| Titre : |
Colorimetric chemosensor for Cu(II) from electrospun nanofibrous mat mixed with 5-methoxy-salicylaldehyde azine |
| Type de document : |
texte imprimé |
| Auteurs : |
Apisit Karawek, Auteur ; Pipattra Mayurachayakul, Auteur ; Apisama Dilokpramuan, Auteur ; Choladda Srisuwannaket, Auteur ; Kornkanya Pratumyot, Auteur ; Withawat Mingvanish, Auteur ; Mongkol Sukwattanasinitt, Auteur ; Pinit Kidkhunthod, Auteur ; Nakorn Niamnont, Auteur |
| Année de publication : |
2022 |
| Article en page(s) : |
p. 38-46 |
| Note générale : |
Bibliogr. |
| Langues : |
Anglais (eng) |
| Catégories : |
Acétate de cellulose L'acétate de cellulose est une matière plastique inventée en 1865. C'est l'ester acétate de la cellulose.
Capteurs chimiques
Caractérisation
Colorimétrie
Composés organiques -- Synthèse
Electrofilature
Ions cuivre
Ligands
Nanofibres
|
| Index. décimale : |
677.46 Cellulosiques : rayonnes, acetates |
| Résumé : |
The condensation product of 5-methoxy-salicylaldehyde with hydrazine hydrate (referred to below as compound 1) was used as a ligand in a cellulose acetate electrospun nanofibrous mat to determine copper ions in aqueous solutions. The electrospun nanofibrous mats, based on cellulose acetate mixed with compound 1, were constructed using an electrospinning method and had a diameter of 260 nm. The sensing nanofibrous mat exhibited a sensitive and selective response for Cu(II) ions over a linear concentration range of 1-30 µM in a 0.1 M HEPES buffer (pH 7.4) using a colorimeter. The detection limit of the method was 1.04 µM lower than the maximum level of Cu(II) in drinking water (16 µM, as determined by the US Environmental Protection Agency). Additionally, it exhibited high selectivity for Cu(II) ions over 13 other cations. The sensing nanofibrous mat was fully reversible for ethylenediamine tetraacetic acid treatment cycles. Preliminary results indicated the sensitivity and selectivity of the nanofibrous mat for detecting Cu(II) ions by naked-eye detection from yellow to orange. The reaction product of compound 1 and the Cu(II) ion was studied using X-ray absorption spectroscopy. The Cu-coordination number was approximately 5.023 ± 1.42, and the Cu–N distance (R) was 1.986 Å. The nanofibrous mat demonstrated a convenient and straightforward Cu(II) ion-detection technique in both wastewater and water environments. |
| Note de contenu : |
- EXPERIMENTAL : Materials and methods - Analytical instruments - Synthesis of compound - Electrospinning and characterisation of CA nanofibrous mat mixed with compound - General procedure for visual detection of Cu(II) ions of the nanofibrous mat using a colorimeter - X-ray absorption near-edge structure measurement for Cu-oxidation number determination of compound 1–Cu complex - Real samples of Cu(II) detection using the nanofibrous mat
- RESULTS AND DISCUSSION : Synthesis of compound - Fabrication and characterisation of compound 1-incorporated CA nanofibrous mat - Optimal conditions for Cu(II) ion-sensing using the nanofibrous mat - Cu(II) ion detection - Interference study - XANES measurement for Cu-oxidation number determination of compound 1–Cu complex - Real sample detection - The reusability and reproducibility of the nanofibrous mat
- Table 1 : The percentage recovery data for the detection of Cu(II) in spiked wastewater samples (n = 3)
- Table 2 : Comparison of the Cu(II) ion-sensing properties of different sensors |
| DOI : |
https://doi.org/10.1111/cote.12567 |
| En ligne : |
https://onlinelibrary.wiley.com/doi/epdf/10.1111/cote.12567 |
| Format de la ressource électronique : |
Pdf |
| Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37497 |
in COLORATION TECHNOLOGY > Vol. 138, N° 1 (02/2022) . - p. 38-46
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