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Controllable self-organization of polyphenylene oxide honeycomb microstructure / H. Chen in INTERNATIONAL POLYMER PROCESSING, Vol. XXVII, N° 4 (08/2012)
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Titre : Controllable self-organization of polyphenylene oxide honeycomb microstructure Type de document : texte imprimé Auteurs : H. Chen, Auteur ; X. Shang, Auteur ; D. Zhang, Auteur ; I. Hagiwara, Auteur Année de publication : 2012 Article en page(s) : p. 486-492 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Films plastiques
Hydrophobie
Microstructures
Oxyde de polyphénylène
Plastiques alvéolaires
Structure en nid d'abeilles
Systèmes auto-organisésIndex. décimale : 668.9 Polymères Résumé : Polymer films with patterned microstructure have been widely applied in various industrial areas such as micro reactors, chemical sensors and micro-molded template etc. In this paper, a self-supporting polymer film with regular honeycomb microstructure is fabricated by self-organization via evaporation of polyphenylene oxide (PPO) solution in which carbon disulfide is used as solvent under humid ambience. Apart from investigation of self-organization mechanism of PPO honeycomb including nucleation, growth of water droplets condensed upon liquid supporting substrate, the quantitative relationship between honeycomb microstructure and ambient conditions is built through tremendous self-organization experiments. The controllable formation of honeycomb microstructure with desirable hydrophobicity was achieved by use of built quantitative relationship. Moreover, hydrophobicity mathematical model of self-organized honeycomb thin film was proposed, and its validation was experimentally verified. Note de contenu : - PPO SELF-ASSEMBLY EXPERIMENT
- RESULTS AND DISCUSSION : Stability of the self-organized film - Influence of ambient humidity on self-organized film - Influence of solution concentration on the self-organized film - Controllability of honeycomb microstructure formationDOI : 10.3139/217.2606 En ligne : https://drive.google.com/file/d/1pHrueSKIlee_MtkTq9VWdrzJ_1bpmlmE/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=15772
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