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[article]
Titre : |
The processing behavior of liquid Sn/molten polyethylene during internal mixing |
Type de document : |
texte imprimé |
Auteurs : |
G. Zhang, Auteur ; T. Liu, Auteur ; X. Liu, Auteur ; Y. Yi, Auteur ; L. Liu, Auteur ; X. Tan, Auteur ; J. Luo, Auteur ; J. He, Auteur ; H. Ma, Auteur ; A. Lu, Auteur ; Z. Deng, Auteur ; Y. Shu, Auteur |
Année de publication : |
2014 |
Article en page(s) : |
p. 175-183 |
Note générale : |
Bibliogr. |
Langues : |
Anglais (eng) |
Catégories : |
Composites Etain Etat fondu (matériaux) Interfaces (Sciences physiques) Mélange Polyéthylène haute densité Taille des particules
|
Index. décimale : |
668.9 Polymères |
Résumé : |
In our study, liquid tin (Sn) was mixed with molten polyethylene using an internal mixer; the interfacial tension between the liquid Sn and molten polyethylene was measured using the deformed drop retraction method. The results showed that liquid Sn separated when the Sn content was higher than approximately 2?% by volume because of the interfacial tension of up to 167?mN/m and the 106-fold viscosity difference between the liquid Sn and the molten polyethylene. When Sn separation did not occur, the effects of the mixing time and rotary speed on the degree of mixing and the Sn particle size were analyzed using thermogravimetric analysis and scanning electron microscopy. The results showed that the effects of mixing time and rotary speed on the degree of mixing and Sn particle size can be combined as the impact of specific energy input. With increasing specific energy input, the degree of mixing initially increased and subsequently remained constant, while the Sn particle size initially decreased and subsequently remained constant. The refinement of the dispersed phase was completed with a low specific energy input, but the homogenization of the dispersed phase required a higher specific energy input to achieve completion, revealing the relationship between distributive mixing and dispersive mixing. |
Note de contenu : |
- EXPERIMENTS : Raw materials - Internal mixing of Sn and HDPE - Determination of the interfacial between liquid Sn and molten HDPE - Evaluation of the homogeneity of the composites - Morphologies and sizes of the metal phase in the composites
- RESULTS AND DISCUSSION : Aggregation and separation of liquid Sn - Relationship of the degree of mixing and Sn particle size with processing conditions |
DOI : |
10.3139/217.2635 |
En ligne : |
https://drive.google.com/file/d/1-PqBCAezE0A2WzEL0_iHa1HCJ8s1wO2q/view?usp=drive [...] |
Format de la ressource électronique : |
Pdf |
Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=21309 |
in INTERNATIONAL POLYMER PROCESSING > Vol. XXIX, N° 2 (05/2014) . - p. 175-183
[article]
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