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Wood substrate - The foundation / E. R. Miller in SURFACE COATINGS INTERNATIONAL. PART B : COATINGS TRANSACTIONS, Vol. 88, B3 (09/2005)  

[article]  inSURFACE COATINGS INTERNATIONAL. PART B : COATINGS TRANSACTIONS > Vol. 88, B3 (09/2005) . - p. 157-161 Titre : Wood substrate - The foundation Type de document : texte imprimé Auteurs : E. R. Miller, Auteur Année de publication : 2005 Article en page(s) : p. 157-161 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Assurance qualité Bois -- Revêtements Humidité -- Absorption:Eau -- Absorption Revêtements -- Entretien et réparations:Peinture -- Entretien et réparations Tanins Index. décimale : 667.9 Revêtements et enduits Résumé : Cost-effective protection for the wood substrate is the foundation for ensuring the successful performance of exterior wood components. However, notwithstanding the considerable research and development efforts in the coatings industries during the last two decades, the fundamental problems of protecting the wood substrate against surface weathering and water entry remain as challenging as ever. This paper will focus on two main issues: water entry into wood and the performance of maintenance paint systems. The benefits of end-grain sealing will be reviewed, and results of recent Building Research Establishment (BRE) work into the relationship between coating permeability and moisture content in the wood will be presented. It will be argued that most modern coatings fail to control adequately moisture content fluctuations in the surface layers of the wood, and that this is detrimental for the long-term performance of the wood and coating alike. The need for ‘robust’ maintenance coatings possessing improved tolerance to imperfect surfaces and for quality assurance for wood coatings will also be discussed. Note de contenu : - Substrate factors affecting joinery performance : Tannin staining - Susceptibility of wood surfaces to photodegradation - Water absorption into wood - Relation between coating permeability and wood moisture content in service - Maintenance painting - Quality assurance for wood coatings DOI : 10.1007/BF02699567 En ligne : https://link.springer.com/content/pdf/10.1007/BF02699567.pdf Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=5410 [article]

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Prospects for assessing the adhesive performance of coatings by non-destructive methods / J. A. Graystone in SURFACE COATINGS INTERNATIONAL. PART B : COATINGS TRANSACTIONS, Vol. 88, B3 (09/2005)  

[article]  inSURFACE COATINGS INTERNATIONAL. PART B : COATINGS TRANSACTIONS > Vol. 88, B3 (09/2005) . - p. 163-170 Titre : Prospects for assessing the adhesive performance of coatings by non-destructive methods Type de document : texte imprimé Auteurs : J. A. Graystone, Auteur ; R. Kennedy, Auteur Année de publication : 2005 Article en page(s) : p. 163-170 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Adhésion Contrôle non destructif Emission acoustique Interférométrie lasers Revêtements organiques Thermographie Tags : Formation  motif  Subsurface  Interférométrie  Thermographie  Emission  acoustique  Peinture  Propriété  surface  Adhérence  Essai  non  destructif  Revêtement  Performance  Etude  expérimentale Index. décimale : 667.9 Revêtements et enduits Résumé : Adequate adhesion is the sine qua non for good practical performance in surface coatings systems such as paint. By far the majority of tests used in the coatings industry are destructive and difficult to correlate with performance. Moreover, destructive tests are incompatible with best practice in inspection and quality control. A range of non-destructive testing techniques was appraised for their ability to investigate different types of coating failure involving adhesion. Three techniques were selected for preliminary investigation, namely acoustic emission, pulse thermography and laser interferometry. All three techniques were capable of investigating different aspects of adhesive failure. Pulse thermography could detect subsurface damage not apparent to visual inspection, and acoustic emission could, under some circumstances, give information of damage initiation prior to catastrophic failure. Electronic speckle pattern shearing interferometry (ESPSI) was also able to detect sub-surface damage, and showed promise of detecting differences in strain transfer prior to any detachment failure. Note de contenu : - DISCUSSION : Approaches to non-destructive testing of coatings - Summary of specific techniques - EXPERIMENTAL WORK AND PRACTICAL EVALUATION : Test panels - Evaluation of electronic speckle pattern shearing interferometry - Evaluation of pulse thermography - Acoustic emission - Table 1 : Summary of some methods for assessing adhesive performance non-destructively - Table 2 : Potential techniques for studying different types of coating adhesion problem in four major application areas - Table 3 : Pull-off and cross hatch results for various primed panels at two films thicknesses DOI : 10.1007/BF02699568 En ligne : https://link.springer.com/content/pdf/10.1007/BF02699568.pdf Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=5411 [article]

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Modelling printing processes : A computational approach / C. A. Powell in SURFACE COATINGS INTERNATIONAL. PART B : COATINGS TRANSACTIONS, Vol. 88, B3 (09/2005)  

[article]  inSURFACE COATINGS INTERNATIONAL. PART B : COATINGS TRANSACTIONS > Vol. 88, B3 (09/2005) . - p. 171-176 Titre : Modelling printing processes : A computational approach Type de document : texte imprimé Auteurs : C. A. Powell, Auteur ; M. D. Savage, Auteur ; James Thomas Guthrie, Auteur Année de publication : 2005 Article en page(s) : p. 171-176 Note générale : Bibliogr. Langues : Anglais (eng) Tags : 'Méthode  des  éléments  finis'  'Volume  de  fluide  méthode'  'Processus  d'impression'  'Instabilités  processus' Index. décimale : 667.9 Revêtements et enduits Résumé : In a variety of industrial printing processes, liquids must be transferred from one substrate to another in order to create a liquid pattern, the wet print. With the notable exception of inkjet printing, surprisingly to date there has been no serious attempt to model printing processes either theoretically or computationally. As industrial competition places increasingly stringent demands on print quality and operation speed, fundamental research into the underlying fluid mechanics of liquid printing- long overlooked - is now becoming essential. Two quite different numerical schemes, a Lagrangian finite element method and an Eulerian volume of fluid method, are reviewed and the relative merits of both methods are briefly discussed. Sample computations are then presented to illustrate how a numerical approach may be used to (a) simulate micro-scale liquid printing from a trapezoidal cavity to a moving substrate, and (b) model a ‘pintool’ in which a rod is used to deposit a small dot of liquid onto a substrate. Finally, the authors model two distinct printing-related phenomena that may lead to serious process instabilities. Note de contenu : - INTRODUCTION : Lagrangian finite element method - Volume of fluid method - APPLICATIONS TO PRINTING : Printing liquid from a trapezoidal cavity - Printing with a pintool - The effect of imperfect cell filling in gravure printing - Gravity and rotation-driven instabilities DOI : 10.1007/BF02699569 En ligne : https://link.springer.com/content/pdf/10.1007/BF02699569.pdf Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=5412 [article]

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Monte carlo approach to estimating coating service lifetime during weathering / Stuart G. Croll in SURFACE COATINGS INTERNATIONAL. PART B : COATINGS TRANSACTIONS, Vol. 88, B3 (09/2005)  

[article]  inSURFACE COATINGS INTERNATIONAL. PART B : COATINGS TRANSACTIONS > Vol. 88, B3 (09/2005) . - p. 177-183 Titre : Monte carlo approach to estimating coating service lifetime during weathering Type de document : texte imprimé Auteurs : Stuart G. Croll, Auteur ; Brian R. Hinderliter, Auteur Année de publication : 2005 Article en page(s) : p. 177-183 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Angle de contact Brillance (optique) Durée de vie (Ingénierie) Monte-Carlo, Méthode de Mouillage (chimie des surfaces) Résistance aux conditions climatiques Revêtements organiques Index. décimale : 667.9 Revêtements et enduits Résumé : Change in a coating surface, or bulk, during weathering is the accumulation of repeated, random, nanoscale erosion or chemical events that may be modelled using Monte Carlo techniques. Multiphase coatings, including pigments, may be simulated, as well as polymers that change their sensitivity to degradation during weathering. The results of the Monte Carlo model are compared with those of macroscopic properties, such as, gloss, fracture toughness, and wetting contact angle. Simulated properties change through the lifetime of the coating in ways that are consistent with published results. Seemingly complicated changes in properties may be described by repeated simple, random processes. Note de contenu : - EXPERIMENTAL PROCEDURE : Monte Carlo modelling - Photon flux - Modelling materials - RESULTS : Fracture toughness - Gloss - Wetting contact angle - Correlation between properties during degradation DOI : 10.1007/BF02699570 En ligne : https://link.springer.com/content/pdf/10.1007/BF02699570.pdf Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=5413 [article]

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The evaluation of printability and non-enzymatic NADH reduction of 4'-chlorophenylazo-2-naphthol for use as a printing pigment / M. Oktav in SURFACE COATINGS INTERNATIONAL. PART B : COATINGS TRANSACTIONS, Vol. 88, B3 (09/2005)  

[article]  inSURFACE COATINGS INTERNATIONAL. PART B : COATINGS TRANSACTIONS > Vol. 88, B3 (09/2005) . - p. 185-188 Titre : The evaluation of printability and non-enzymatic NADH reduction of 4'-chlorophenylazo-2-naphthol for use as a printing pigment Type de document : texte imprimé Auteurs : M. Oktav, Auteur ; M. Ulgen, Auteur Année de publication : 2005 Article en page(s) : p. 185-188 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Chromatographie en phase liquide à hautes performances Colorants azoïques Colorimétrie Dispersions et suspensions Encre d'imprimerie Formulation (Génie chimique) Papier et carton couché Pigments Réduction (chimie) Vernis Index. décimale : 667.9 Revêtements et enduits Résumé : The printability of 4'-chlorophenylazo-2-naphthol (CPAN) was evaluated on gloss-coated paper. The preliminary results indicated that the proposed pigment could be used in offset and oil-based ink production. The pigment and its potential reduction product, 4-chloroaniline, were then separated by a reverse phase high-pressure liquid chromatography system. The pigment was incubated with NADH at 37°C for half an hour at different pH values to investigate its possible reduction into the corresponding primary amines (ie 4-chloroaniline and 2-amino-1-naphthol). However, no reduction was observed. This finding indicates a desirable evidence for the pigment in terms of its stability against NADH (nicotinamide adenine dinucleotide), a known biochemical reducing agent in living organisms when the potential toxicity from aromatic primary amines is considered. Note de contenu : - Preparation of 4'-chlorophenylazo-2-naphthol (CPAN) - Preparation of the ink dispersions and the printing experiment - High-performance liquid chromatography liquid chromatography and reaction of CPAN with NADH - Table 1 : Printing ink formulation - Table 2 : Varnish composition - Table 3 : Some colour properties of CPAN on gloss-coated paper DOI : 10.1007/BF02699571 En ligne : https://link.springer.com/content/pdf/10.1007/BF02699571.pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=5414 [article]

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Ultrasonic atomisation : A novel technique for surface coatings / S. G. Gaikwad in SURFACE COATINGS INTERNATIONAL. PART B : COATINGS TRANSACTIONS, Vol. 88, B3 (09/2005)  

[article]  inSURFACE COATINGS INTERNATIONAL. PART B : COATINGS TRANSACTIONS > Vol. 88, B3 (09/2005) . - p. 189-196 Titre : Ultrasonic atomisation : A novel technique for surface coatings Type de document : texte imprimé Auteurs : S. G. Gaikwad, Auteur ; C. Reddy V., Auteur ; A. B. Pandit, Auteur Année de publication : 2005 Article en page(s) : p. 189-196 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Analyse qualitative (chimie) Analyse quantitative (chimie) Atomisation Dépôt par pulvérisation Epaisseur -- Mesure Gouttelettes Revêtement de surface Ultrasons Index. décimale : 667.9 Revêtements et enduits Résumé : In this work, ultrasonic atomisation as a possible spray coating on a moving surface has been studied. The experimental method employed here involved the spraying of ink vertically downwards onto a paper, which was moving laterally. It was found that the percentage area of the covered surface increased with an increase in the height of the ultrasound atomiser from the surface and the vibrational amplitude of the atomiser, while the liquid film thickness on the coated surface decreased with an increase in the height of the ultrasound atomiser, vibrational amplitude of the atomiser and the linear velocity of the moving surface. Also, it was observed that the percentage area as well as the liquid film thickness increased with an increase in the liquid flow rate irrespective of changes in other parameters. The increase in the viscosity of the spraying liquid reduced the area covered by the spray for surface coating, while it increased the coating film thickness. Note de contenu : - EXPERIMENTATION : Experimental set-up - Amplitude control of the ultrasonic atomiser - Experimental conditions - Analysis - RESULTS AND DISCUSSION : Qualitative analysis - Quantitative analysis DOI : 10.1007/BF02699572 En ligne : https://link.springer.com/content/pdf/10.1007/BF02699572.pdf Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=5415 [article]

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Study on potential distribution of atmospheric corrosion using a scanning Kelvin probe / J. Wang in SURFACE COATINGS INTERNATIONAL. PART B : COATINGS TRANSACTIONS, Vol. 88, B3 (09/2005)  

[article]  inSURFACE COATINGS INTERNATIONAL. PART B : COATINGS TRANSACTIONS > Vol. 88, B3 (09/2005) . - p. 197-200 Titre : Study on potential distribution of atmospheric corrosion using a scanning Kelvin probe Type de document : texte imprimé Auteurs : J. Wang, Auteur ; Y. Wang, Auteur Année de publication : 2005 Article en page(s) : p. 197-200 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Construction métallique -- Corrosion Corrosion -- Analyse Kelvin, Sonde de La sonde de Kelvin est un dispositif permettant de mesurer la différence de potentiel de Volta entre deux surfaces métalliques, ou bien entre une surface métallique et un électrolyte. - Principe : Deux surfaces métalliques séparées par un isolant (diélectrique) forment un condensateur. Ce condensateur est caractérisé par sa capacité électrique C. La charge électrique Q est alors reliée à la différence de potentiel de Volta Δψ par : Q = C⋅Δψ Si l'on éloigne ou que l'on rapproche les surfaces, cela fait varier la capacité du système. Si les deux surfaces sont reliées par un fil résistant, il en résulte une modification de l'écoulement de charge dans le fil, donc une variation de Q. Cela permet de déterminer le potentiel de Volta Δψ. - Applications : Le principe de la sonde de Kelvin est utilisé dans certains microscopes à force atomique, nommés KPFM (Kelvin probe force microscopy). Index. décimale : 667.9 Revêtements et enduits Résumé : A scanning Kelvin probe setup was developed for potential map measurements, and the characteristic of a potential distribution for atmospheric corrosion of metal with salt particle deposition was investigated using this setup. It was found that as the relative humidity increased to a level higher than that over the saturated solution of the salt, the potential map changed from homogeneity into heterogeneity, which formed initially a valley, then a volcano shape. As a result, atmospheric corrosion was initiated due to the heterogeneity shown by the potential distribution, which led to the formation of anodes and cathodes on the metal surface. It also indicated that ambient relative humidity and dry-and-wet cycles played an important role in accelerating the corrosion process shown by the changing potential map. In addition, the potential map had a close relationship with the chemical maps of the corrosion products. Based on the above findings, a model was proposed and discussed for describing the initiation of atmospheric corrosion resulting from salt particle deposition. Note de contenu : - The potential map over metal surface with salt particle deposition - The effect of relative humidity and wet-dry cycles on a potential map - The correlation between the potential map and the chemical map - The model of a potential map for atmospheric corrosion initiation caused by salt particle deposition DOI : 10.1007/BF02699573 En ligne : https://link.springer.com/content/pdf/10.1007/BF02699573.pdf Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=5416 [article]

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The kinetics and mechanism of the direct fluorination of polyethylenes / Alexander P. Kharitonov in SURFACE COATINGS INTERNATIONAL. PART B : COATINGS TRANSACTIONS, Vol. 88, B3 (09/2005)  

[article]  inSURFACE COATINGS INTERNATIONAL. PART B : COATINGS TRANSACTIONS > Vol. 88, B3 (09/2005) . - p. 201-212 Titre : The kinetics and mechanism of the direct fluorination of polyethylenes Type de document : texte imprimé Auteurs : Alexander P. Kharitonov, Auteur ; Reiner Taege, Auteur ; Grant Ferrier, Auteur ; N. P. Piven, Auteur Année de publication : 2005 Article en page(s) : p. 201-212 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Cinétique chimique Fluoration Polyéthylène basse densité Polyéthylène haute densité Polyfluorure de vinyle Polyfluorure de vinylidène Index. décimale : 668.9 Polymères Résumé : Two types of low-density polyethylene (LDPE), five types of high-density polyethylene (HDPE), poly(vinyl fluoride) (PVF) and poly(vinylidene fluoride) (PVDF) were studied. The fluorination of LDPE and HDPE is a diffusion-controlled process and proceeds via a branched chain mechanism following an induction period. Initiation of the reaction takes place via the reaction of molecular fluorine with the C-H bond. The rate of fluorination of HDPE exceeds that of LDPE. PVDF cannot be fluorinated even at temperatures as high as 430K and/or under UV irradiation. The kinetics associated with the formation and termination of peroxy RO •2 and fluorocarbon long-lifetime radicals was studied. It is mainly middle peroxy radicals that are formed at treatment conditions close to those used in industrial processes. Note de contenu : - INTRODUCTION : Materials - Experimental - RESULTS AND DISCUSSION : Kinetics of formation of a fluorinated layer - The relationship between fluorination and chemical composition : IR study - The relationship between fluorination and chemical composition - IR study - summary - The kinetics of formation of long-life radicals - Kinetics of the termination of long-lifetime radicals - The kinetics of elementary reactions - Summary - Preliminary schematic of the elementary reaction DOI : 10.1007/BF02699574 En ligne : https://link.springer.com/content/pdf/10.1007/BF02699574.pdf Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=5417 [article]

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Novel procedure for polymer coatings of nanoscopic surface topology / C. D. Eisenbach in SURFACE COATINGS INTERNATIONAL. PART B : COATINGS TRANSACTIONS, Vol. 88, B3 (09/2005)  

[article]  inSURFACE COATINGS INTERNATIONAL. PART B : COATINGS TRANSACTIONS > Vol. 88, B3 (09/2005) . - p. 213-216 Titre : Novel procedure for polymer coatings of nanoscopic surface topology Type de document : texte imprimé Auteurs : C. D. Eisenbach, Auteur ; M. Entenmann, Auteur ; Thadeus Schauer, Auteur Année de publication : 2005 Article en page(s) : p. 213-216 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Copolymères séquencés Revêtements organiques Séparation de phases Transition de phase En physique, une transition de phase est une transformation du système étudié provoquée par la variation d'un paramètre extérieur particulier (température, champ magnétique...). Cette transition a lieu lorsque le paramètre atteint une valeur seuil (plancher ou plafond selon le sens de variation). La transformation est un changement des propriétés du système. Index. décimale : 667.9 Revêtements et enduits Résumé : A new coating technique based on the so-called lower critical solution temperature (LCST) phase transition phenomena known from polymer solutions has been studied. Contrary to the commonly-known features that precipitation from solution occurs upon cooling (or solvent evaporation) or by a precipitant, LCST behaviour means a coagulation and precipitation of the polymer from solution upon heating, once a critical temperature is exceeded. This technology not only allows a controlled surface modification of pigments or flat substrates by an organic polymer coating layer, but also allows one to introduce specific surface features of nanoscopic to mesoscopic dimensions. The surface topology may be reversibly varied from a regular, almost close-packed, mesoscopic hemisphere texture to a nanoscopic roughness or rendered evenly smooth. DOI : 10.1007/BF02699575 En ligne : https://link.springer.com/content/pdf/10.1007/BF02699575.pdf Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=5418 [article]

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The role of castor oil in epoxy and polyamide systems for coating and adhesive application / V. Shukla in SURFACE COATINGS INTERNATIONAL. PART B : COATINGS TRANSACTIONS, Vol. 88, B3 (09/2005)  

[article]  inSURFACE COATINGS INTERNATIONAL. PART B : COATINGS TRANSACTIONS > Vol. 88, B3 (09/2005) . - p. 217-220 Titre : The role of castor oil in epoxy and polyamide systems for coating and adhesive application Type de document : texte imprimé Auteurs : V. Shukla, Auteur ; M. Singh, Auteur ; D. K. Singh, Auteur ; Ri. Shukla, Auteur Année de publication : 2005 Article en page(s) : p. 217-220 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Adhésion Alliages polymères Brillance (optique) Epoxydes Essais dynamiques Huile de ricin et constituants Polyamides Un polyamide est un polymère contenant des fonctions amides -C(=O)-NH- résultant d'une réaction de polycondensation entre les fonctions acide carboxylique et amine. Selon la composition de leur chaîne squelettique, les polyamides sont classés en aliphatiques, semi-aromatiques et aromatiques. Selon le type d'unités répétitives, les polyamides peuvent être des homopolymères ou des copolymères. Polyamines Résistance chimique Réticulants Souplesse (mécanique) Index. décimale : 667.9 Revêtements et enduits Résumé : Over the past few years, the challenges of globalisation, consolidation and economical point of view have meant that manufacturers of epoxy formulations have to constantly improve their capability to meet the needs of customers. An active area for advancement is that of epoxy and polyamide resin with castor oil. Generally, people working in the coating industries are familiar with castor oil, but this paper provides information on the new use of castor oil in epoxy and polyamide resin. This novel product (castor oil-modified epoxy resin/castor oil-modified polyamide) provides a previously unattainable combination and improved flexibility and toughness to a variety of ambient cure applications. This communication will review the performance of these castor oil-modified epoxy and polyamide resin surface coatings and adhesives. Based on the results of this study, these systems offer some advantages without much affecting the traditional properties of epoxy and polyamide resin in a variety of applications. Note de contenu : - EXPERIMENTAL : Materials - Methods - RESULTS AND DISCUSSION : Flexibility - Impact test - Adhesion - Gloss - Chemical resistance DOI : 10.1007/BF02699576 En ligne : https://link.springer.com/content/pdf/10.1007/BF02699576.pdf Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=5419 [article]

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