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Absorbency / Pronoy K. Chatterjee / Amsterdam [Pays Bas] : Elsevier Scientific Publishing Company (1985)
Titre : Absorbency Type de document : texte imprimé Auteurs : Pronoy K. Chatterjee, Editeur scientifique Editeur : Amsterdam [Pays Bas] : Elsevier Scientific Publishing Company Année de publication : 1985 Collection : Textile science and technology, ISSN 0920-4083 num. 7 Importance : XIV-333 p. Présentation : ill. Format : 25 cm ISBN/ISSN/EAN : 978-0-444-42377-1 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Absorption
Cellulose -- Dérivés
CelluloseLa cellulose est un glucide constitué d'une chaîne linéaire de molécules de D-Glucose (entre 200 et 14 000) et principal constituant des végétaux et en particulier de la paroi de leurs cellules.
Copolymères greffés
Energie de surface
liquides
Matériaux fibreux
Nontissés
Textiles et tissusIndex. décimale : 677 Textiles Note de contenu : - 1. Fibrous materials
- 2. Mechanism of liquid flow and structure property relationships
- 3. Surface tension and surface energy
- 4. Experimental aspects of fiber wetting and liquid movement between fibers
- 5. The role of surfactants
- 6. Synthetic and natural polymers
- 7. Crosslinked cellulose and cellulose derivatives
- 8. Polymer grafted cellulose and starch
- 9. The role of nonwoven materials
- 10. Technology perspectivesPermalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=34501 Réservation
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Code-barres Cote Support Localisation Section Disponibilité 22283 677 CHA Monographie Bibliothèque principale Documentaires Disponible Acrylate grafted dehydrated castor oil alkyd : A binder for exterior paints / Subhasri Majumdar in JOURNAL OF COATINGS TECHNOLOGY (JCT), Vol. 70, N° 879 (04/1998)
[article]
Titre : Acrylate grafted dehydrated castor oil alkyd : A binder for exterior paints Type de document : texte imprimé Auteurs : Subhasri Majumdar, Auteur ; Dhirendra Kumar, Auteur ; Y. P. S. Nirvan, Auteur Année de publication : 1998 Article en page(s) : p. 27-33 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Anticorrosion
Bateaux -- Revêtements:Bateaux -- Peinture
Copolymères greffés
Huile de ricin et constituants
Huiles et graisses
Liants
Polyméthacrylate de butyle
Résistance aux conditions climatiquesIndex. décimale : 667.9 Revêtements et enduits Résumé : To meet the requirement of improved durability of alkyd resin for use in weatherwork paint for superstructure of ships, an attempt has been made to chemically modify a castor oil alkyd by graft copolymerization with methyl methacrylate and butyl methacrylate in view of their ability to provide polymers with good exterior durability. Characterization of the experimental resins, in respect to physical properties, was carried out using instruments such as a vapor pressure osmometer, rotational viscometer, universal tensile testing instrument (Instron 1123), and differential scanning calorimeter. Performance of the resins was evaluated using a fluorescent UV accelerated weatherometer and multi-head glossmeter. The results reveal substantial improvement in drying and weather resistance properties of castor oil alkyd on graft copolymerization with both methyl methacrylate and butyl methacrylate. The improvement in these properties is marginally superior in the case of MMA grafted alkyds. MMA modification also enhances the mechanical properties of the grafted castor oil alkyd. Note de contenu : - Chemicals
- Synthesis of acrylated alkyd
- Characterization of acrylated alkyd resins
- Performance evaluation of acrylated alkyd filmsPermalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=17968
in JOURNAL OF COATINGS TECHNOLOGY (JCT) > Vol. 70, N° 879 (04/1998) . - p. 27-33[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 003548 - Périodique Bibliothèque principale Documentaires Disponible An optimization study of the graft polymerization of HEMA onto leather / R. A. Masoud in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 87, N° 4 (07-08/2003)
[article]
Titre : An optimization study of the graft polymerization of HEMA onto leather Type de document : texte imprimé Auteurs : R. A. Masoud, Auteur Année de publication : 2003 Article en page(s) : p. 159-161 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Allongement à la rupture
Copolymères greffés
Cuirs et peaux -- Propriétés mécaniques
Essais dynamiques
Polyméthacrylate d'hydroxyéthyle
Traction (mécanique)Index. décimale : 675 Technologie du cuir et de la fourrure Résumé : 2-Hydroxyethyl methacrylate (HEMA) has been graft copolymerized onto chrome-tanned leather using benzoyl peroxide in methanol as the initiator. The influence of synthesis variables, including monomer concentration, initiator selection and temperature, have been investigated. As the graft polymerization of HEMA onto chrome-
tanned leather was increased, water absorption was reduced and tensile strength and elongation at break improved.
FT-IR spectroscopic analysis of ungrafted and grafted leather showed a band at 1735 cm-1 corresponding to the carbonyl of the ester of acrylate (HEMA), while subsequent SEM analysis revealed a decrease in the porosity of the leather surface as a result of the graft polymerization.Note de contenu : - EXPERIMENTAL PROCEDURES :
- Materials
- Graft polymerization method
- Elongation at break
- RESULTS AND DISCUSSION :
- Effect of benzoyl peroxide [B.P]concentration
- Effect of time
- Effect of HEMA monomer concentration
- IR spectra
- Water absorption
- Scanning Electron Microscope SEM
- Table 1 : Effect of the level of graft polymerization of HEMA onto chrome-tanned leather on water absorption
- Table 2 : Effect of the degree of grafting on Tensile strength and elongation at breakEn ligne : https://drive.google.com/file/d/1o_G0vxMYeHCALuAxQjr_aQrRCkq0lKdW/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=39772
in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC) > Vol. 87, N° 4 (07-08/2003) . - p. 159-161[article]Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire Anti-aging performance of cardanol grafted onto polypropylene by reactive extrusion / J.-R. Lin in INTERNATIONAL POLYMER PROCESSING, Vol. XXX, N° 3 (07/2015)
[article]
Titre : Anti-aging performance of cardanol grafted onto polypropylene by reactive extrusion Type de document : texte imprimé Auteurs : J.-R. Lin, Auteur ; J.-H. Lin, Auteur ; Q.-H. Chen, Auteur Année de publication : 2015 Article en page(s) : p. 310-316 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Allongement à la rupture
Cardanol
Copolymères -- Propriétés mécaniques
Copolymères greffés
Elasticité
Extrusion réactive
Polypropylène
Résistance à la rupture
Résistance des matériauxIndex. décimale : 668.4 Plastiques, vinyles Résumé : The cardanol grafted onto polypropylene (CAPP) was prepared by reactive extrusion with polypropylene (PP) and natural renewable cardanol, which could improve the inherent defects of PP such as chemical inertness and hydrophobicity. Moreover, the cardanol grafted onto PP could resolve the degradation of PP during the process of reactive extrusion, storage and application. In this paper, the yield strength, tensile strength, elongation at break of modified and unmodified PPs were tested during the aging process. A possible aging mechanim of PP and anti-aging mechanism of cardanol grafted onto PP were proposed. Results showed that the initiator dicumyl peroxide caused the degradation of PP chains during the aging processing. After being aged for 24 h, the yield strength CAPP0 decreased from 28 MPa to 15 MPa and the elongation at break reduced by 795%. CAPPs possessed outstanding anti-aging performance owing to the cross-linking and entanglement of the side chains of cardanol grafted onto PP. The yield strength, tensile strength and the elongation at break of CAPP5 changed lightly even when it was in long-term irradiation for 480 h. The CAPPs had better anti-aging properties than the mixture of PP and 5% of cardanol. CAPP containing 3% of cardanol could effectively prevent the degradation of the main chain polypropylene. Note de contenu : - EXPERIMENTAL : Materials - Preparation of cardanol grafted onto polypropylene (CAPP) - Mechanical properties testing
- RESULTS AND DISCUSSION : Yield strength of cardanol grafted onto polypropylene (CAPP) - Tensile strength of cardanol grafted onto polypropylene (CAPP) - Elongation at break of CAPP - Deduction of aging mechanism - Comparison of aging performance of CAPPs with CAPPm - The effect of cardanol concentration on anti-ageing properties of CAPPsDOI : 10.3139/217.2944 En ligne : https://drive.google.com/file/d/1wZfxne7fYnTZfwfaVmr_nyFDB3gT4KA7/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=24325
in INTERNATIONAL POLYMER PROCESSING > Vol. XXX, N° 3 (07/2015) . - p. 310-316[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 17309 - Périodique Bibliothèque principale Documentaires Disponible Antigraffiti polyurethane coating containing fluorocarbon side chains grafted polymethylsiloxane / Hu Liu in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 10, N° 3 (05/2013)
[article]
Titre : Antigraffiti polyurethane coating containing fluorocarbon side chains grafted polymethylsiloxane Type de document : texte imprimé Auteurs : Hu Liu, Auteur ; Baosong Fu, Auteur ; Yi Li, Auteur ; Qianqian Shang, Auteur ; Guomin Xiao, Auteur Année de publication : 2013 Article en page(s) : p. 361-369 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Copolymères greffés
Fluoropolymères
HydrosilylationLa réaction d'hydrosilylation consiste en l'addition d'une fonction hydrogénosilane (Si-H) sur un composé organique insaturé.
Il existe principalement deux méthodes pour mettre en œuvre cette réaction :
La génération de radicaux silyle : thermiquement (300 °C), par irradiation (rayonnement ultraviolet ou par décomposition de peroxydes ou d'azonitriles.
La catalyse par des métaux de transition généralement du groupe VIII. Parmi ces différents catalyseurs employés pour la réaction d'hydrosilylation, les composés à base de platine et plus particulièrement l'acide hexachloroplatinique hexahydraté sont ceux qui présentent la plus grande efficacité1. Ce catalyseur utilisé en très faible quantité et pour des temps de réaction généralement inférieurs à 5 h permet d'atteindre des rendements relativement élevés.
Un mécanisme plus récent de l'hydrosilylation a été proposé dans la thèse de Patrick Cancouët sur un polysiloxane porteur de fonction hydrogénosilanes latérales.
Polyméthylsiloxane
Polyuréthanes
Revêtements anti-graffitisIndex. décimale : 667.9 Revêtements et enduits Résumé : The novel polymethylsiloxane grafted by fluorocarbon side chains was synthesized via hydrosilylation reaction of polymethylhydrosiloxane (PMHS) with 2,2,3,4,4,4-hexafluorobutyl acrylate (HFBA) in the presence of Karstedt’s catalyst. The reaction factors of reaction temperature, reaction time, catalyst dosage, solvent dosage, and molar ratio of the reactants were investigated through orthogonal experiments. Under optimal conditions, the grafting ratio of HFBA to PMHS reached 91.6%. The structure of the grafted polymer was characterized by FTIR and 1H NMR spectra. The synthesized polymer was incorporated into two-component polyurethane coating formulations as an additive to prepare antigraffiti coatings. After curing, the contact angle measurement was performed and the results showed that surface free energy of the coating film decreased dramatically from 30.7 to 21.4 mJ/m2. The inks of permanent markers cannot spread readily on the coating film and can be removed easily, indicating that the incorporation of the synthesized polymer endowed the coating with admirable antigraffiti performance. XPS analysis revealed that atomic concentrations of silicon and fluorine near the surface (about 10 nm) were much higher than deeper within the film (about 100 nm), suggesting that these two elements had a strong migration tendency toward the coating–air interface. AFM measurement showed that the inclusion of synthesized polymer in coating did not affect the surface roughness of the film. Note de contenu : - EXPERIMENTAL : Materials - Synthesis of PHMS-graft-HFBA (PSF) - Preparation of antigraffiti polyurethane paints (AGPU) - Characterization
- RESULTS AND DISCUSSION : Orthogonal experiment design for the synthesis of PSF - Structure characterization - Surface properties of coatingsDOI : 10.1007/s11998-012-9452-4 En ligne : https://link.springer.com/content/pdf/10.1007%2Fs11998-012-9452-4.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=18735
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Code-barres Cote Support Localisation Section Disponibilité 15149 - Périodique Bibliothèque principale Documentaires Disponible 15593 - Périodique Bibliothèque principale Documentaires Disponible Application of the experimental results to the modified Halpin-Tsai micromechanical model to evaluate the clay dispersion in clay-reinforced polyethylene nanocomposites / N. Uyanik in INTERNATIONAL POLYMER PROCESSING, Vol. XXIX, N° 1 (03/2014)
PermalinkCharacterisation and application of polyurethane copolymers grafted with photoluminescent dyes / Yong Chan Chung in COLORATION TECHNOLOGY, Vol. 130, N° 4 (08/2014)
PermalinkCollagen modification using nanotechnologies : a review / Deng-Ge Gao in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CVIII, N° 10 (10/2013)
PermalinkComparative effects of mEOC on the structures and properties of PP/SGF and PP/EOC/SGF composite foams / J.-N. Yang in INTERNATIONAL POLYMER PROCESSING, Vol. XXXI, N° 3 (07/2016)
PermalinkComposites of cysteamine functionalised graphene oxide and polypropylene / S. S. Abbas in INTERNATIONAL POLYMER PROCESSING, Vol. 36, N° 3 (2021)
PermalinkCrystallization behavior of polypropylene-graft-cardanol prepared by reactive extrusion / Q. Chen in INTERNATIONAL POLYMER PROCESSING, Vol. XXVIII, N° 1 (03/2013)
PermalinkCyclic extrusion of recycled high density polyethylene/banana fiber/fly ash cenosphere biocomposites : thermal and mechanical retention properties / Sukanya Satapathy in INTERNATIONAL POLYMER PROCESSING, Vol. XXXIV, N° 1 (03/2019)
PermalinkDérivés de protéines greffés aux silicones / Jones Roger in PARFUMS COSMETIQUES AROMES, N° 109 (01-02/93)
PermalinkDevelopment and characterization of polyurethane and acrylonitrile butadiene styrene and their compatibilized blends / Khaled A. Alfadhel in INTERNATIONAL POLYMER PROCESSING, Vol. XXXII, N° 3 (07/2017)
PermalinkDevelopments in polymer architecture and design applicable to surface coatings / S. Perrier in SURFACE COATINGS INTERNATIONAL. PART B : COATINGS TRANSACTIONS, Vol. 87, B4 (12/2004)
PermalinkDirect observation of freeze-thaw instability of latex coatings via high pressure freezing and cryogenic SEM / Cheng-Le Zhao in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 3, N° 2 (04/2006)
PermalinkEffects of colloidal silica on the properties of POSS-containing fluorinated poly(styrene–acrylate)/SiO2 composite materials / Wenbo Liao in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 18, N° 1 (01/2021)
PermalinkEffects of montmorillonite content and maleic anhydride compatibilization on the mechanical behavior of polylactide nanocomposites / B. Sari in INTERNATIONAL POLYMER PROCESSING, Vol. XXXI, N° 4 (08/2016)
PermalinkLes élastomères thermoplastiques fluorés / Bruno Améduri in L'ACTUALITE CHIMIQUE, N° 301-302 (10-11/2006)
PermalinkEnzymatic synthesis of sodium alginate-g-poly (acrylic acid) grafting copolymers as a novel printing thickener / Nan Zhang in COLORATION TECHNOLOGY, Vol. 138, N° 3 (06/2022)
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