| Titre : |
Methyl acrylate polymers as suitable materials for the conservation of stone : performance improvements through atom transfer radical polymerization |
| Type de document : |
texte imprimé |
| Auteurs : |
Barbara Sacchi, Auteur ; Laura Giannini, Auteur ; Marco Frediani, Auteur ; Luca Rosi, Auteur ; Piero Frediani, Auteur |
| Année de publication : |
2013 |
| Article en page(s) : |
p. 649-657 |
| Note générale : |
Bibliogr. |
| Langues : |
Américain (ame) |
| Catégories : |
Copolymérisation
Fluoropolymères
Polyacrylate de méthyle
Polymérisation radicalaire par transfert d'atome
Revêtements protecteurs
|
| Index. décimale : |
667.9 Revêtements et enduits |
| Résumé : |
Acrylic polymers are a suitable category of materials for application in building stone conservation mainly due to their peculiarities (i.e., easy to apply, low cost, good adhesive and cohesive properties, and high solubility in many organic solvents). The performances of polyacrylates have been improved through atom transfer radical polymerization (ATRP). Polymers were obtained with low polydispersity, controlled molecular weight, and showing better stability to UV irradiation than products obtained by radical polymerization. New poly(methyl acrylate-co-perfluoropolyethers) were also prepared via ATRP, using a perfluoropolyether derivative as initiator, showing the possibility of synthesizing copolymers between acrylates and perfluoropolyethers in common solvents. Protective efficiency of poly(methyl acrylate-co-perfluoropolyether) was close to that of commercially available products. |
| Note de contenu : |
- EXPERIMENTAL : Instruments - Solvents and reagents - Synthesis of the monomers - Synthesis of polymers - Stone material - Performances of the polymers applied on stone materials
- RESULTS AND DISCUSSION : Synthesis and characterization of polymers - Stability of polymers - Protective performances of polymers |
| DOI : |
10.1007/s11998-013-9495-1 |
| En ligne : |
https://link.springer.com/content/pdf/10.1007%2Fs11998-013-9495-1.pdf |
| Format de la ressource électronique : |
Pdf |
| Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=19799 |
in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH > Vol. 10, N° 5 (09/2013) . - p. 649-657
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Methyl acrylate polymers as suitable materials for the conservation of stone : performance improvements through atom transfer radical polymerization in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 10, N° 5 (09/2013)
