[article]
| Titre : |
Complete inhibition of hexavalent chromium formation from chrome-tanned leather with combined inhibitors |
| Type de document : |
texte imprimé |
| Auteurs : |
Koki Ogata, Auteur ; Yuki Kumazawa, Auteur ; Yoichi Koyama, Auteur ; Keiji Yoshimura, Auteur ; Koji Takahashi, Auteur |
| Année de publication : |
2017 |
| Article en page(s) : |
p. 27-32 |
| Note générale : |
Bibliogr. |
| Langues : |
Anglais (eng) |
| Catégories : |
Chrome hexavalent
Cuir -- Teneur en chrome hexavalent
Extraction (chimie)
Inhibiteurs (chimie)
Oxydoréduction
Phosphate de potassiumLe phosphate de potassium est le nom générique pour les sels formés des ions phosphate et potassium résultant de l'attaque de l'hydroxyde de potassium (KOH ou potasse, base) par l'acide phosphorique.
Statistique
|
| Index. décimale : |
675 Technologie du cuir et de la fourrure |
| Résumé : |
Hexavalent chromium (Cr6+) is formed in chrome-tanned leather due to oxidation of trivalent chromium (Cr3+) under certain conditions and may induce dermatitis and cancer. Specifically, significant amounts of Cr6+ are generated during the heat-ageing process by pre-heating at 80°C for 24 hours in accordance with ISO rnethod17075, promoting the formation of Cr6+ from Cr3+ in chrome-tanned leather. Thus, inhibiting or minimizing the production of Cr6+ is needed badly. A previous report demonstrated that 0.1mol/L potassium phosphate buffer (P-buffer ; pH5.5) was highly efficient as an extractant for the measurement of Cr6+ from chrome-tanned leather as compared with P-buffer (pH8.0).
The present report describes efforts to control the redox behaviour of Cr3+ with the goal of inhibiting the formation of Cr6+ in chrome-tanned leather using a low-molecular weight (At 9,400) collagen peptide (CP-9), 2, 6-di-t-butyl-4-methylphenol (BHT), 3(2)-t-butyl-4-hydroxyanisole (BHA), and ascorbic acid (AsA) as inhibitors, even with heat-aged leather. Chrome-tanned leather was treated with the inhibitors, and the resulting leather samples were extracted with P-buffer (pH5.5) to determine the amount of Cr6+ in the extracts. The results showed that CP-treatment significantly reduced the amount of Cr6+ formed, probably due to a combination of chelation of CP on the Cr3+ complex, quenching of reactive oxygen, and radical scavenging. The BHT, and BHA, and AsA treatments also reduced the amount of Cr6+ formed, probably due la scavenging radicals from the oxidative products of the fatliquoring agent and alterations in the reducing conditions. However, treatment with any of the inhibitors individually did not cause complete inhibition of Cr3+ oxidation. Therefore, the action of the combined inhibitors was investigated. The results demonstrated that treatment with BHA + CP and with BHA + AsA produced a synergistic reduction in Cr6+ production. Use of BHA + AsA + CP completely inhibited the formation of Cr6+ from heat-aged leather samples. |
| Note de contenu : |
- Materials
- Treatment of the leather sample with inhibitor
- Extraction of Cr from the treated leather sample
- Analytical methods
- Statistical analysis |
| En ligne : |
https://drive.google.com/file/d/1iYCWrvmmpRnUAnE4Xf8BR9QBsfNnBDPz/view?usp=drive [...] |
| Format de la ressource électronique : |
Pdf |
| Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=27986 |
in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC) > Vol. 101, N° 1 (01-02/2017) . - p. 27-32
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Complete inhibition of hexavalent chromium formation from chrome-tanned leather with combined inhibitors in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 101, N° 1 (01-02/2017)
