdf/10.1186/s42825-021-00063-2.pdf Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37545 [article]

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Biomass-based tanning agent for sustainable leather manufacture via cyanuric chloride modified chitooligosaccharide / Min Jiang in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CXVIII, N° 10 (10/2023)  

[article]  inJOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA) > Vol. CXVIII, N° 10 (10/2023) . - p. 417-427 Titre : Biomass-based tanning agent for sustainable leather manufacture via cyanuric chloride modified chitooligosaccharide Type de document : texte imprimé Auteurs : Min Jiang, Auteur ; Yuanhang Xiao, Auteur ; Jun Sang, Auteur ; Chunhua Wang, Auteur ; Jiajing Zhou, Auteur ; Wei Lin, Auteur Année de publication : 2023 Article en page(s) : p. 417-427 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Agents de tannage Analyse morphologique Biomasse Caractérisation Chitooligosaccharide Composés organiques -- Synthèse Cuirs et peaux -- Propriétés organoleptiques Cuirs et peaux -- Propriétés physiques Poids Index. décimale : 675.2 Préparation du cuir naturel. Tannage Résumé : Developing alternative tanning agents to avoid the potential environmental and human health risks from the conventional chrome tanning is essential for the leather industry. In this work, we prepared an eco-friendly biomass-based tanning agent dichlorotriazinyl chitooligosaccharide (DTCS) by modifying chitooligosaccharide (COS) with cyanuric chloride (CC) for chrome-free leather manufacture. The synthesis of such biomass-based tanning agent was systematically optimized to obtain the target product with high grafting degree of 67% and weight-average molecular weight (Mw) of 1465 g/mol. The non-pickling tanning procedure using DTCS was investigated, and the interactions between DTCS and collagen fibers were studied. Our results showed that the hydrothermal stability of the tanned leather was significantly increased, i.e., the shrinkage temperature (Ts) exceeding 82.0°C, and the mechanical properties were improved. Moreover, the organoleptic properties of leather (e.g., fullness, softness and grain tightness) exhibited obvious improvement. This research not only offers a reliable approach for cleaner leather manufacturing while addressing the underlying ecological pressure, but also highlights the emerging use of biomass materials in the leather industry. Note de contenu : - MATERIALS AND METHODS : Materials - Synthesis of DTCS - Determination of grafting degree (GD) of DTCS - Characterization of DTCS - DTCS tanning trials - Leather properties analysis - RESULTS AND DISCUSSION : Optimization of DTCS synthesis condition - Characterization of DTCS - Optimizatin of DTCS tanning process - Leather morphology anlaysis - Thickening rate analysis - Physical and organoleptic properties analysis - Table 1 : Tanning process for DTCS - Table 2 : Tanning process for F-90 - Table 3 : The average molecular weight and molecular-weight distribution of COS and DTCS - Table IV : The optimum tanning process of DTCS DOI : https://doi.org/10.34314/jalca.v118i10.8230 En ligne : https://drive.google.com/file/d/1csGAWb8R-ZPLSmdInoTLfYTzOcUHK0KN/view?usp=share [...] Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=39940 [article]

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Carbon footprint and toxicity indicators of alternative chromium-free tanning in China / Xiaoying Xu in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CX, N° 5 (05/2015)  

[article]  inJOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA) > Vol. CX, N° 5 (05/2015) . - p. 130-137 Titre : Carbon footprint and toxicity indicators of alternative chromium-free tanning in China Type de document : texte imprimé Auteurs : Xiaoying Xu, Auteur ; Grau Baquero, Auteur ; Rita Puig, Auteur ; Jiabo Shi, Auteur ; Sang Jun, Auteur ; Wei Lin, Auteur Année de publication : 2015 Article en page(s) : p. 130-137 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Bilan des émissions de gaz à effets de serre Durée de vie (Ingénierie) Énergie -- Consommation Environnement -- Etudes d'impact Tannage -- Aspect de l'environnement Toxicologie Index. décimale : 675.2 Préparation du cuir naturel. Tannage Résumé : This paper analyzes, from a life cycle perspective, the environmental performance of a newly developed chromium-free tanning process compared to the conventional one, in China. Both processes were evaluated by using carbon footprint, energy consumption and toxicity indicators. Chromium-free tanning process has been found to significantly reduce the considered impact categories compared to conventional tanning. The impact contribution of each process step was calculated, with the tanning step being the major contributor. Results show that the production of chemicals used in the tanning process, have a significant effect on the impacts evaluated. Some of these chemicals have been substituted with similar ones (used as proxies) when no manufacturing-data was available in the databases. Thus, it is important for future and more precise LCA studies to develop databases on the specific chemicals used. This study is a first estimation of the impacts and will help on the decision of expending time and efforts on developing and optimizing the new technology. The results show that it is interesting to use this LCA methodology to environmentally evaluate new research processes and products, before industrial scaling and implementing them, to optimize research time and efforts towards the most environmentally promising products and processes. Note de contenu : - AIM OF THE STUDY - METHODOLOGY - INVENTORY DATA AND MODELING : Functional unit and system boundaries - Conventional tanning process model and inventory data - Chromium free tanning process model and inventory data - Chinese electrical power grid mix and thermal energy mix - Wastewater treatment - RESULTS AND DISCUSSION : Evaluation of the GWP index - Evaluation of the energy consumption - Evaluation of the toxicological impacts to humans and freshwater - Comparative evaluation of tanning steps En ligne : https://drive.google.com/file/d/10vyeauNiwsjpJ9kr5HmOz6pgSDeKiJ7c/view?usp=drive [...] Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=24053 [article]

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A facile preparation of a novel non-leaching antimicrobial waterborne polyurethane leather coating functionalized by quaternary phosphonium salt / Wang Chunhua in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 2 (Année 2020)  

[article]  inJOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 2 (Année 2020) . - 12 p. Titre : A facile preparation of a novel non-leaching antimicrobial waterborne polyurethane leather coating functionalized by quaternary phosphonium salt Type de document : texte imprimé Auteurs : Wang Chunhua, Auteur ; Jianhui Wu, Auteur ; Changdao Mu, Auteur ; Wei Lin, Auteur Année de publication : 2020 Article en page(s) : 12 p. Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Ammoniums quaternaires Antibactériens Caractérisation Composés organiques -- Synthèse Cuir Essais (technologie) Formulation (Génie chimique) Polymères en émulsion Polyuréthanes Revêtements Index. décimale : 675 Technologie du cuir et de la fourrure Résumé : The aim of this research is to develop a novel non-leaching antimicrobial waterborne polyurethane (WPU) leather coating material with covalently attached quaternary phosphonium salt (QPS). The structure of the QPS-bearing WPU has been identified, and their thermal stability, mechanical property, and antimicrobial performance have been investigated. The results reveal that the incorporation of QPS slightly reduces the thermal stability of WPU material but would not affects its usability as leather coating. Despite the presence of hydrophobic benzene in QPS structure, the strong hydration of its cationic groups leads to the increased surface contact angle (SCA) and water absorption rate (WAR) of the films, suggesting that the water resistance of the films needs to be improved for the purpose of leather coatings. Antibacterial tests demonstrate that when the QPS content is 20 wt%, QPS-bearing WPU shows effective antimicrobial activity against bacteria. The WPU containing QPS prepared in this study is a non-leaching antimicrobial material and has great potential application as leather coating. Note de contenu : - Materials - Synthesis of dihydroxy-terminated QPS (HQPS) - Synthesis of QPS-bearing WPU - Characterization methods - Testing of antibacterial property - Table 1 : Formulations and characteristics of WPU DOI : 10.1186/s42825-019-0014-8 En ligne : https://link.springer.com/content/pdf/10.1186/s42825-019-0014-8.pdf Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37138 [article]

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Life cycle assessment and leather production / Diego Navarro in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 2 (Année 2020)  

[article]  inJOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 2 (Année 2020) . - 13 p. Titre : Life cycle assessment and leather production Type de document : texte imprimé Auteurs : Diego Navarro, Auteur ; Jianhui Wu, Auteur ; Wei Lin, Auteur ; Pere Fullana-i-Palmer, Auteur ; Rita Puig, Auteur Année de publication : 2020 Article en page(s) : 13 p. Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Cuir Cuirs et peaux -- Déchets Durée de vie (Ingénierie) Production Index. décimale : 675 Technologie du cuir et de la fourrure Résumé : Leather industry is facing new trends on production and consumption patterns due to society concerns. Circular economy is proposing a transition from the current economic model to a more sustainable one, in which waste is designed out and resources will be reused and recycled as long as possible. In this transition, Life Cycle Assessment (LCA) is an important tool to help decision-making. In the present review, 39 English-written peer-reviewed papers related to LCA and leather have been found, 30 of which were published in the last 6 years, meaning LCA is nowadays an important subject. Papers are presented within 4 types, focused on: 1) the whole leather production process, 2) a single step in the production process (e.g, new technologies for unhairing), 3) waste treatment and recycling, and 4) life cycle thinking with ideas on long-term strategies for leather industries. As discussed in the literature review, leather industry has important challenges to address: increasing sustainability and transparency on the supply chain, and strengthening the beauty of leather. Taking up these challenges from a life cycle perspective will help leather industry flourish in the coming future. Note de contenu : - Details on LCA methodology - Methodology - Table 1 : LCA studies which include the complete leather production process - Table 2 : LCA papers found in the literature, studying a specific part of the leather production - Table 3 : LCA papers studying leather-waste treatment processes - Table 4 : Life cycle thinking papers related to leather production DOI : https://doi.org/10.1186/s42825-020-00035-y En ligne : https://link.springer.com/content/pdf/10.1186/s42825-020-00035-y.pdf Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37459 [article]

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A novel approach for lightfast wet-white leather manufacture based on sulfone syntan-aluminum tanning agent combination tannage / Zhang Long in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CXIII, N° 6 (06/2018)  

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A novel ester-bonded gemini quaternary ammonium salt with good antimicrobial activity and anti-mold performance for wet blue leather / Tao Zhang in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CXVII, N° 4 (04/2022)  

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A novel non-pickling combination tanning for chrome-free leather based on reactive benzesulphonate and tannic acid / Yuanhang Xiao in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CXV, N° 1 (01/2020)  

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Pickering aqueous foam templating : a promising strategy to fabricate porous waterborne polyurethane coatings / Jianhui Wu in COLLAGEN AND LEATHER, Vol. 5 (2023)  

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Polyethylene glycol as a preservative for pigskin and its interaction with collagen / Chunhua Wang in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CXIII, N° 10 (10/2018)  

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Simultaneous determination of N-methyl-2-pyrrolidone (NMP) and N-ethyl-2-pyrrolidone (NEP) in leather by gas chromatography-mass spectrometry / Sang Jun in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 99, N° 3 (05-06/2015)  

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Sustainable metal-free leather manufacture via synergistic effects of triazine derivative and vegetable tannins / Yuanhang Xiao in COLLAGEN AND LEATHER, Vol. 5 (2023)  

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