[article]
| Titre : |
Biomimetic synthesis of calcium carbonate films on bioinspired polydopamine matrices |
| Type de document : |
texte imprimé |
| Année de publication : |
2017 |
| Note générale : |
Bibliogr. |
| Langues : |
Américain (ame) |
| Catégories : |
Calcite Grâce à leurs performances analytiques, on observe un intérêt croissant pour l’utilisation des installations en rayonnement synchrotron et de certains appareils portables employant des sources de rayons X afin d’analyser, de révéler et de conserver les matériaux des objets du patrimoine.
La diffraction des rayons X va ainsi permettre de révéler la complexité de la nature des pigments utilisés par les artistes : c’est par la structure de la matière cristalline que l’on peut comprendre certaines de leurs propriétés optiques et mécaniques ainsi que leurs modes de synthèse.
Caractérisation
Carbonate de calciumLe carbonate de calcium (CaCO3) est composé d'un ion carbonate (CO32-) et d'un ion calcium (Ca2+), sa masse molaire est de 100,1 g/mole.
C'est le composant principal du calcaire et de la craie, mais également du marbre. C'est aussi le principal constituant des coquilles d'animaux marins, du corail et des escargots.
Chimie biomimétique
Couches minces
Hydrophobie
Matériaux bio-inspirés
Minéralisation
Polydopamine
|
| Index. décimale : |
667.9 Revêtements et enduits |
| Résumé : |
We combine the active surface of polydopamine (PDA) with the biomimetic mineralization of CaCO3 to obtain the macroscopically continuous CaCO3 films under mild conditions. In this approach, the organic matrices were adhesive PDA coatings, which were dip-coated on silicon wafers by the self-polymerization of dopamine in an alkaline aqueous solution (pH 8.5). The inorganic layers were CaCO3 films, which were formed in a CaCl2 solution in the presence of poly(acrylic acid) (PAA) via a CO2 diffusion method. During the biomimetic mineralization, amorphous calcium carbonate (ACC) was formed on PDA matrices with the help of PAA, which, subsequently, was transformed into a flat continuous calcite film on the PDA matrices. As the mineralization time increased, a new layer of CaCO3 crystals was formed over the calcite and, as a result, led to continuous CaCO3 films with rough surfaces. The thicknesses of CaCO3 films can be controlled by tuning the mineralization time. Our approach may provide a simple, yet efficient way for the preparation of macroscopically continuous organic–inorganic composite CaCO3 films under mild conditions. Moreover, superhydrophobic surfaces can be successfully achieved via a hydrophobic modification of the rough CaCO3 films, which make them suitable candidates for a variety of superhydrophobic applications, such as self-cleaning surfaces or anticorrosion, antiadhesive coatings. |
| Note de contenu : |
- Materials
- Fabrication of bioinspired polydopamine matrices
- Preparation of CaCO3 films on polydopamine matrices
- Hydrophobic modification of CaCO3 films
- Characterization |
| DOI : |
10.1007/s11998-016-9898-x |
| En ligne : |
https://link.springer.com/content/pdf/10.1007%2Fs11998-016-9898-x.pdf |
| Format de la ressource électronique : |
Pdf |
| Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=29144 |
in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH > Vol. 14, N° 5 (09/2017)
[article]
|
Aller sur edunet
Accueil
Biomimetic synthesis of calcium carbonate films on bioinspired polydopamine matrices in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 14, N° 5 (09/2017)
