| Titre : |
Effect of solvent volatility on diameter selection of bicomponent nanofibers produced by gas jet fiber process test |
| Type de document : |
texte imprimé |
| Auteurs : |
S. S. Rajgarhia, Auteur ; Sadhan C. Jana, Auteur |
| Année de publication : |
2017 |
| Article en page(s) : |
p. 582-589 |
| Note générale : |
Bibliogr. |
| Langues : |
Anglais (eng) |
| Catégories : |
Caractérisation
Core-Shell
Evaporation
Fibres textiles bi-composant
Fibres textiles synthétiques
Nanofibres
Production
Réseaux polymères
Rhéologie
Solutions de polymère
solvants
Viscosité
|
| Index. décimale : |
668.4 Plastiques, vinyles |
| Résumé : |
This paper addresses the role of solvent volatility on diameter selection of bicomponent polymer nanofibers produced via gas jet fibers (GJF) process whereby an axisymmetric turbulent gas jet is used for liquid jet initiation, liquid jet stretching, and solvent evaporation. Several morphological forms, such as interpenetrating network (IPN), bi-lobal, and core-shell are obtained by spinning homogeneous solutions of two immiscible polymers in two mutually miscible solvents. The diameter selection of fibers of the same morphology, e. g., bi-lobal, is achieved by spinning polymer solutions of two sets of solvents of different volatility. The results show that fiber diameter is strongly dependent on the value of vapor pressure of the solvents while the morphology is strongly dependent on the vapor pressure difference of the two respective solvents. The diameter selection by GJF process is most prominent for IPN nanofibers, moderately prominent for core-shell fibers, and almost indifferent for bi-lobal nanofibers. The relative rates of solvent evaporation are useful in interpreting the experimental trend. |
| Note de contenu : |
- EXPERIMENTAL SECTION : Materials - Measurement of shear viscosity - Sample preparation - Method of fiber production - Fiber characterization - Fiber diameter - Evaporation time of the solvents
- RESULTS AND DISCUSSION : Fibers with IPN morphology - Fibers with bi-lobal morphology - Fibers with core-shell morphology |
| DOI : |
10.3139/217.3453 |
| En ligne : |
https://drive.google.com/file/d/1_Ebdocr2-JzpktuFq9jSVVp41zFbUi0X/view?usp=drive [...] |
| Format de la ressource électronique : |
Pdf |
| Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=29425 |
in INTERNATIONAL POLYMER PROCESSING > Vol. XXXII, N° 5 (11/2017) . - p. 582-589
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Effect of solvent volatility on diameter selection of bicomponent nanofibers produced by gas jet fiber process test in INTERNATIONAL POLYMER PROCESSING, Vol. XXXII, N° 5 (11/2017)
