Antifouling improvement of a polyacrylonitrile membrane blended with an amphiphilic copolymer in INTERNATIONAL POLYMER PROCESSING, Vol. 37, N° 1 (2022)  

[article]  inINTERNATIONAL POLYMER PROCESSING > Vol. 37, N° 1 (2022) . - p. 93-105 Titre : Antifouling improvement of a polyacrylonitrile membrane blended with an amphiphilic copolymer Type de document : texte imprimé Année de publication : 2022 Article en page(s) : p. 93-105 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Adhésion Caractérisation Copolymère acrylonitrile-co-polyhydroxyéthyl méthacrylate Copolymères Hydrophilie Matériaux -- Propriétés antisalissures Membranes (technologie) Perméation Polyacrylonitrile Polymères amphiphiles Taille des pores Index. décimale : 668.4 Plastiques, vinyles Résumé : The amphiphilic copolymer polyacrylonitrile-co-poly(hydroxyethyl methacrylate) (PAN-co-PHEMA) was readily blended with polyacrylonitrile (PAN) to fabricate a flat-sheet blending membrane through non-solvent induced phase separation (NIPS). In the membrane-forming process, the hydrophilic PHEMA chains are uniformly distributed on the surface, as revealed by the energy-dispersive X-ray tests. The sponge-like sub-layer embedded with droplet-shaped structures is formed at the cross-sections of membranes, because of the high viscosity of the casting solution. With the increase of copolymer concentration, the mean pore size of the blending membranes increases from 26.9 to 99.8 nm, leading to the increase of membrane flux from 93.6 to 205.4 l/(m2h). The incorporation of PAN-co-PHEMA copolymer endows the blending membrane with a rough surface microstructure and enhanced hydrophilicity. The rejection ratio of membranes for emulsified pump oil reaches 99.9%, indicating a prominent separation performance. In the cycle permeation experiments, the flux recovery ratio of the blending membranes is as high as 99.6%, which is much higher than those of PAN membrane. The irreversible fouling of blending membranes induced by oil adsorption is alleviated, and converted into reversible fouling, owing to the reduction of the adhesion force between foulant and membrane surface. These results suggest that the anti-fouling property of PAN membranes has been dramatically strengthened via the addition of PAN-co-PHEMA copolymer. Note de contenu : - EXPERIMENTAL : Materials - Membrane preparation - Membrane characterization - Permation experiments - RESULTS AND DISCUSSION : Chemical structure and composition of the blending membranes - Morphology of the membranes - Hydrophilicity of the membranes - Adhesion force between foulant and membrane surface - Permeation and antifouling properties - Table 1 : Compositions and viscosities of casting solutions - Table 2 : Elemental concentration of the membrane surfaces - Table 3 : Mean roughness parameter (Ra) and mean pore size (dm) of the membranes DOI : https://doi.org/10.1515/ipp-2021-4175 En ligne : https://drive.google.com/file/d/1gHIUnshbRcjPcKdHhmL5HqHm_wBDgAWG/view?usp=share [...] Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=38444 [article]

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