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Formaldehyde release from chekiang lambskin, characteristic parameter determination and influencing factors / Hao Dong-Yan in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 103, N° 5 (09-10/2019)
[article]
Titre : Formaldehyde release from chekiang lambskin, characteristic parameter determination and influencing factors Type de document : texte imprimé Auteurs : Hao Dong-Yan, Auteur ; Wang Xue-Chuan, Auteur ; Lu Wei-Na, Auteur ; Li Ji, Auteur Année de publication : 2019 Article en page(s) : p. 260-267 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Coefficient de diffusion Un coefficient de diffusion est une grandeur caractéristique du phénomène de diffusion de la matière. Le coefficient de diffusion mesure le rapport entre le flux molaire dû à la diffusion moléculaire, et le gradient de concentration de l'espèce chimique considérée (ou, plus généralement, de la variable d'effort entraînant cette diffusion), comme formulé par la loi de Fick.
Cuirs et peaux de moutons
Distillation
EmissivitéEn transfert radiatif, l'émissivité correspond au flux radiatif du rayonnement thermique émis par un élément de surface à température donnée, rapporté à la valeur de référence qu’est le flux émis par un corps noir à cette même température. Cette dernière valeur étant la valeur maximale possible, l'émissivité est un nombre inférieur ou égal à l'unité. (widipedia)
Extraction (chimie)
Fourrures -- Teneur en formaldehydeIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : VOC emissions may cause poor indoor (vehicle cabins included) air quality (IAQ). Recent studies have been conducted on the characteristics of volatile organic compounds (VOCs) emissions, most of them are focused on wood-based building materials, fur or fur imitations are scarcely mentioned. However, formaldehyde or formaldehyde-containing chemicals are often used in the production of fur, resulting in a certain amount of formaldehyde remaining in the finished product. This paper takes formaldehyde (FA) as an example to study its diffusion in fur. In order to understand and control the behaviour of the formaldehyde emission characteristics. Based on detailed mass transfer analysis of the emission process in a ventilated chamber, this paper measured the three emission characteristic parameters, i.e., the initial emittable concentration (C0), the diffusion coefficient (Dm) and the partition coefficient (K). The influence of different factors on the release parameters was also studied, as well as the time required for the emission of formaldehyde under different ventilation rates ; we also compared the formaldehyde results of different test methods. The results showed that both Dm and C, increased as temperature rose, but Co increase is significant. With the increase of relative humidity, Dm decreased but Co increased. In addition, the prediction model agrees well with the experimental data. The greater the ventilation rate, the faster the improvement of air quality standards in the cabin; The initial concentration was less than 43% of the formaldehyde content obtained through the extraction method and less than 4.6% of the formaldehyde content obtained by the distillation method. Note de contenu : - EXPERIMENTAL PROCEDURE : Materials - Equipment and instruments - Formaldehyde emission test of fur - Extraction method - Distillation method - Mass release model
- RESULTS AND DISCUSSION : Effects of different temperatures on the release parameters - The effect of different relative humidity levels on characteristic parameters - Comparison of diffusion coefficient Dm between fur and other materials in the literature - Comparison of release time of formaldehyde in the environmental cabin under different ventilation conditions - Comparison of the initial concentration of fur formaldehyde with the concentration measured by distillation and extraction method - Sensitivity analysisEn ligne : https://drive.google.com/file/d/1yku0zJdX5XxuEJ6e7E33dfsg429hja_r/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=33001
in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC) > Vol. 103, N° 5 (09-10/2019) . - p. 260-267[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 21222 - Périodique Bibliothèque principale Documentaires Disponible Nonparametric bootstrap method for estimating the upper confidence limits of exposure point concentrations of formaldehyde in fur products - A case study of tongxiang city, China / Yuan Xuzheng in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CXII, N° 11 (11/2017)
[article]
Titre : Nonparametric bootstrap method for estimating the upper confidence limits of exposure point concentrations of formaldehyde in fur products - A case study of tongxiang city, China Type de document : texte imprimé Auteurs : Yuan Xuzheng, Auteur ; Wang Xuechuan, Auteur ; Lu Weina, Auteur ; Jiang Sujie, Auteur Année de publication : 2017 Article en page(s) : p. 387-394 Note générale : Bibliogr Langues : Américain (ame) Catégories : Fourrures -- Analyse
Fourrures -- Teneur en formaldehyde
Mesure -- Méthodes statistiquesIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : The distribution characteristics of the formaldehyde (FA) content of fur products produced in Tongxiang City over three consecutive years (2014-2016) were analyzed by the Lilliefors test, quarterback robust statistical method, and kernel density estimation. The bootstrap simulation sampling method was used to calculate the upper confidence limits (UCL) of the exposure point concentration (EPC) of FA. The robustness and rationality of the UCL estimation were verified by the distribution of the mean value of each bootstrap sample dataset. The results showed that their distributions were close to normal distribution but were highly skewed. The one-sided 95% UCL on the mean were 95.45 mg/kg, 93.02 mg/kg and 86.64 mg/kg, which decreased year by year. The Wilcoxon rank sum test indicated that the population distribution of the FA content in 2016 showed a structural improvement over those of the previous two years. Note de contenu : - SAMPLE SOURCES AND METHODS : Case study area : tongxiang city - Samples sources - Method for determination of FA - Data processing method for samples below the LOD - Polymorphic analysis of FA content for every year
- Estimation UCL for EPC of FA for every year
- Pairwise comparison of FA content by wilcoxon rank sum test
- RESULTS AND DISCUSSION : Data processing method for samples below the LOD - Descriptive statistical analysis of the FA content in fur products - Symmetry analysis of distribution of FA content in fur products - Computing UCL and programmed by MATLAB - UCL values and robustness verification - Pairwise comparison of FA content by the wilcoxon rand sum testEn ligne : https://drive.google.com/file/d/1d_Ldj-bt-EwIaewoBJT4Ha4OWKF6Yxxp/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=29397
in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA) > Vol. CXII, N° 11 (11/2017) . - p. 387-394[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 19363 - Périodique Bibliothèque principale Documentaires Disponible