Mechanical properties of UV-waterborne varnishes reinforced by cellulose nanocrystals / Vahe Vardanyan in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 11, N° 6 (11/2014)  

[article]  inJOURNAL OF COATINGS TECHNOLOGY AND RESEARCH > Vol. 11, N° 6 (11/2014) . - p. 841-852 Titre : Mechanical properties of UV-waterborne varnishes reinforced by cellulose nanocrystals Type de document : texte imprimé Auteurs : Vahe Vardanyan, Auteur ; Bouddah Poaty, Auteur ; Gregory Chauve, Auteur ; Véronic Landry, Auteur ; Tigran Galstian, Auteur ; Bernard Riedl, Auteur Année de publication : 2014 Article en page(s) : p. 841-852 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Cellulose La cellulose est un glucide constitué d'une chaîne linéaire de molécules de D-Glucose (entre 200 et 14 000) et principal constituant des végétaux et en particulier de la paroi de leurs cellules. Dispersions et suspensions Matériaux nanocristallins Polyuréthanes Traîtements de surface Vernis -- Propriétés mécaniques Vernis en phase aqueuse Index. décimale : 667.9 Revêtements et enduits Résumé : There are many instances in the literature of nanocellulose-thermoplastic composites, but there are few studies on coatings reinforced by cellulose nanocrystals (CNCs). The overall objective of this research was to develop organic nanoparticles-reinforced UV-water-based coatings for wood applications and to study the effect, mainly on wear properties, of the final composite coatings. CNC was mixed in the varnishes to improve the mechanical properties of the coatings. One of the key aspects in the technology of nanocomposites remains the dispersion of the nanoparticles within the matrix as well as its affinity with the matrix. To quantify the dispersion, efficient methods of characterization are needed in order to reveal the nanosized particles. In this article, a novel characterization method based on atomic force microscopy was employed to characterize such nanocomposite coatings, by measuring surface nanoroughness, which is clearly correlated with quality of dispersion and mechanical properties. CNC was modified by either alkyl quaternary ammonium bromides or acryloyl chloride. The mechanical properties (abrasion and scratch resistances, hardness and adhesion) were analyzed and compared to the reference varnish without nanoparticles. The modified CNC addition in UV-water-based coatings results in an approximately 30–40% increase in wear resistance (abrasion and scratch), without any loss of appearance. Note de contenu : - INTRODUCTION : Waterborne coating - CNC - CNC dispersion characterization - MATERIALS AND EXPERIMENTAL PROCEDURE : The composition of the formulation - CNC - Surface modification of cellulose nanocrystals - Preparation of formulations and samples - Experimental methods - RESULTS AND DISCUSSION : Coating with unmodified CNC - Effect of surface modification of CNC - Mechanical properties of coatings DOI : 10.1007/s11998-014-9598-3 En ligne : https://link.springer.com/content/pdf/10.1007%2Fs11998-014-9598-3.pdf Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=22308 [article]

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