Titre : |
Dyes derived from 1,4-naphthoquinone as initiators for radical and cationic photopolymerisation |
Type de document : |
texte imprimé |
Auteurs : |
Agnieszka Szymczak, Auteur ; Radoslaw Podsiadly, Auteur ; Karolina Bazela, Auteur ; Jolanta Sokolowska, Auteur |
Année de publication : |
2012 |
Article en page(s) : |
p. 378-386 |
Note générale : |
Bibliogr. |
Langues : |
Anglais (eng) |
Catégories : |
Amorceurs (chimie) Colorants -- Synthèse Naphtoquinone Photochimie Photoréticulation Polyaddition Spectrométrie de masse Spectroscopie de la résonance magnétique nucléaire
|
Index. décimale : |
667.3 Teinture et impression des tissus |
Résumé : |
Several 2-phenylamino-1,4-naphthoquinone-based dyes and two related benzo[2,3-b]–phenazines were synthesised and characterised by proton nuclear magnetic resonance spectroscopy and electron ionisation mass spectrometry. The electrochemical and spectral properties of these compounds were investigated. The synthesised dyes were found to be capable photosensitisers for radical (reducible/oxidisable) and cationic polymerisations, respectively. In radical polymerization, better results in the oxidisable process were achieved. |
Note de contenu : |
- EXPERIMENTAL : General - Synthesis of 2-(4-chloroanilino)-3-chloro-1,4-naphthoquinone Id - Synthesis of 2-(4-chloroanilino)-3-bromo-1,4-naphthoquinone IId - Synthesis of 6,11-dihydro-benzo[2,3-b]phenazine-6,11-dione IIIa - Photochemical |
DOI : |
10.1111/j.1478-4408.2012.00391.x |
En ligne : |
http://onlinelibrary.wiley.com/doi/10.1111/j.1478-4408.2012.00391.x/pdf |
Format de la ressource électronique : |
Pdf |
Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=15806 |
in COLORATION TECHNOLOGY > Vol. 128, N° 5 (2012) . - p. 378-386