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JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA) . Vol. CXIX, N° 7Mention de date : 07/2024Paru le : 15/07/2024 |
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Ajouter le résultat dans votre panierInfluence of polyurethane binders on the surface properties of finished leathers : Part 1 - Function as a sealing coat / Suriya Madhan in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CXIX, N° 7 (07/2024)
[article]
Titre : Influence of polyurethane binders on the surface properties of finished leathers : Part 1 - Function as a sealing coat Type de document : texte imprimé Auteurs : Suriya Madhan, Auteur ; R. Monica Denise, Auteur ; Sujata Mandal, Auteur ; Swarna Vinodh Kanth, Auteur Année de publication : 2024 Article en page(s) : p. 295-302 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Adhésion
Angle de contact
Croûte (cuir)On entend par "cuir en croûte" des cuirs ayant subi les opérations jusqu'au tannage, à l'exclusion de toute opération de corroyage ou de finissage, mais qui, par opposition aux wet-blue ont été séchés.
Cuirs et peaux -- Finition
Cuirs et peaux -- Propriétés mécaniques
Cuirs et peaux -- Propriétés organoleptiques
Cuirs et peaux de bovins
Energie de surface
Essais dynamiques
Etanchéité
Liants
Mesure
Perméabilité
PolyuréthanesIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : Finishing is the final stage of the leather-making process, where the surface of the leather is enhanced to improve its durability, appearance, and texture. The sealing coat (used predominantly in corrected grain leathers for leather accessories and footwear industries) is the first step that forms the bottom layer of the leather finishing film before the base coat. The goal of the sealing coat is to keep the leather surface reactive and prevent the pigmented base coat from sinking completely into the grain of the leather. The chemicals used in the sealing coat provide the leather surface with a charge and condition (addition of oil/fat and/or polyurethane -PU) to ensure that the chemicals (pigments, binders, and other additives) used in the base coat of the finishing process are not completely absorbed into the grain layer of the crust leather. In the present study, the influence of PU as an additive to the sealing coat formulation was evaluated through measurement of surface properties, such as contact angle, surface energy, and work of adhesion. The values of the contact angle between the liquids (water/dimethyl sulfoxide/hexadecane) and the leather surface were used to evaluate the leather’s surface energy and work of adhesion. The water contact angle of the uncoated crust, cationic oil ground (COG)-coated crust, and COG-PU-coated crust was measured as 77.3, 93.6, and 109.0 degrees respectively. The increase in contact angle indicates an increase in the hydrophobicity of the leather’s surface on coating with COG and COG+PU. The surface energy component (γs) of the crust leather surface without coating, COG-coated, and COG-PU-coated leathers were 35.2, 28.3, and 24.8 m/Nm, while the work of adhesion of the above leathers for water were 88.8, 68.2, and 49.1 mJm-2, respectively. The experimental values indicated that PU plays an important role as an additive to the sealing coat and enhances the required properties in the finishing process for the desired final leather. Note de contenu : - EXPERIMENTAL SECTION : Materials
- METHOD : Determination of contact angle - Measurement of work of adhesion and surface energy - Determination of wet and dry fastness - Determination of water-vapor permeability - Determination of physical strength characteristics - Measurement of adhesion of finish - Determination of organoleptic properties
- RESULTS AND DISCUSSON : Contact angle and surface parameters of dyed crust, COG-coated and COG-PU-coated leather - Work of adhesion and surface energy of dyed crust, COG-coated leather, and COG-PU-coated leather - Relationship between work of achesion/surface energy and acidity/basicity of leathers coated with COG and COG-PU - Relationship between surface energy and polarity of leathers coated with COG and COG-PU - Water vapor permeability - The influence of COG and COG-PU coat on the physical organoleptic properties of finished leathers
- Table 1 : Process of wet blue to black crust from cow hides
- Table 2 : Process of sealing coat
- Table 3 : Process of PU-sealing coat
- Table 4 : Process of base and top coat after sealing/PU sealing coat
- Table 5 : Contact angle, surface energy (ysv), acidity, basicity, polarity, work of adhesion (Wa) of dyed crust, COG-coated, and COG-PU-coated leathers
- Table 6 : Finish adhesion, fastness to rub, and elongatio at break of dyed crust, COG-coated and COG-PU-coated leather
- Table 7 : Organoleptic properties of the dyed crust, COG-coated and COG-PU-coated leatherDOI : https://doi.org/10.34314/wdwj1p18 En ligne : https://drive.google.com/file/d/1J-_XLaKaV9az3xQYOPmWX42gVhsR-1lP/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=41283
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Code-barres Cote Support Localisation Section Disponibilité 24734 - Périodique Bibliothèque principale Documentaires Sorti jusqu'au 30/09/2024 Preparation and characterization of decellularized ECM hydrogel from adipose tissues of hide/skin : Unlocking untapped resource potential / Gayathri Devi Chakrapani in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CXIX, N° 7 (07/2024)
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Titre : Preparation and characterization of decellularized ECM hydrogel from adipose tissues of hide/skin : Unlocking untapped resource potential Type de document : texte imprimé Auteurs : Gayathri Devi Chakrapani, Auteur ; Fathima Shifana, Auteur ; Gladstone Christopher Jayakumar, Auteur ; Balaraman Madhan, Auteur Année de publication : 2024 Article en page(s) : p. 303-313 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Biomatériaux
Caractérisation
Cuirs et peaux -- Déchets -- Recyclage
Glycosaminoglycanes
hydrocolloïdes
Ingénierie tissulaireIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : Raw fleshing wastes is the major solid waste generated during leather manufacturing. Utilization of the fleshing waste for the development of biomaterial holds a promising and sustainable solution for leather manufacturing. Decellularized hydrogels possess the ability to differentiate into specific tissue types of the host microenvironment and supports the cell adhesion, migration, proliferation, and differentiation of cells. Hydrogel is a biocompatible biomaterial that has the potential to mimic extracellular matrix (ECM). ECM-based biomaterials derived from animal tissues are ideal for applications in tissue engineering. In the present research work, dECM-derived hydrogels from the decellularized raw fleshing waste was prepared and characterized for its possible applications in tissue engineering. The fleshing waste was decellularized using varying concentrations of SDS and Triton-X 100 detergents. The tissue sample treated with 0.1% SDS and 1% Triton-X 100 for decellularization exhibited higher collagen and glycosaminoglycans (GAG) retention. The study also provides a possible way for the transformation of tannery fleshing waste into high value products. Note de contenu : - EXPERIMENTAL : Materials - Preparation of decellularized fleshing tissue - Preparation of hydrogel from decellularized fleshing - Characterisation of decellularized - DNA content quantification - Collagen estimation assay - Glycosaminoglycans (GAGs) assay - Histological analysis - Fibrillation assay - Scanning electron microscopy (SEM) - Gelation kinetics - Methylene blue active substances (MBAS) assay - Cell viability and cytotoxicity studies
- RESULTS : DNA content quantification - Collagen estimation assay - Glycosaminoglycans (GAGs) assay - Histological analysis - Fibrillation assay and gelation kinetics - Microscopic analysis - Methylene blue active substances (MBAs) assay - Cell viability and cytotoxicity studies
- Table 1 : Chemical decellularization treatment protocols
- Table 2 : The concentration of GAGs (µg/mg) present in the sample
- Table 3 : Turbidity analysis results of decellularized ECM-based hydrogelsDOI : https://doi.org/10.34314/ay8wjt13 En ligne : https://drive.google.com/file/d/1g4xEpzMNkBrQuebDIHGAuUqsOeL0--h2/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=41284
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Code-barres Cote Support Localisation Section Disponibilité 24734 - Périodique Bibliothèque principale Documentaires Sorti jusqu'au 30/09/2024 Keratin hydrolysis from tannery unhairing process wastes structural property determination and keratin size investigation reducing by electrospinning method / Eser Eke Bayramoglu in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CXIX, N° 7 (07/2024)
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Titre : Keratin hydrolysis from tannery unhairing process wastes structural property determination and keratin size investigation reducing by electrospinning method Type de document : texte imprimé Auteurs : Eser Eke Bayramoglu, Auteur ; Anil Ozcelik, Auteur ; Sultan Civi, Auteur ; Güversel Eke, Auteur ; Bilgehan Bayramoglu, Auteur Année de publication : 2024 Article en page(s) : p. 314-322 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Analyse quantitative (chimie)
Cuirs et peaux -- Déchets -- Recyclage
Cuirs et peaux de chèvres
Electrofilature
Epilage
Hydrolyse
Kératines -- Propriétés physiques
Kératines -- Propriétés thermiques
kératinesLa kératine est une protéine, synthétisée et utilisée par de nombreux êtres vivants comme élément de structure, et également l'exemple-type de protéine fibreuse.
La kératine est insoluble, et peut être retrouvée sur l'épiderme de certains animaux, notamment les mammifères, ce qui leur garantit une peau imperméable. Parfois, lors d'une friction trop importante, la kératine se développe à la surface de la peau formant une callosité. Les cellules qui produisent la kératine meurent et sont remplacées continuellement. Les morceaux de kératine qui restent emprisonnés dans les cheveux sont couramment appelés des pellicules.
La molécule de kératine est hélicoïdale et fibreuse, elle s'enroule autour d'autres molécules de kératine pour former des filaments intermédiaires. Ces protéines contiennent un haut taux d'acides aminés à base de soufre, principalement la cystéine, qui forment un pont disulfure entre les molécules, conférant sa rigidité à l'ensemble. La chevelure humaine est constituée à 14 % de cystéine.
Il y a deux principales formes de kératines : l'alpha-kératine, ou α-keratin, présente chez les mammifères notamment, dont l'humain, et la bêta-kératine, ou β-keratin, que l'on retrouve chez les reptiles et les oiseaux. Ces deux types de kératines ne présentent clairement pas d'homologie de séquence.
Chez l'être humain, la kératine est fabriquée par les kératinocytes, cellules se trouvant dans la couche profonde de l'épiderme. Les kératinocytes absorbent la mélanine (pigment fabriqué par les mélanocytes), se colorent et ainsi cette pigmentation de l'épiderme permet de protéger les kératinocytes des rayons ultraviolets du Soleil. (Wikipedia)
Poils -- RecyclageIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : White goat skin waste hair obtained as a by-product of the leather unhairing process was used to produce hydrolyzed keratin, the starting point for this study. Properties of this keratin hydrolyzed such as thermal stability (DSC), structure (FTIR) and nitrogen content (Kjeldahl Method) were characterized. The powdered form of this keratin was reduced to micro size (Matsusada brand high power supply) and further characterized for molecular size (SEM). The outcome of this study found that keratin made from waste goat hair was more resistant to heat than the initial starting point goat hair. This important finding offers a means to leverage waste goat hair for valued end uses thus improving the overall environmental impact of the leather making process.
impact of the leather making process.Note de contenu : - MATERIALS AND METHODS : Material - Methods : Leather unhairing process - Kerating production from unhairing waste - Reducing the molecular size of keratin and dimensional analysis with SEM - Determination of the nitrogen amount of keratin by the Kjeldahl method - Determining structural properties of keratin with FTIR analysis - Determination of thermal properties of keratin with DSC analysis
- RESULTS AND DISCUSSION : FTIR analysis results - DSC analysis results - SEM analysis results - Nitrogen determination results - pH determination
- Table 1 : Amino acids contain in keratin and their chemical formulas
- Table 2 : Wavenlengths of peaks of keratin bondsDOI : https://doi.org/10.34314/paqtar25 En ligne : https://drive.google.com/file/d/1eI8tiarpAzax4Ym3IzaGfrAx2WvrlyYo/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=41285
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Code-barres Cote Support Localisation Section Disponibilité 24734 - Périodique Bibliothèque principale Documentaires Sorti jusqu'au 30/09/2024
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Code-barres | Cote | Support | Localisation | Section | Disponibilité |
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24734 | - | Périodique | Bibliothèque principale | Documentaires | Sorti jusqu'au 30/09/2024 |