[article]
| Titre : |
Structural development and properties of melt spun poly(butylene succinate) and poly(butylene terephthalate-co-succinate-co-adipate) biodegradable fibers |
| Type de document : |
texte imprimé |
| Auteurs : |
X. Q. Chi, Auteur ; Takeshi Kikutani, Auteur ; Hiroshi Ito, Auteur ; M. Takasaki, Auteur |
| Année de publication : |
2006 |
| Article en page(s) : |
p. 64-69 |
| Note générale : |
Bibliogr. |
| Langues : |
Anglais (eng) |
| Index. décimale : |
668.9 Polymères |
| Résumé : |
High-speed melt spinning of biodegradable aliphatic polyester poly(butylene succinate) (PBS), and aliphatic-aromatic copolyester poly(butylene terephthalate-co-succinate-co-adipate) (PBTSA) was carried out. The effects of spinning conditions on the structural development of PBS and PBTSA fibers were investigated through the measurements on on-line velocity profile, birefringence, wide-angle X-ray diffraction (WAXD), differential scanning calorimetry, and tensile test. Both PBS and PBTSA fibers showed well-developed crystal structure in WAXD patterns, though the deformation of the spinline continued down to the position of winding suggesting that substantial orientation induced crystallization did not occur in spinline of both cases.
Increasing take-up velocity or decreasing extrusion temperature led to the enhancement of molecular orientation, crystal structure and mechanical property of both PBS and PBTSA fibers, but no distinct effect on the thermal property of those fibers. The melting temperature of PBTSA fibers was at ca.115 °C, same as that of PBS fibers. Elastomeric property of hard-soft units consisting PBTSA fibers leads to its good recoverability ; however, this behavior lowers the initial modulus and tensile strength compared with those of the corresponding aliphatic PBS fibers. |
| DOI : |
10.3139/217.0071 |
| En ligne : |
https://drive.google.com/file/d/18Q0Z6At1ICrHvR02N-QaVOVulwhUa041/view?usp=drive [...] |
| Format de la ressource électronique : |
Pdf |
| Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=2930 |
in INTERNATIONAL POLYMER PROCESSING > Vol. XXI, N° 1 (03/2006) . - p. 64-69
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