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Evaluation of siliconized epoxy coatings by electrochemical impedance spectroscopy / S. Ananda Kumar in EUROPEAN COATINGS JOURNAL (ECJ), N° 4/00 (04/2000)
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Titre : Evaluation of siliconized epoxy coatings by electrochemical impedance spectroscopy Type de document : texte imprimé Auteurs : S. Ananda Kumar, Auteur ; M. Alagar, Auteur ; K. P. O. Mahesh, Auteur ; T. S. N. Sankara Narayanan, Auteur ; V. Mohan, Auteur Année de publication : 2000 Article en page(s) : p. 64-77 Note générale : Bibliogr. Langues : Anglais (eng) Index. décimale : 667.9 Revêtements et enduits Résumé : Solvent free siloxane modified epoxy coatings were developed by interpenetrating technique. The corrosion resistant behaviour of siliconized epoxy coating systems with 25% zinc powder cured with four different curatives has been investigated by Electrochemical Impedance Spectroscopy (EIS). The results are comparable with those obtained from neutral salt spray tests. The siloxane (10%) modified epoxy coating system A with 25% zinc powder cured by hexamethylene diamine offers maximum corrosion protection to steel surface. Note de contenu : - Preparation of siloxane modified epoxy coating system
- Preparation of prepolymer mix
- Siloxane introduction into epoxy coating system
- Electrode preparation
- Impedance measurements
- Formation of a low frequency diffusion tail confirms that the corrosion process is a diffusion controlled reaction
- The resistance and the capacitance values of coating systems A, B, C and D are in the range of 10^9 ohm.cm² and 10^-10 F
- Better corrosion protection of steel surfaces
- The Bode plot can be explained with the help of threshold frequency limits and the variation of logarithmic values of impedance with frequency
- The data analysis of the coating systems A,B,C, and D confirms the existence of a single constantPermalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=10994
in EUROPEAN COATINGS JOURNAL (ECJ) > N° 4/00 (04/2000) . - p. 64-77[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 000615 - Périodique Bibliothèque principale Documentaires Disponible 000616 - Périodique Bibliothèque principale Documentaires Disponible Novel siliconized-epoxy interpenetrating coating / S. Ananda Kumar in EUROPEAN COATINGS JOURNAL (ECJ), N° 9/99 (09/1999)
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Titre : Novel siliconized-epoxy interpenetrating coating Type de document : texte imprimé Auteurs : S. Ananda Kumar, Auteur ; M. Alagar, Auteur ; K. P. O. Mahesh, Auteur ; V. Mohan, Auteur Année de publication : 1999 Article en page(s) : p. 84-88 Note générale : Bibliogr. Langues : Anglais (eng) Index. décimale : 667.9 Revêtements et enduits Résumé : Interpenetrating polymer networks (IPN) are novel types of polymer blends and they possess excellent physicochemical properties suitable for high performance coatings. In the present work a novel siliconized-epoxy coating system was developed by interpenetrating technique. The effect of siloxane introduction into epoxy resin and nature of curatives on the corrosion resistance characteristics towards steel specimen were studied by weight loss and electrochemical potential measurements. It was observed that, the siloxane incorporation enhances the corrosion resistant properties and reduce moisture absorption. It was also observed that the aromatic polyamineadduct cured siloxane modified epoxy coating system with 25% zinc powder exhibits better corrosion resistance than the polyamidoamine cured system. Note de contenu : - Status quo
- Siloxane polymeric component is suitable to modify epoxy resin
- Experimental: - Surface preparation of test specimen - Preparation of siloxane modified epoxy coating system - Preparation of prepolymer mix - Siloxane introduction into epoxy coating system - Application of coating over test specimen - Weight loss method - Calculation of weight loss a raw specimen (x) - Electrochemical potential measurement
- Minimum weight loss and maximum corrosion protection with siloxane modified epoxy
- Cured by aromatic polyamineadduct better than polyamidoamine cured system
- Incorporation of siloxane as well as zinc powder enhances corrosion protection behaviour
- Aromatic nature of the curative minimizes the oxidation of steel specimenEn ligne : https://drive.google.com/file/d/1L6MR7jFmxogva2mCVG5UlfsNjV4Y4Pgb/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=11208
in EUROPEAN COATINGS JOURNAL (ECJ) > N° 9/99 (09/1999) . - p. 84-88[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 000609 - Périodique Bibliothèque principale Documentaires Disponible