| Titre : |
The grafting of PE-g-MA chains on graphene derivatives to improve tensile properties of polyethylene |
| Type de document : |
texte imprimé |
| Auteurs : |
M. Elhamnia, Auteur ; Ghodratollah Hashemi Motlagh, Auteur ; R. Goudarzi, Auteur |
| Année de publication : |
2017 |
| Article en page(s) : |
p. 623-636 |
| Note générale : |
Bibliogr. |
| Langues : |
Anglais (eng) |
| Catégories : |
Composites -- Propriétés électriques
GraphèneLe graphène est un cristal bidimensionnel (monoplan) de carbone dont l'empilement constitue le graphite. Il a été isolé en 2004 par Andre Geim, du département de physique de l'université de Manchester, qui a reçu pour cette découverte le prix Nobel de physique en 2010 avec Konstantin Novoselov. Il peut être produit de deux manières : par extraction mécanique du graphite (graphène exfolié) dont la technique a été mise au point en 2004, ou par chauffage d'un cristal de carbure de silicium, qui permet la libération des atomes de silicium (graphène epitaxié). Record en conduction thermique jusqu'à 5300 W.m-1.K-1. C'est aussi un matériaux conducteur.
Greffage (chimie)
Matériaux hybrides
Oxyde de graphite
Polyéthylène greffé anhydride maléique
Polymères -- Propriétés mécaniques
Traction (mécanique)
|
| Index. décimale : |
668.4 Plastiques, vinyles |
| Résumé : |
Polyethylene chains having functional maleic anhydride groups were grafted on several graphene derivatives. These chain grafted graphene derivatives were added to polyethylene and the properties of the obtained nano-composites were investigated. Modified Hummers' method was employed to produce graphite oxide (GO). Then amino-functionalized GO (AFGO) was prepared through the functionalization of GO by ethylenediamine. Thermally reduced GO (TRGO) was prepared by the heating of the GO in the presence of nitrogen. TRGO was amino-functionalized to obtain amino functionalized nano-graphite (AFNG). Low density polyethylene (PE) and polyethylene grafted maleic anhydride (PEgMA) nano-composites, containing 1 to 3 wt% of the obtained fillers, were produced by solution mixing. With the incorporation of amino-functionalized graphene into PEgMA, the amine groups on the graphene surface and the maleic anhydride in PE chains covalently bonded and improved the mechanical properties of the nano-composites; by comparing PEgMA nano-composite with 1 wt% AFGO and 1 wt% GO, a 155 percent enhancement in the elongation at break was observed. The modulus and tensile strength of these nano-composites increased over the pure matrix. In addition, the effect of PEgMA content in the 1 wt% AFGO nano-composites was studied and the optimum ratio of PEgMA to PE was found to be 0.40 to 0.60. At this ratio, the best mechanical properties were achieved. Also, at 2 wt% nano-filler the elongation at break of the AFNG nano-composite was higher than that of the TRGO nano-composite. AFNG created more chain grafting but AFNG exfoliates more. The electrical conductivity of TRGO powders by amino-functionalization decreased about 20 times. Therefore, the electrical conductivity of the graphene nano-composites was higher than amino-functionalized graphene nano-composites. |
| Note de contenu : |
- EXPERIMENTAL : Chemicals and materials - Preparation of GO - Preparation of TRGO and CRGO - Preparation of AFNG and AFGO - Preparation of graphene based nano-composites - Analysis
- RESULTS AND DISCUSSION : Filler characterization - Nano-composite characterization |
| DOI : |
10.3139/217.3508 |
| En ligne : |
https://drive.google.com/file/d/1qjpHFf5exl-gUON-Qb1vXoqhz1400e6F/view?usp=drive [...] |
| Format de la ressource électronique : |
Pdf |
| Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=29429 |
in INTERNATIONAL POLYMER PROCESSING > Vol. XXXII, N° 5 (11/2017) . - p. 623-636
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The grafting of PE-g-MA chains on graphene derivatives to improve tensile properties of polyethylene in INTERNATIONAL POLYMER PROCESSING, Vol. XXXII, N° 5 (11/2017)
