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Crystallization behavior and mechanical properties of nanosilica-reinforced isotactic polypropylene composites / J. Li in INTERNATIONAL POLYMER PROCESSING, Vol. XXX, N° 5 (11/2015)
[article]
Titre : Crystallization behavior and mechanical properties of nanosilica-reinforced isotactic polypropylene composites Type de document : texte imprimé Auteurs : J. Li, Auteur ; L.-J. Long, Auteur ; W.-T. He, Auteur ; K. Zhang, Auteur ; Y.-S. Xiang, Auteur ; J. Zhang, Auteur ; M.-M. Zhang, Auteur ; C.-P. Yang, Auteur ; J. Yu, Auteur Année de publication : 2015 Article en page(s) : p. 542-547 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Caractérisation
Charges (matériaux)
Flexion (mécanique)
Gel de silice
Nanoparticules
Polymères -- Propriétés mécaniques
Polymères isotactiques
Polypropylène
Résistance au chocs
SiliceLa silice est la forme naturelle du dioxyde de silicium (SiO2) qui entre dans la composition de nombreux minéraux.
La silice existe à l'état libre sous différentes formes cristallines ou amorphes et à l'état combiné dans les silicates, les groupes SiO2 étant alors liés à d'autres atomes (Al : Aluminium, Fe : Fer, Mg : Magnésium, Ca : Calcium, Na : Sodium, K : Potassium...).
Les silicates sont les constituants principaux du manteau et de l'écorce terrestre. La silice libre est également très abondante dans la nature, sous forme de quartz, de calcédoine et de terre de diatomée. La silice représente 60,6 % de la masse de la croûte terrestre continentale.
Structure cristalline (solide)
Traction (mécanique)Index. décimale : 668.9 Polymères Résumé : Two different types of inorganic silica fillers, nano-silica powder (NSP) and colloidal silica sol (CSS) were added into isotactic polypropylene (iPP) with low silica content (0.2 wt%) and the influence of the two silica fillers on the crystallization behavior and mechanical properties of iPP were investigated. Differential scanning calorimeter (DSC) results showed that the crystallization temperature of iPP with CSS and NSP were increased by 4.1 °C, and 2.4 °C, respectively. The tensile strength, flexural strength, and izod impact strength of iPP/CSS (33.75 MPa, 33.04 MPa, and 4.80 kJ/m2) were higher than that of iPP/NSP (32.09 MPa, 32.27 MPa, and 4.25 kJ/m2). In addition, the haze value of iPP/CSS was decreased from 37.6 % to 27.6 %, which was 4.7 % lower than that of iPP/NSP (32.3 %). The better performance of CSS as ascribed to its better dispersion ability in iPP matrix than NSP, and it was verified by scanning electron micrograph (SEM) and transmission electron microscope (TEM). Overall, these results indicated that inorganic silica sols had a potential application in the nanoparticle-reinforced composites field. Note de contenu : - EXPERIMENTAL : Raw materials - Preparation of iPP/silica composites - Characterization
- RESULT AND DISCUSSION : Crystalline structure and crystallization behaviorDOI : 10.3139/217.3065 En ligne : https://drive.google.com/file/d/1TckKt9TRURlEoVI-WZbYRc0LDIc3Gqeg/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=24815
in INTERNATIONAL POLYMER PROCESSING > Vol. XXX, N° 5 (11/2015) . - p. 542-547[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 17557 - Périodique Bibliothèque principale Documentaires Disponible Effects of cooling ways on the structure of polypropylene hollow fiber membranes prepared by stretching / D.-J. Luo in INTERNATIONAL POLYMER PROCESSING, Vol. XXXIV, N° 2 (05/2019)
[article]
Titre : Effects of cooling ways on the structure of polypropylene hollow fiber membranes prepared by stretching Type de document : texte imprimé Auteurs : D.-J. Luo, Auteur ; F.-J. Wei, Auteur ; H.-J. Shao, Auteur ; K.-Z. Zhang, Auteur ; Z.-Y. Cui, Auteur ; J. Yu, Auteur ; S.-H. Qin, Auteur Année de publication : 2019 Article en page(s) : p. 172-181 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Essais dynamiques
Extrusion filage
Fibres creuses
Membranes (technologie)
Morphologie (matériaux)
Polypropylène
Porosité
Surfaces (Physique)
Systèmes de refroidissement
Traction (mécanique)Index. décimale : 668.4 Plastiques, vinyles Résumé : Air, water, and DINCH (Di-isononyl-cyclohexane-1,2-dicarboxylate) were selected as the cooling media to prepare polypropylene hollow fiber membranes by melt spinning. The effects of various cooling ways with different cooling rates on the row-nucleated lamellar crystallization were investigated. The crystallinity, orientation and arrangement of the crystals were examined by differential scanning calorimetry (DSC), wide-angle X-ray diffraction (WAXD), and small-angle X-ray scattering (SAXS). Membrane morphology was observed by SEM. The less uniform pores, a layer of amorphous phase, and only a small part of slit-shaped pores were observed on the surface of samples when water and DINCH were used as the heat transfer medium because the fast cooling rate froze the surface molecules and decreased the crystallinity and orientation. However, when air was used as the cooling medium, the higher crystallinity and the better orientation of the annealed hollow fibers were obtained mainly due to the slow cooling rate. Corresponding hollow fiber membranes prepared by stretching had better interconnectivity of pores and larger pure water flux. Thus this study explains why air was selected as the cooling medium to prepare polypropylene hollow fiber membranes which can have larger pure water flux. Also, it provides new insights into the structure control of polypropylene hollow fiber membranes by stretching in order to prepare membranes with high strength. Note de contenu : - EXPERIMENTAL : Materials - Membrane preparation - Differential Scanning Calorimetry - Surface morphology - Tensile properties - Elastic recovery rate
- RESULTS AND DISCUSSION : Crystallization and DSC analysis - SAXS and WAXD analysis - Tensile properties and elastic recovery rate - Surfaces morphologies - Porosity and pure water fluxDOI : 10.3139/217.3638 En ligne : https://drive.google.com/file/d/1T1rC3UNtaRnspchVpMtyqp5EaKrJkRWH/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=32393
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Code-barres Cote Support Localisation Section Disponibilité 20883 - Périodique Bibliothèque principale Documentaires Disponible Influence of rubber ratio and crosslinking agent on mechanical properties, crystallization and rheological behaviors of EPDM/PP thermoplastic elastomer / D.-H. Xu in INTERNATIONAL POLYMER PROCESSING, Vol. XXXIV, N° 4 (08/2019)
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Titre : Influence of rubber ratio and crosslinking agent on mechanical properties, crystallization and rheological behaviors of EPDM/PP thermoplastic elastomer Type de document : texte imprimé Auteurs : D.-H. Xu, Auteur ; Y. Zhou, Auteur ; W.-D. He, Auteur ; H.-M. Wu, Auteur ; J. Yu, Auteur Année de publication : 2019 Article en page(s) : p. 457-466 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Analyse mécanique dynamique
Analyse thermique
Caoutchouc -- Propriétés mécaniques
Cristallisation
Elastomères thermoplastiques -- Propriétés mécaniques
Ethylène-propylène-diène monomère
Morphologie (matériaux)
Polypropylène
Réticulants
Rhéologie
VulcanisationIndex. décimale : 668.4 Plastiques, vinyles Résumé : The ethylene-propylene-diene monomer/polypropylene (EPDM/PP) thermoplastic elastomer is prepared by dynamic vulcanization. The effects of different rubber ratios and crosslinking agent contents on the static and dynamic mechanical properties, crystallization and rheological behaviors are investigated and discussed. EPDM/PP with the rubber ratio from 40 to 50 % and crosslinking agent content of 1.2 wt% has the highest tensile strength and elongation at break. The fracture morphologies indicate that EPDM/PP with high rubber ratios and crosslinker contents is over vulcanized to harden, which results in that some large particles cannot be fragmented by shear force. The crystallinity obtained from differential scanning calorimetry (DSC) shows a decrease with increasing rubber ratio and a very slight variation with increasing the crosslinking content. The dynamic mechanical analysis (DMA) results display a decrease trend in storage modulus and tan δ with increasing crosslinking density. The rheological behaviors show that the complex viscosity also increases with increasing crosslinking density, indicating that the elastic deformation becomes superior to viscous flow in EPDM/PP. Note de contenu : - EXPERIMENTAL : Materials - Preparation of samples - Measurements and characterization
- RESULTS AND DISCUSSION : Mechanical properties - Morphology analysis - Crystallization behavior - Dynamic mechanical properties - Rheology behaviorDOI : 10.3139/217.3817 En ligne : https://www.degruyter.com/document/doi/10.3139/217.3817/pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=33064
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Code-barres Cote Support Localisation Section Disponibilité 21083 - Périodique Bibliothèque principale Documentaires Disponible Modeling and characterization of the relationship between cell size and mechanical behavior of microcellular PP/mica composites / W. Gong in INTERNATIONAL POLYMER PROCESSING, Vol. XXV, N° 4 (09/2010)
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Titre : Modeling and characterization of the relationship between cell size and mechanical behavior of microcellular PP/mica composites Type de document : texte imprimé Auteurs : W. Gong, Auteur ; J. C. Gao, Auteur ; M. Jiang, Auteur ; J. Yu, Auteur ; L. He, Auteur Année de publication : 2010 Article en page(s) : p. 270-274 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Caractérisation
Composites -- Propriétés mécaniques
Mica
Mousses plastiques -- Propriétés mécaniques
PolypropylèneIndex. décimale : 668.9 Polymères Résumé : The microcellular foamed polypropylene (PP)/mica composites were prepared through chemical microcellular injection to investigate the relationship between the mechanical behavior and the cell size. The mechanical behavior model of the microcellular foams is built based on the elastic stress/strain field. The mechanical behavior of the microcellular composites coincides well with the theoretical model. Under loading the large and non uniform cells are in a state of plane strain, which leads to low tensile and impact strengths, whereas small and uniform cells are in a state of plane stress, which contributes to the transition from brittle to tough fracture behavior in the microcellular PP/mica composite. DOI : 10.3139/217.2339 En ligne : https://drive.google.com/file/d/1Kd32PgdddqcamxdgPUkmThuPcSsqVZBe/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=9823
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Code-barres Cote Support Localisation Section Disponibilité 012380 - Périodique Bibliothèque principale Documentaires Disponible Morphology and isothermal crystallization kinetics of polypropylene/poly(ethylene-co-vinyl alcohol) blends / D.-J. Luo in INTERNATIONAL POLYMER PROCESSING, Vol. XXXIV, N° 2 (05/2019)
[article]
Titre : Morphology and isothermal crystallization kinetics of polypropylene/poly(ethylene-co-vinyl alcohol) blends Type de document : texte imprimé Auteurs : D.-J. Luo, Auteur ; H.-J. Shao, Auteur ; F.-J. Wei, Auteur ; K.-Z. Zhang, Auteur ; Z.-Y. Cui, Auteur ; J. Yu, Auteur ; S.-H. Qin, Auteur Année de publication : 2019 Article en page(s) : p. 195-208 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Alliages polymères
Caoutchouc
Copolymère éthylène alcool de vinyleC'est aujourd'hui le matériau le plus utilisé dans l'emballage rigide alimentaire. Il peut être utilisé avec des matériaux de structure comme le polyéthylène, polypropylène ou polystyrène. Ce copolymère présente une excellente imperméabilité à l'oxygène, au gaz carbonique et aux arômes, à condition de protéger de l'influence de l'humidité qui fait chuter fortement ses performances. Pour palier cet inconvénient, il est souvent pris en sandwich dans des structures multicouches à base de polyoléfines PE ou PP peu sensibles à l'humidité. Il est utilisé pour les emballages de compotes, jus de fruits, fromages, sauces, crèmes et yaourts, mayonnaise, sauce tomate...
Cristallisation
Diffractométrie de rayons X
PolypropylèneIndex. décimale : 668.4 Plastiques, vinyles Résumé : Polypropylene (PP)/poly(ethylene-co-vinyl alcohol) (EVOH) blends were prepared by melt blending using PP-g-MAH as a compatabilizer. The microstructure and rheological behavior of PP/EVOH blends were studied. The results showed the that EVOH particles were uniformly dispersed in the PP matrix and inhibited the mobility of PP chains. The isothermal crystallization kinetics and morphology development of PP/EVOH blends were compared with that of pure PP. It was found that the EVOH essentially acted as an effective nucleating agent for PP, which could significantly increase the nucleation rate because the EVOH molecules in PP/EVOH blends aggregated together to form interface. Therefore, the introduction of EVOH increased the overall rate of isothermal crystallization compared with pure PP, although the PP molecular chains would be hindered seriously if excessive amounts of EVOH were added. X-ray diffraction showed that pure PP and PP/EVOH blends exhibited an identical crystal structure, and the crystallinity of the PP phase in the blends was not significantly different from that of pure PP. Note de contenu : - EXPERIMENTAL : Materials - Sample preparation - Characterization
- RESULTS AND DISCUSSION : Microstructural and viscoelastic properties of PP/EVOH blends - Non-isothermal crystallization behavior of PP/EVOH blends - Isothermal crystallization kinetics of PP/EVOH blends - Melting behavior of isothermally crystallized PP/EVOH blends - Morphology and microstructure of PP/EVOH blendsDOI : 10.3139/217.3589 En ligne : https://www.degruyter.com/document/doi/10.3139/217.3589/pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=32395
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Code-barres Cote Support Localisation Section Disponibilité 20883 - Périodique Bibliothèque principale Documentaires Disponible Study of melt spinning processing conditions for a polyacrylonitrile copolymer with a water/ethanol mixture as a plasticizer / J. Yu in INTERNATIONAL POLYMER PROCESSING, Vol. XXXIV, N° 5 (11/2019)
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